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71.
72.
Effect of Particle Size on Monometallic and Bimetallic (Au,Pd)/C
on the Liquid Phase Oxidation of Glycerol 总被引:2,自引:0,他引:2
Nikolaos Dimitratos Jose Antonio Lopez-Sanchez David Lennon Francesca Porta Laura Prati Alberto Villa 《Catalysis Letters》2006,108(3-4):147-153
The influence of metal particle size of monometallic and bimetallic supported catalysts (Au, Pd, Au–Pd)/C was studied using
as a model reaction the liquid phase oxidation of glycerol. By tuning the metal particle size from 2 to 16 nm a progressive
decrease of activity and simultaneously an increase in the selectivity to sodium glycerate was observed. Moreover, the influence
of the temperature was studied and it was found that by increasing the temperature, only with a large particle size the formed
glycerate was retained and not over-oxidized to tartronate. 相似文献
73.
It is shown, by means of Lagrangian momentum and power balances across the slug nose in slug flow, that the power dissipated due to sudden expansion of the fluid in the film immediately downstream of the slug nose is greater than the power lost due to viscous action at the pipe wall but that it may not be large enough to materially aid particle transport. This has the implication that sand transport in intermittent flow may be considered as transport in a hybrid flow of hydraulic conveying and stratified flow when the length of the mixing section at the slug nose is short compared to the length of the slug body. 相似文献
74.
75.
本文采用粒子追踪理论对水平管中粒子流动状态进行了数值模拟.文中提出了一种新的粒子碰撞模型,并忽略粒子的旋转和扬力,仅考虑气流阻力和重力对粒子的影响,在输送量为9.13×10~3kg/s,混合比约0.3的条件下,通过数值计算得知:由于粒子间的碰撞,使得异径粒子的速度趋向平均化;粒子间的碰撞是粒子悬浮的原因之一;粒子的浓度沿管轴向是随时间而发生变化的. 相似文献
76.
77.
A general variance predictor for Cavalieri slices 总被引:1,自引:0,他引:1
L. M. CRUZ-ORIVE 《Journal of microscopy》2006,222(3):158-165
A general variance predictor is presented for a Cavalieri design with slices of an arbitrary thickness t ≥ 0. So far, prediction formulae have been available either for measurement functions with smoothness constant q = 0, 1, … , and t ≥ 0, or for fractional q ∈ [0, 1] with t = 0. Because the possibility of using a fractional q adds flexibility to the variance prediction, we have extended the latter for any q ∈ [0, 1] and t ≥ 0. Empirical checks with previously published human brain data suggest an improved performance of the new prediction formula with respect to the hitherto available ones. 相似文献
78.
Makoto Kohga 《含能材料》2006,14(6):471-474
1 IntroductionThe ammonium perchlorate ( AP)-based compositepropellant is currently the most widely used one becausethis propellant has good burning characteristics and me-chanical properties. One of the few serious drawbacks ofthe AP-based propellant is that its products of combus-tion, which include HCl, chlorine, and chlorine oxides,cause atmospheric pollution. Increasing concern for aclean atmosphere in recent years has resulted in a com-pelling need for developing a chlorine-free,enviro… 相似文献
79.
旋风管不同排尘结构内流场及颗粒浓度场分析 总被引:4,自引:0,他引:4
采用智能型五孔球探针测试技术及等动采样方法,对两种新型旋风管排尘结构内的流场及颗粒浓度场进行测量。通过大量实验,发现在双锥内部存在的二次流及涡流使得颗粒分布呈现横向返混状态,这不利于颗粒的分离,对单锥与双锥两种不同排尘结构内的流场及颗粒浓度场分布特点进行了对比研究,为进一步优化旋风管排尘结构,提高分离性能奠定了实验基础。 相似文献
80.
If a low weight percentage of crude fine fillers can improve properties of polymer materials directly without complicated chemical treatment process involved, it will be significant for many industrial applications. Our previous study indicated that a kind of Cancun natural sand could be an effective filler material for polymer composites. In this current work, the epoxy composites reinforced by this kind of natural sand particles were prepared and thermal and mechanical properties of the composites containing up to 5 wt % of the sand particles were characterized. Results showed that the highest flexural strength appears in the epoxy composite containing 1 wt % sand particles. A damage model was used to interpret the flexural properties, which showed an acceptable agreement with the experimental results. The glass transition temperature, high temperature storage modulus, and dimensional stability of the sand/epoxy composites monotonically increased with the addition of the sand particles. The sand particle/epoxy composites also displayed a noticeable enhancement in thermal conductivity. Theoretical analysis showed that in addition to conduction, other heat transport mechanisms played roles in the improved heat transmission through the composites. As a natural porous micron-scale material, Cancun sand has the potential for applications in cost-effective composites with enhanced mechanical and thermal properties. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献