不同牌号丁苯橡胶的耐低温性能研究

研究3种牌号丁苯橡胶(SKMS-10,SL-4525-0,SBR1502)的硫化特性、物理性能和耐低温性能。结果表明:SKMS-10具有优异的耐低温性能,生胶的玻璃化转变温度(T_g)为-73.3℃,硫化胶的T_g为-59.8℃,适于在极寒条件下使用;SL-4525-0胶料的F_max-FL较大,硫化胶的拉伸强度为19.3 MPa,撕裂强度为53 kN·m^-1,T_g为-48.6℃,具有优异的综合性能;SBR1502硫化胶的拉伸强度高达24.9 MPa,撕裂强度为49 kN·m^-1,但T_g为-38.4℃,耐低温性能较差,适用于载荷较大且耐低温性能要求不高的橡胶减振制品。     

3D Printing of Polyvinylidene Fluoride Based Piezoelectric Nanocomposites: An Overview

Recently, polyvinylidene fluoride (PVDF) based nanocomposites have attracted much attention for next-generation wearable applications such as promising piezoelectric energy harvesters (nanogenerators), energy storage devices, sensing devices, and biomedical devices due to their high flexibility, and high dielectric and piezoelectric properties. 3D printing technology, PVDF based piezoelectric nanocomposites, the studies based on 3D printing of PVDF based piezoelectric nanocomposites by inkjet printing and fused deposition modeling, and enhancements of energy harvesting and storage performance of nanocomposites by structural design are comprehensively overviewed here. An insight is provided into 3D printing techniques, structure and properties of PVDF based polymers, various nanofillers and production methods for nanocomposites, solutions to enhance β phase (crystallinity) of PVDF, and improvements of nanocomposites’ breakdown strength, discharged energy density, and piezoelectric power output by mentoring structural design.     

Synergistic Effect of PVDF-Coated PCL-TCP Scaffolds and Pulsed Electromagnetic Field on Osteogenesis

Bone exhibits piezoelectric properties. Thus, electrical stimulations such as pulsed electromagnetic fields (PEMFs) and stimuli-responsive piezoelectric properties of scaffolds have been investigated separately to evaluate their efficacy in supporting osteogenesis. However, current understanding of cells responding under the combined influence of PEMF and piezoelectric properties in scaffolds is still lacking. Therefore, in this study, we fabricated piezoelectric scaffolds by functionalization of polycaprolactone-tricalcium phosphate (PCL-TCP) films with a polyvinylidene fluoride (PVDF) coating that is self-polarized by a modified breath-figure technique. The osteoinductive properties of these PVDF-coated PCL-TCP films on MC3T3-E1 cells were studied under the stimulation of PEMF. Piezoelectric and ferroelectric characterization demonstrated that scaffolds with piezoelectric coefficient d₃₃ = −1.2 pC/N were obtained at a powder dissolution temperature of 100 °C and coating relative humidity (RH) of 56%. DNA quantification showed that cell proliferation was significantly enhanced by PEMF as low as 0.6 mT and 50 Hz. Hydroxyapatite staining showed that cell mineralization was significantly enhanced by incorporation of PVDF coating. Gene expression study showed that the combination of PEMF and PVDF coating promoted late osteogenic gene expression marker most significantly. Collectively, our results suggest that the synergistic effects of PEMF and piezoelectric scaffolds on osteogenesis provide a promising alternative strategy for electrically augmented osteoinduction. The piezoelectric response of PVDF by PEMF, which could provide mechanical strain, is particularly interesting as it could deliver local mechanical stimulation to osteogenic cells using PEMF.     

