AP的安全制备（英）

1 IntroductionThe ammonium perchlorate ( AP)-based compositepropellant is currently the most widely used one becausethis propellant has good burning characteristics and me-chanical properties. One of the few serious drawbacks ofthe AP-based propellant is that its products of combus-tion, which include HCl, chlorine, and chlorine oxides,cause atmospheric pollution. Increasing concern for aclean atmosphere in recent years has resulted in a com-pelling need for developing a chlorine-free,enviro…     

旋风管不同排尘结构内流场及颗粒浓度场分析

采用智能型五孔球探针测试技术及等动采样方法，对两种新型旋风管排尘结构内的流场及颗粒浓度场进行测量。通过大量实验，发现在双锥内部存在的二次流及涡流使得颗粒分布呈现横向返混状态，这不利于颗粒的分离，对单锥与双锥两种不同排尘结构内的流场及颗粒浓度场分布特点进行了对比研究，为进一步优化旋风管排尘结构，提高分离性能奠定了实验基础。     

Thermal and mechanical properties of epoxy composites reinforced by a natural hydrophobic sand

If a low weight percentage of crude fine fillers can improve properties of polymer materials directly without complicated chemical treatment process involved, it will be significant for many industrial applications. Our previous study indicated that a kind of Cancun natural sand could be an effective filler material for polymer composites. In this current work, the epoxy composites reinforced by this kind of natural sand particles were prepared and thermal and mechanical properties of the composites containing up to 5 wt % of the sand particles were characterized. Results showed that the highest flexural strength appears in the epoxy composite containing 1 wt % sand particles. A damage model was used to interpret the flexural properties, which showed an acceptable agreement with the experimental results. The glass transition temperature, high temperature storage modulus, and dimensional stability of the sand/epoxy composites monotonically increased with the addition of the sand particles. The sand particle/epoxy composites also displayed a noticeable enhancement in thermal conductivity. Theoretical analysis showed that in addition to conduction, other heat transport mechanisms played roles in the improved heat transmission through the composites. As a natural porous micron-scale material, Cancun sand has the potential for applications in cost-effective composites with enhanced mechanical and thermal properties. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Accelerated wear testing with a microfabricated surface to evaluate the lubrication ability of biomolecules on polyethylene

Wear of ultrahigh‐molecular‐weight polyethylene (UHMWPE) and wear‐particle‐induced osteolysis and bone resorption are the major factors causing the failure of total joint replacements. It is feasible to improve the lubrication and reduce the wear of artificial joints. We need further understanding of the lubrication mechanism of the synovial fluid. The objective of this study is to evaluate the lubricating ability of three major components in the synovial fluid: albumin, globulin, and phospholipids. An accelerated wear testing procedure in which UHMWPE is rubbed against a microfabricated surface with controlled asperities has been developed to evaluate the lubrication behavior. An analysis of the wear particle dimensions and wear amount of the tests has provided insights for comparing their lubrication performance. It is concluded that the presence of biomolecules at the articulating interface may reduce friction. A higher concentration of a biological lubricant leads to a decrease in the wear particle width. In addition, in combination with the wear results and mechanical analysis, the roles of individual biomolecules contributing to friction and wear at the articulating interface are discussed. These results can help us to identify the role of the biomolecules in the boundary lubrication of artificial joints, and further development of lubricating additives for artificial joints may be feasible. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

聚丙烯增韧改性研究进展

综述了国内增韧改性聚丙烯的研究动向 ,介绍了近年来茂金属聚烯烃弹性体和有机/无机纳米粒子增韧聚丙烯的新技术     

Physical Properties Important to Electrostatic and Non electrostatic Powder Transfer Efficiency in a Tumble Drum

ABSTRACT: Popcorn was oiled and coated in a tumble drum nonelectrostatically and electrostatically with sugar, cornstarch, salt, cellulose, maltodextrin, all-purpose flour, whole-wheat flour, or soy flour. Particle size, density, flowability, and chargeability were correlated to transfer efficiency using regression analysis. Of the various methods to measure chargeability, charge-to-mass and adhesion improvement were the most significant. For nonelectrostatic coating, small, dense, free-flowing powders were most efficient. Small, free-flowing highly charging powders were most efficient for electrostatic coating. Percent improvement was the highest for the least efficient powders. The greatest benefit with electrostatic coating was for low density, highly charging powders with no effect of size.     

The deposition morphology of Brownian/non-Brownian particles within a constricted tube

The deposition morphology of Brownian/non-Brownian particles within a constricted tube is investigated by applying the Brownian dynamics simulation method in the present paper. Two different geometric structures, the parabolic constricted tube (PCT) and the sinusoidal constricted tube (SCT), are adopted. The effect of various types of the total interaction energy curves of the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory, and of the shadow area cast by those deposited particles, on the particles’ collection efficiencies are also examined. For the PCT structure, under the same interaction energy curve, it is found that the non-Brownian particles always own a higher collection efficiency than that of the Brownian particles. Since the deposition location moves closer to the constriction part of the tube, the collection efficiencies of the Brownian/non-Brownian particles increase with the decrease of flow velocity. The SCT behaves differently, it is found that the collection efficiencies of non-Brownian particles are only slightly higher than those of Brownian particles when SCT is adopted. The steep slope of the tube wall near the constriction part of SCT dominates the whole deposition process of Brownian/non-Brownian particles. In comparison with the available experimental data, it is found that the present method can give a good simulation result.     

Investigation into Displacement of Placer Gold Particles

The experimental research in displacement of gold particles in washed-out thickness of sand-gravel layer is conducted. The parameters of ability of gold particles to migrate in pulp flow are determined, and their immersion into loose soil is investigated.     

颗粒表面改性法制备PTC粉体的研究

本文介绍了一种通过液相颗粒表面改性技术添加二次掺杂物来制备ＰＴＣ粉体的新方法。即将烧结助熔剂Ａｌ２Ｏ３，ＳｉＯ２以及受主杂质ＭｎＯ采用溶液形式，包裹在ＢａＴｉＯ３基粉体颗粒表面进行改性，由此可以得到二次掺杂物Ａｌ２Ｏ３、ＳｉＯ２和ＭｎＯ分布均匀的ＰＴＣ粉体。     

CH_4、CO_2与O_2制合成气的研究 Ⅱ工艺条件的影响

在固定床反应器中考察了１２％Ｎｉ－５％ＲＥ－２％Ｃｕ－２％Ｌｉ／Ａｌ２Ｏ３（ｍａｓｓ）催化剂在ＣＨ４、ＣＯ２与Ｏ２催化氧化重整制合成气反应中催化剂粒径、工艺操作条件（空速与温度）及原料气配比对反应的影响，确定了较佳的操作条件：催化剂粒径２０～４０目，反应最佳温度为８００℃，ＳＶ＝４×１０４ｍｌ／（ｇ·ｈ）。同时看到在不同的原料气配比的条件下该催化剂的活性亦很稳定，不仅达到了反应平衡，且产物Ｖ（ＣＯ）／Ｖ（Ｈ２）比有很强的调变性。