新型含能增塑剂——硝氧乙基硝胺族化合物发展概况

回顾了硝氧乙基硝胺族（ＮＥＮＡｓ）化合物的发展过程，概述了含ＮＥＮＡｓ火炸药的主要性能及其可能的应用和该化合物的发展现状。文中介绍了１７篇参考文献。     

几种增塑剂对大豆蛋白质塑料拉伸性能的影响研究

采用了增塑剂聚乙二醇300,聚乙二醇400,聚乙二醇600及己内酰胺,对大豆蛋白质进行增塑,并测试了增塑后的大豆蛋白材料的拉伸性能,得到了这些塑增剂在增塑蛋白质中的最佳含量。     

邻苯二甲酸酯类增塑剂检测技术研究进展

着重介绍近年来邻苯二甲酸酯类化合物检测技术的研究进展,主要从前处理技术和检测方法两个方面进行归纳和总结,并对存在的问题及前景进行了探讨和展望。     

Synthesis and evaluation of dioctyl 2,5-thiophenedicarboxylate as a potentially bio-based plasticizer for poly(vinyl chloride)

In this work, dioctyl 2,5-thiophenedicarboxylate (DOT), a potentially bio-based plasticizer, was synthesized and evaluated as an alternative to traditional petroleum-based plasticizers. The chemical structure of DOT was confirmed by FTIR and ¹H NMR. Besides, its plasticization effect on poly(vinyl chloride) (PVC) was investigated in detail, and dioctyl 2,5-furandicarboxylate (DOF) as well as dioctyl isophthalate (DOIP) with similar chemical structures were used as references. The DMA results showed that the glass transition temperature (T_g) of PVC/DOT, PVC/DOF, and PVC/DOIP was 45.1°C, 33.6°C, and 51.3°C, respectively, indicating that the plasticizing efficiency of DOT was better than that of DOIP but lower than that of DOF. However, the tensile test results exhibited that the elongation at the break of PVC/DOT was higher than that of PVC/DOF, which was attributed to the easy phase separation between DOF and PVC. In addition, DOT displayed the best volatility resistance and exudation resistance among the three plasticizers, attributed to its highest molecular weight. Moreover, the migration loss of DOT in non-polar solvents was much smaller than that of DOIP because of its stronger molecular polarity. In conclusion, DOT has good potential to replace traditional petroleum-based plasticizers and be used as a primary plasticizer for PVC.     

环氧植物油基增塑剂的发展状况

介绍了无毒、环保型增塑剂环氧植物油的制备原理、方法,以及环氧化过程中的影响因素如反应时间、有机酸和氧化剂的配比、反应温度、双氧水浓度等。简述了国内植物油的环氧化工艺的发展状况,重点讨论了国外先进的植物油环氧化催化工艺。     

环烷基减四线馏分油加氢精制-糠醛萃取制备环保橡胶增塑剂的研究

以SZ36-1环烷基减四线馏分油为原料,考察加氢精制-糠醛单段萃取以及加氢精制-糠醛两段萃取两种组合工艺制备高芳烃含量环保橡胶增塑剂的技术可行性.结果表明:采用两种组合工艺均可以制得满足国家标准指标要求的橡胶增塑剂产品,加氢精制-糠醛单段萃取可以制得环保橡胶增塑剂A1220产品,在产品收率上更具优势;加氢精制-糠醛两段...     

聚氯乙烯环保型增塑剂的合成及应用

聚氯乙烯中常用的环保型增塑剂主要有柠檬酸酯类增塑剂、对苯二甲酸酯类增塑剂、聚酯类增塑剂、偏苯三酸酯增塑剂、环己烷二羧酸酯类增塑剂、植物油基增塑剂等,通过了解和分析这些增塑剂的特征和合成,推进环保型增塑剂在塑料生产中的应用.     

新型增塑剂DPHP的应用性能评述

介绍了增塑剂DOP的替代产品邻苯二甲酸二(2-丙基庚)酯(DPHP)的物性、力学性能、加工性、电性能、耐候性等应用性能,并提出国内发展DPHP的建议。     

偏苯三酸酐的国内外市场分析

目前世界偏苯三酸酐的总生产能力约为 2 3 0万t/a ,产量约为 16 5万t/a ,消费量约为 16 0万t/a。2 0 0 3年 ,我国偏苯三酸酐的生产能力约为 4 1万t/a,产量约为 1 6万t,消费量约为 1 35万t。在我国 ,偏苯三酸酐主要用于生产粉末涂料及树脂固化剂、偏苯三酸酯类增塑剂、聚酰亚胺绝缘漆以及改性醇酸树脂等 ,另外有少量用于电影胶片絮凝剂、飞机发动机润滑油以及偏苯酸酯钠盐阴离子表面活性剂等。预计 2 0 0 5年我国偏苯三酸酐的消费量将达到约 1 75万t。     

PVC塑料增塑剂邻苯二甲酸酯类的应用研究

本文介绍了聚氯乙烯的增塑机理,常用增塑剂的种类及其应用现状。重点介绍了邻苯二甲酸二辛酯和邻苯二甲酸二丁酯的合成工艺和催化剂的选择,并展望了邻苯二甲酸二辛酯和邻苯二甲酸二丁酯的合成发展。