石油焦原料性质及炭化工艺对活性炭性能的影响

从分析石油焦原料着手，考察了其热解特性、孔隙率和石墨化程度。由于石油焦结构致密，属易石墨化碳，因此用水蒸气法直接活化得到的炭质材料吸附性能差，其碘吸附值小于350mg/g。不同来源的石油焦由于组成不同，其活化性能也有差异。通过成型法，以金山石油焦为原料轻预炭化、预氧化和炭化，得到炭化料，再用水蒸气活化得到的活性炭的碘吸附值达800.40mg/g、亚甲蓝值达120.40mg/g。以独山子石油焦为主要原料制得的活性炭的碘吸附值与亚甲蓝值分别达871．58mg/g、100..67mg/g。     

Kinetic Studies on Cocracking of Petroleum Vacuum Residue with Thermoplastics and Biomass (Petrocrop)

Cracking of petroleum vacuum residue (XVR) and its cocracking with plastics (PP or PS), Calotropis procera (CL) as a binary, ternary, and quaternary mixture of these individual plastics, and CL with XVR was carried out in a Perkin-Elmer thermogravimetric analyzer (TGA) for the purpose of comparing the process of the mixture with those of the individual components. Experiments were conducted at a heating rate of 40 K/min, in the temperature range of 30-900°C. Based on the results obtained, three temperature regimes were selected for studying the nonisothermal kinetics of TGA of individual XVR, plastics, and biomass as well as of the cocracking of these with XVR, i.e., below 400°C, between 400-500°C, and above 500°C. The kinetic studies were performed using the Coats and Redfern kinetic modeling equation. The overall activation energies obtained were 25 kJ/mole for petroleum vacuum residue, 99 kJ/mole for polypropylene, 21 kJ/mole for coal, and 35 kJ/mole for the mixture of all these materials. Thus, it has been found that there exists an overall synergy when three materials were coprocessed together. The overall orders and activation energies change during coprocessing of two or three different macromolecules, including mixed vacuum residue as presently observed. The detailed results that were obtained will be reported.     

长输管道建设物流管理新模式——物资配送

长输管道工程是以线路管道与沿途站场为主要内容的建设工程,其物资配送有着不同于一般物流管理的特点,点多线长,且交通不便.文章结合西南成品油管道建设工程的物资配送实践,总结出长输管道物资配送的类型,并从机构设置、计划编制、台账和报表管理等方面介绍了物资配送的管理内容及经验,实践证明,这种物资配送方法不但使业主的物资管理人员大为减少,而且使长输管道工程的物资供应更加及时有序.     

Estimation of the Substrate Concentration Profiles in Petroleum Pipelines Containing Biofilms

In industrial systems, the formation of biofilms can cause many problems, such as an increase in the flow resistance of pipelines, energy losses in fluid transport and heat exchangers, product contamination, materials deterioration, and biocorrosion. As a result, biofilms contribute substantially to economic losses in the industry. Corrosion is particularly an issue in the petroleum industry and its implications range from down-hole completion through petroleum processing units. Much of this corrosion is attributed to microbial activities. This paper proposes a mathematical model for predicting substrate concentration for such microbial growth. Substrate concentrations in the system and near the biofilm surface are one of the parameters that has a great effect in determining the extent of the problems associated with biofilms. In this study, a convective-diffusion model under various flow conditions (stagnant, laminar, and turbulent) has been solved using the finite difference technique, employing the alternating direction implicit (ADI) method. The model assumes that a liquid containing substrate and bacteria is flowing in a pipeline with known concentrations at the inlet and then predicts the variation of the transient (as a function of time) substrate concentration along the pipeline and as a function of the pipe radius. The model is then used to predict and estimate the substrate concentration profiles on the biofilm surface under different environmental conditions. A parametric study was also conducted to study the effect of the different parameters influencing the substrate concentration profiles in the system and on the biofilm surface.     

DT型粉状炸药专用蜡的研制

以多种含蜡馏分为基础原料，添加适量DT复合添加剂研制的DT型粉状炸药专用蜡具有优异的分散性和抗水性，可满足各种低梯粉状炸药要求，简化炸药配方，方便操作及其质量控制，以其生产的炸药爆速高，贮存期长，各项性能满足GB12437－2000标准要求。     

修井作业中的自动起下管柱系统探讨

目前在油田修井作业中起下管柱的人工作业量大、工作效率低、危险性大、工作条件差。提出了一种自动起下管柱作业系统,主要包括通井机、井架、液压钳、筒式吊卡、卡瓦支座、立式排管架和控制系统等,支座卡瓦为弹性体微条嵌入式结构,筒式吊卡能自动卡入和松开管柱接箍,排管架可实现管柱的立式排放,控制系统协调各部分的工作。该系统构思新颖,结构简单,技术可行,并能够与现有修井设备配合使用,实现油田修井作业的自动化。     

输气干线单个分输站站址最优化研究

输气干线分输站站址规划设计合理与否，直接影响到分输站至各城市门站之间输气管线总投资和未来管网系统的发展。为此,着重讨论并建立了以分输站站址、各城市门站与分输站之间管道直径、壁厚、分输站压力为设计变量，以各城市门站与分输站之间管道投资最小为目标函数的分输站站址优化数学模型。根据模型特点，采用混合离散变量复合形法与数据库技术相结合来求解分输站站址。以此站址为参考点，结合现场勘察，在参考点附近沿输气干线预选多个分输站站址，并对影响分输站建设和管理的环境因素用多目标模糊评价方法进行综合评价，以评价效果好的站址为最优分输站站址。用算例说明了分输站站址优化结果不仅与工艺参数变化有关，且与分输站所处环境因素有关。提出还应深入研究输气干线中具有多个分输站的站址优化问题。     

炼油厂废水的最小化

石油炼厂作为用水大户，在水资源逐渐短缺、环境污染日益严重的情况下，实施废水最小化改造具有重要的现实意义。笔者以石油炼厂整个水分配系统年度费用最小为目标函数，提出采用回用、再生回用和再生循环3种措施减少新鲜水用量和废水排放量。利用超结构建模求解所得优化的水分配系统不但要满足各用水过程的需求，而且使排放的废水达标。给出的实例证明，所提出的方法更全面地考虑了废水最小化的机会，且所得结果可行、有效。     

炼油化工装置技术改造的决策与实施

针对炼油和石化工业装置技术改造的特点，系统地总结了技术改造的类型和改造方案的制定、决策及实施的原则、程序和方法，指出对炼化装置实施技术改造是一项极其复杂、极具难度的系统工程，必须结合实际情况，以投资回报最大化为原则，通过深入细致地研究和反复比选优化改造方案，并结合现场情况制定切实、可靠、安全的实施方案。     

我国管道业发展对板带业的拉动

本文叙述了我国管道业面临的市场机遇和受到天然气价格等因素的制约以及进口钢管的挑战。建议中国管道业应适当发展ERW610机组和UOE机组的高质量产品；在钢板上宜以X70级为主，设备潜力可向X80级为目标而努力。