Assessment of different techniques for quantification of α-Al(FeMn)Si and β-AlFeSi intermetallics in AA 6xxx alloys

During homogenisation of AA 6xxx aluminium alloys, the platelike β-AlFeSi intermetallic phase will transform to a less Si-rich and more spheroidised α-Al(FeMn)Si phase which is more favourable for extrusion. In this study, several quantitative methods, which determine the relative volume fraction of α-Al(FeMn)Si and β-AlFeSi, are compared and an assessment of each method is made. The methods used are optical microscopy, scanning electron microscopy (SEM) in combination with electron dispersive X-ray (EDX) using polished samples, and X-ray diffraction (XRD) on intermetallics, extracted through selective dissolution of the Al matrix. The highest accuracy is obtained by using SEM/EDX analysis and applying two criteria.     

X射线衍射线形Fourier变换

采用计算机辅助实验技术，研究X射线衍射线开在仪器宽化修正过程中Fourier系数变化的规律及其影响，结果表明，只要实测线形接近Gauss 分布，Fourier变换就会导致弯勾效应；Forier变换可引起真实线形的尾部波动及大于实际值的宽化，引入边界条件可予以消除，Kα双线形经过Fourier变换后，Fourier纱数与真实Fourier系数存在着一定的差异。通过真实线形的Fourier变换可以修正。     

Oxidation of porous nanocrystalline titanium nitride. II. Scale structure and composition

We have used x-ray phase analysis to study the composition of the products of reaction between oxygen and nanocrystalline powders with particle sizes 15, 40, 55, and 80 nm, and also specimens pressed (and sintered) from them. The powders were oxidized in air at 100°C (400 h) to 500°C (5 min), while the sintered specimens were oxidized at 600–900°C for 15, 120, and 240 min. In all cases, in the initial oxidation step the oxynitride Ti(O_xN_y) is formed, which over time is oxidized to TiO, Ti₂O₃, Ti₃O₅, TiO₂ (anatase) and TiO₂ (rutile). In the range 600–800°C, formation of a continuous oxide layer and conversion of anatase to rutile slows down diffusion of oxygen in the scale. We have established that at 900°C, the growth rate of the scale thickness increases and so the reflections from the oxynitride are barely noticeable on the diffraction patterns taken from the surface of the oxidized specimen. In these diffraction patterns, along with strong reflections from the rutile, we also observed weak reflections from lower oxides and anatase, which may be due to reaction between oxygen and the titanium ions diffused to the scale surface. We have concluded that at T > 850°C, the mechanism for oxidation of TiN changes. This is due to superposition of counterdiffusion of titanium ions on the diffusion of oxygen. __________ Translated from Poroshkovaya Metallurgiya, Nos. 3–4(448), pp. 72–78, March–April, 2006.     

同杆并架双回线基于电流突变量的综合选相

相电流差突变量选相元件在单回线故障中具有良好的选相性能，但在同杆双回线跨线故障中可能误选相。利用六序故障分量的分析方法，分析了相电流突变量在同杆双回线跨线故障中的幅值和相位特征，给出了其相位比相方程。在此基础上，提出了一种运用测量阻抗和方向元件相结合的综合选相方法，并给出了选相流程图。仿真结果表明，在双回线简单故障和跨线故障时，基于单回线单端电气量的同杆并架双回线综合选相方法具有较理想的选相性能。     

小型水电站计算机监控系统的设计与设备选择

在对一些小型水电站的考察与调研的基础上，对小型水电站计算机监控系统实施现状和普遍存在的问题进行了分析，并提出了解决的方法。建议小型水电站监控系统的设计要强调简单可靠和实用的原则，采用性价比高的实用新技术。可供有关专业人员参考。     

Phase equilibria in the system Al-Rh

Methods of differential thermal analysis, x-ray diffraction, microstructural analysis and electron probe microanalysis are used to study alloys of the Al-Rh system over the whole concentration range. It is established that the phase of equiatomic composition AlRh melts congruently at 2060°C and it has an extended range of homogeneity (45.1–54.2 at.% Rh). The solubility of aluminum in rhodium reaches 9 at.%, decreasing to 6 at.% at 850°C. Coordinates are determined for the eutectic point l ⇆ AlRh + 〈Rh〉 as 70 at.% Rh and 1715°C. The existence of intermediate phases, their crystal structure, and also the method of forming phases in the field of composition rich in aluminum given in publications are confirmed. __________ Translated from Poroshkovaya Metallurgiya, Nos. 5–6(449), pp. 48–56, May–June, 2006.     

离心式空压机轴承技术改造

针对离心式空压机各级轴振动值超标的现象进行技术攻关,解决了制约装置安全平稳生产的瓶颈问题。     

两相电流互感器配电网零序电流构造方法

中性点非直接接地配电网大多只安装A，C两相电流互感器（TA），而现有单相接地故障选线方法基本都以零序电流为基础实现。如何在两相TA配电网中准确检测并隔离接地故障线路，成为长期困扰实际运行的技术难题。通过对暂态电流的频域和时域分析，找出B相暂态电流与A，C相暂态电流的对应关系，提出在A相和C相接地时由A相和C相暂态电流构造B相暂态电流，进而得到较精确零序电流的方法。通过大量仿真实验验证了所提出的构造方法的正确性。零序电流的成功构造为实现两相TA配电网单相接地故障选线提供了基础。     

Effect of pH on the Crystallization of Homogeneously Precipitated Nanosized PZT Powder

Nanosized lead zirconate titanate (PZT) powder with Zr:Ti ratio in the morphotropic phase boundary region was synthesized by homogeneous precipitation of metal ions. The powder precipitated at 90°C and at pH 6.7 resulted single-phase perovskite lead zirconate titanate powder when calcined at 550°C and above for 4 hours in air. The solution pH and the precipitation temperature strongly affect the composition of the calcined powder. The results obtained by structural characterization of homogeneously precipitated powder were compared with that obtained from the conventional precipitation method using ammonia in terms of crystallization, homogeneity, and microstructure. The homogeneously precipitated powder showed smaller particle size, minimum agglomeration and uniform shape on calcination and annealing. Powdered samples that precipitated by homogeneous precipitation crystallized directly to perovskite PZT, without any intermediate pyrochlore phase formation. In contrast, the NH₃ precipitated powder converted to perovskite PZT via metastable pyrochlore and it showed phase segregation upon annealing at higher temperatures. The reaction kinetics has been studied by X-ray diffraction, differential thermal analysis, and differential scanning calorimetry.     

（Ba1-xSrx）（Zn1/3Nb2/3）O3微波介质陶瓷温度系数的异常

研究了（Ba1-xSrx）（Zn1/3Nb2/3）O3微波介质陶瓷温度系数的非线性变化以及异常的原因。根据CM公式，随着系统中Sr（Zn1/3Nb2/3）O3的增多，τc的异常是由于氧八面体的畸变导致的相转变（对称性降低）所造成的（晶体结构由无序立方相向有序赝立方相的连续变化）。相转变的发生相应影响了极化以及极化模式，这是造成τc异常的根本原因。