强磁场对硅锰铸钢于A_1点附近等温珠光体相变的影响

通过开展12 T强磁下硅锰铸钢(50Si_2Mn_3)于A_1点温度附近不同等温时间的热处理试验,并对比强磁场与无磁场条件下等温珠光体相变试验结果,研究了磁场对珠光体转变量及组织形貌的影响。研究表明,对于50Si_2Mn_3在A1点以下较高温度范围内,强磁场可缩短珠光体相变的孕育期,促进硅锰铸钢珠光体转变,使其转变量明显增加;强磁场能够提高珠光体转变临界点,使50Si_2Mn_3在A1点以上等温过程中能够发生珠光体相变。     

Structural control of Fe-based alloys through diffusional solid/solid phase transformations in a high magnetic field

Abstract

A magnetic field has a remarkable influence on solid/solid phase transformations and it can be used to control the structure and function of materials during phase transformations. The effects of magnetic fields on diffusional solid/solid phase transformations, mainly from austenite to ferrite, in Fe-based alloys are reviewed. The effects of magnetic fields on the transformation temperature and phase diagram are explained thermodynamically, and the transformation behavior and transformed structures in magnetic fields are discussed.     

Mn、Cu对球墨铸铁组织性能的影响

为获得高强度高塑性的球墨铸铁,通过加入微量合金元素 Mn 和 Cu,研究 Mn 和 Cu 对球墨铸铁微观组织和力学特性的影响。结果表明：Mn 的加入提高了球墨铸铁中珠光体含量、球墨铸铁的抗拉强度和硬度,但塑性下降;在 Mn 含量一定时,添加适量的 Cu 后,球墨铸铁的性能进一步提高。研究发现,添加适量的合金元素 Mn 和 Cu 可生产高强度的球墨铸铁,且塑性值比对应的国家标准大幅度提高。     

The analysis for morphological evolution and crystallography of degenerate pearlite in 100Mn13 steel

During approximate 773 K aging treatment of 100Mn13 steel, degenerate pearlite will occur and evolve into lamellar pearlite during growth process. The microstructures of degenerate pearlite and its evolutionary lamellar pearlite are observed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results show that after 748 K, 773 K and 798 K aging, degenerate pearlites occur at grain boundary. At growth front of degenerate pearlite forming at 773 K and 798 K, pearlite presents a morphology of short lamellae of carbide and ferrite, indicating a trend of developing into lamellar pearlite. The higher the temperature is, the more obvious the trend is, and even a conventional lamellar pearlite has developed. However, there is no morphological evolution for degenerate pearlite forming at 748 K aging. Besides, the constituents of degenerate pearlite is identified as M₂₃C₆ and ferrite, and Kurdjumov-Sachs orientation relationship exists between them, (01 )_α//( 1 )_M23C6, [111]_α//[110]_M23C6. This orientation relationship maintains in morphological evolution from degenerate pearlite to lamellar pearlite.     

免球化退火SWRCH35K冷镦钢的试验研究

采用热模拟试验研究了形变温度和冷速对SWRCH35K冷镦钢组织和硬度的影响.结果表明,形变温度低于750 ℃,部分珠光体发生了球化,硬度明显降低;当形变温度在700 ℃左右,珠光体明显球化,硬度达到最低;形变后冷速越慢,珠光体球化越明显,其硬度也越低.通过工艺调整,适当降低精轧温度及冷却强度,生产出SWRCH35K热轧盘条,抗拉强度约为560 MPa,面缩率大于55%,表面硬度低于82 HRB.经用户使用,该盘条能实现免球化退火生产8.8级标准件.     

Effect of vanadium and chromium on the microstructural features of V–Cr–Mn–Ni spheroidal carbide cast irons

The objective of this investigation is to study the influence of vanadium（5.0wt%–10.0wt%） and chromium（0–9.0wt%） on the microstructure and hardness of Cr-V-Mn-Ni white cast irons with spheroidal vanadium carbides. The alloys＇ microstructural features are presented and discussed with regard to the distribution of phase elements. The structural constituents of the alloys are spheroidal VC, proeutectoid cementite, ledeburite eutectic, rosette-shaped carbide eutectic（based on M7C3）, pearlite, martensite, and austenite. Their combinations and area fraction（AF） ratios are reported to be influenced by the alloys＇ chemical composition. Spheroidized VC particles are found to be sites for the nucleation of carbide eutectics. Cr and V are shown to substitute each other in the VC and M7C3 carbides, respectively. Chromium alloying leads to the formation of a eutectic（γ-Fe ＋ М7С3）, preventing the appearance of proeutectoid cementite in the structure. Vanadium and chromium are revealed to increase the total carbide fraction and the amount of austenite in the matrix. Cr is observed to play a key role in controlling the metallic matrix microstructure.     

大型离心球铁铸管的组织和性能

从大型离心球墨铸铁管上取样，用光学金相，电子金相法研究了铸造和不同退火状态下的离心球墨铸铁的组织，实现了低温退火新工艺。研究表明，采用低温退火，使片状珠光体转变为粒状珠光体，并且控制粒状珠光体的质量分数为15％－25％，其余为铁素体＋石墨，具有良好的综合机械性能。     

保温隔热材料的新进展

介绍了国内外最新发展的几种具有代表性的保温隔热材料 ,分析了各种材料和保温隔热性能 ,讨论了材料的组分、配制、施工工艺、工程应用及发展前景等。     

铁素体区形变对含铌微合金高强度钢组织及硬度的影响

采用Gleeble-3800热模拟试验机,研究铁素体区变形对含铌微合金高强度(HSLA)钢组织及显微硬度的影响。结果表明:相比于最终变形在Ar3附近(840℃)时获得近等轴状铁素体+退化珠光体组织,最终变形在铁素体区(550～650℃)时获得部分拉长的多边形铁素体+弥散分布的退化珠光体组织。此外,铁素体区最终变形析出的NbC与晶界析出的Fe3C析出相更加细小且弥散。与高温下最终变形相比,铁素体区最终变形获得的组织显微硬度增量达30 HV。通过强化机理分析表明,位错强化与析出相Fe3C和NbC的沉淀强化作用是铁素体区变形组织硬度提高的主要原因,退化珠光体和渗碳体的细化对硬度的提高也有一定量的贡献。     

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利用电子背散射衍射(EBSD)测试技术对国产和进口两种优质弹簧钢55Si Cr的珠光体团尺寸、分布和轧制织构进行了对比分析。结果表明,两种优质弹簧钢中的珠光体团尺寸细小,平均值在6~8μm;国产优质弹簧钢的珠光体团小于10μm的比例达84%。这两种优质弹簧钢中均有3种晶粒取向存在,即<101>、<001>和<111>,国产优质弹簧钢的晶粒在<001>和<111>取向附近的比例较高,而进口优质弹簧钢在<101>取向上的织构强度偏弱。