掺杂对PZT压电陶瓷的影响及研究进展

在介绍掺杂PZT压电陶瓷材料制备的基础上,总结出生产掺杂PZT材料的最佳掺杂条件,以及配方对压电陶瓷性能的影响,只要工艺合适,性能完全能再提高,对压电陶瓷材料的发展趋势进行了展望。     

含储能型虚拟同步发电机的直驱风机并网系统自适应协调阻尼控制策略

储能型虚拟同步发电机(VSG)的灵活控制特性能够为风电并网系统提供有效的频率和电压支撑,然而系统振荡特性会受到一定程度的影响,同时风电时变出力特性导致的运行点变化也将使得定参数阻尼控制表现出适应性不足的问题.为此,提出了适应风电出力时变特性的自适应协调阻尼控制策略.首先,在风电并网系统状态空间模型的基础上推导线性变参数模型,以直驱风机的有功功率为调度变量,根据稳定域确定运行空间范围;然后,利用间隙度量对运行空间进行划分,确定各子运行空间的典型运行点并将其作为多胞形顶点,建立调度增益与系统运行工况以及控制器的映射关系;最后,针对不同频率振荡模式协调设计自适应控制器.测试系统的仿真结果表明,所设计的自适应协调阻尼控制器不仅能够同时阻尼含储能型VSG并网系统中的次同步振荡和低频振荡,也能在风电出力大范围时变工况下保持良好的阻尼水平.     

Effects of CeO2 doping on the structure and properties of PSN-PZN-PMS-PZT piezoelectric ceramics

Quinary system piezoelectric ceramics PSN-PZN-PMS-PZT were prepared by using a two-step method. The effects of CeO2 doping on piezoelectric and dielectric properties of the system were investigated at morphotropic phase boundary （MPB）. The results reveal that the relative dielectric constant ε33^T｜ε0, the Curie temperature To, the piezoelectric constant d33, the mechanical quality factor Qm, and the electromechanical coupling coefficient Kp are changed with the increase of CeO2 content. On the other hand, the effects of CeO2 doping on the dielectric properties of PSN-PZN-PMS-PZT piezoelectric ceramics at high electric field are consistent with the change at weak electric field. The values of dielectric constant and dielectric loss are enhanced with the increasing of electric field.     

热处理和锰含量对CuZnAl合金微观组织结构和宏观性能的影响

采用万能试验机、金相显微镜、扫描电子显微镜以及动态热机械分析仪,研究了时效时间以及Mn元素对CuZnAl合金微观组织结构、力学及阻尼性能的影响。结果表明:Mn元素可以改善材料微观组织结构,提高合金的阻尼性能和拉伸强度;微观组织结构中的针状马氏体和块状马氏体随时效热处理时间的增长发生显著变化,并由此影响材料的阻尼性能;阻尼性能与针状马氏体的长度和密度呈正相关,而与块状马氏体的数量呈负相关,但Mn含量过高时,例如达到10%,出现粗大的块状组织,合金力学性能会有明显下降。     

ZA27-4%Si合金的阻尼性能及阻尼机理

利用低频内耗测试技术研究了ZA27-4%Si合金的阻尼性能, 分析了合金的阻尼机理. 结果表明 ZA27-4%Si合金阻尼随频率增大而减小, 随温度升高而增大, 阻尼不随应变振幅的变化而变化ZA27-4%Si合金室温阻尼为5.83×10-3, 与ZA27合金阻尼相当ZA27-4%Si合金的阻尼是由合金内部的晶界和相界面滑动、位错振动以及各相的热膨胀系数和弹性模量间差造成的微塑性变形共同造成的. 硅合金化的ZA27合金具有良好耐磨减摩性能和减振性能.     

纳米粉及添加剂对压电陶瓷材料性能的影响

采用高能球磨法研磨出PZT-5纳米粉料，添加外购的纳米有机添加剂，按照传统的固相工艺法制备出了压电陶瓷材料，研究分析纳米粉料和纳米有机添加剂对压电陶瓷性能的影响。通过测试分析可以看出，纳米压电粉料与纳米有机添加剂的综合作用，降低了材料的烧结温度、相对介电常数εr,Qm值和以d31，提高了压电应变常数d333，从而压电电压常数g33、gh、dh成倍提高，这些对制作宽带、高灵敏度的换能器是很有好处的。     

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 传感器采用的28 μm厚的4层结构PVDF压电薄膜制成，传感器表面电极形状的制作采用剪切加丙酮腐蚀的方法，保证了传感器有一定的非金属化的边缘。对于电极的引出是将传感器上、下电极面引脚错开，引出电极比较容易做到穿透式，采用压接端子压接和空心小铆钉铆接两种方法。