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Tri(acryloyloxyethyl) phosphate (TAEP) was blended in different ratios with epoxy acrylate EB600 and polyurethane acrylate EB270 to obtain a series of UV curable flame retardant resins. The thermal degradation mechanisms of their cured films in air were studied by thermogravimetric analysis, in situ Fourier‐transform infrared spectroscopy, and direct pyrolysis/mass spectrometry measurements. The results showed that the phosphate group in TAEP first degraded to form poly(phosphoric acid) before the degradation of EB600. Then, the formed poly(phosphoric acid) effectively promoted the conversion of EB600 to form char, which prevented the sample from further burning. However, urethane group in EB270 degraded simultaneously with phosphate group in TAEP, leading to not effectively increase the conversion of EB270 to char during the thermal degradation. It was thus found that the addition of TAEP more effectively improved the thermal stability, flame retardance, and the char yield during combustion of EB600 than those of EB270. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 99: 3130–3137, 2006 相似文献
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论述近年来云南省硫酸磷肥工业的发展情况及今后的发展方向.到2010年,云南省硫酸产能应控制在12.5 Mt/a左右,约占全国总量的20%;磷肥产能应控制在4.1 Mt/a左右,约占全国总量的25%,其中高浓度磷复肥约占全国总量的35%以上;磷矿产量应控制在20 Mt/a左右,约占全国总量的30%,其中擦洗与浮选磷矿约占70%. 相似文献
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In order to analyse iron phosphate complexes and gel-like phases encountered in the single superphosphate process, experiments were performed with a free-Al, Fe apatite crystal of Durango from Mexico phosphate rock and sulfuric acid. Reaction products were studied by X-ray diffraction and surface analysis methods namely X-ray photoelectron spectroscopy and scanning electron microscopy. Results show that in a free Al, Fe-system, part of the Ca(H2PO4 )2.H2O (MCPM) forms before precipitation of any CaSO4(CS) and gel-like phase such H2SO4.yH3PO4.xH2O is formed. When iron is added, the precipitation rate of (CS) and (MCPM) increases and Fe3(H3O)H8(PO4)6.6H2O is formed. When Fe and Al are added, a gel-like phase is quickly formed with a molar ratio that changes with time and develops into crystalline compounds. The composition of this gel may be represented as a mixture of two phases: H2SO4.yH3PO4.xH2O and a gel containing Al-Fe-Si. 相似文献
57.
锌-锰合金镀层磷化工艺研究 总被引:1,自引:0,他引:1
为进一步提高Zn-M n合金镀层的抗蚀性,采用锌锰系磷化处理Zn-M n合金镀层,研究表明在相同镀层厚度下,Zn-M n合金镀层抗蚀能力是镀锌层的5倍,经磷化后的Zn-M n合金镀层的抗蚀能力是镀锌层的7~8倍。实验结果表明,Zn-M n合金镀层经锌锰系磷化后抗蚀性明显提高。 相似文献
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Ca-P仿生人工骨材料的设计与制备 总被引:2,自引:0,他引:2
本文设计了用磷酸钙生物陶瓷制备仿生人工骨的工艺路线 ,从原料合成、材料成型和烧结等讨论了仿骨材料的制备方法 相似文献
60.
Interaction of inositol phosphate with calcite 总被引:1,自引:0,他引:1
Luisella Celi Sebastiano Lamacchia Elisabetta Barberis 《Nutrient Cycling in Agroecosystems》2000,57(3):271-277
The interaction of myo-inositol hexaphosphate with calcite was studied to evaluate the adsorption mechanisms and the electrochemical modifications induced by interaction of a molecule at such a high-charge density. In addition to quantitative information through the construction of adsorption isotherms, FT-IR and Laser Doppler Velocimetry - Photon Correlation Spectroscopy (LDV-PCS) were employed to investigate the nature of the adsorbent-adsorbate bonds and to determine the electrophoretic mobility and size of the particles before and after sorption. The experiments were also run with orthophosphate (Pi) for comparison. The amount of sorbed P increased to reach a plateau at 17.8 mol m-2 for inositol hexaphosphate (IHP) while for Pi rose 1.4 mol m-2 but at Ce > 610-4
M it had a sharp increase reaching 155 mol m-2. As expected, for Pi, adsorption predominated up Ce 610-4
M by covering about 20% of total surface. The adsorption occurred at sites that behaved as nucleus of formation of the clustering of Ca- and PO4-ions with the ending formation of calcium phosphate precipitates at Ce higher than 610-4
M. The reaction of inositol hexaphosphate with calcite involves, besides adsorption, precipitation of Ca salts and hence calcite dissolution also at the lowest added IHP concentrations, accounting for the large amount retained by calcite. Sorption of IHP on calcite caused aggregation of particles at low concentrations followed by an increase of their negative charge and hence re-dispersion at higher concentrations. These results indicate a great IHP-fixing capacity of calcite that can affect its accumulation in soils and P bioavailability, and a considerable change of calcite electrochemical properties and particle size distribution that can modify aggregate stability. 相似文献