我国塑料助剂生产现状与发展趋势

简述了我国塑料助剂生产现状、市场供需及发展方向，“十五”期间我国塑料助剂工业发展势头强劲，目前已基本满足我国塑料工业的发展需求，但是在品种和产品质量等方面与国外先进水平相比仍有较大的差距。提出了提高我国塑料助剂国际市场竞争力的措施。     

木塑复合材料制品一步法挤出成型技术的研究

介绍了木塑复合材料制品一步法挤出成型中常见的5种挤出设备,提出了选择这些设备时需要考虑的一些因素,分析了木塑复合制品挤出成型技术中温度、压力、喂料和排气等问题产生的原因。并结合实验和理论,从螺杆、机筒、机头设计和加料器选择等方面提出了解决这些问题的措施。     

微孔塑料成型过程中影响聚合物／气体均相体系形成的工艺因素

综述了微孔塑料成型过程中聚合物/气体均相体系形成的影响因素。表征均相体系的重要参数是气体在聚合物中的溶解度，因此通过SEM、玻璃化转变温度法、粘度法等间接方法来衡量溶解度，可以间接表征均相体系。对影响均相体系形成的压力、温度、时间和剪切作用等工艺条件进行了分析。适当增加压力、升高温度有利于均相体系的形成.剪切作用可提高气体的扩散性和溶解性，同时还可大大缩短均相体系形成所需要的时间。     

聚苯乙烯纳米塑料研究进展

介绍了聚苯乙烯纳米塑料的制备方法，对聚苯乙烯纳米塑料的研究进展进行了综述。     

加入WTO后的中国塑机制造业

中国塑机的发展经过3个历史阶段,中国已成为塑机生产与消费的大国,中国塑机的制造业已成为中国现代制造业中的一支新军.加入WTO后标志着中国经济已融入全球经济,也意味着中国加入全球的经济竞争.在这场竞争中,中国塑机企业将面临着历史机遇和挑战.     

塑料注射成型新工艺

简要介绍了气体（水）辅助注射、模具滑动注射、熔芯注射、受控低压注射、注射－压缩、剪切控制取向注射、推－拉注射、层状注射、微孔发泡注射等注塑料工艺的原理，特点及应用前景，说明塑料注射成型工艺的发展趋势主要以节能，节约原材料，提高成型效率，改进制品性能，提高其附加值为前提。     

Preparation and characterization of modified starch‐based plastic film reinforced with short pulp fiber. II. Mechanical properties

Native corn starch‐ and hydroxypropylated starch (HPS‐) based plastic films were prepared using the short pulp fiber as the reinforcement and the glycerol as the plasticizer. The results of tensile test showed that the strain and stress at break and elastic modulus increased with pulp content. With glycerol content, the strain at break increased considerably, but the breaking stress and elastic modulus decreased. And the stress–strain curves showed that the brittleness problem of films was overcome by the pulp, glycerol, and water content. The hydroxypropyl starch films showed results similar to those of the native starch films. The results of the three‐point bending test showed that maximum deflection, flexural strength, and specific work increased with pulp content, but the flexural modulus was the highest at a pulp content of 20%. And with the glycerol content, the maximum deflection and specific work of rupture increased, but the bending elastic modulus decreased. The hydroxypropyl starch films showed results similar to those of native starch films as far as the maximum deflection and flexural strength were concerned, but the bending elastic modulus and specific work of the hydroxypropyl starch films were considerably lower than those of starch films. So it was concluded that the flexibility of films was improved by the hydroxypropylation. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 2108–2117, 2003     

Nanoparticle induced network self-assembly in polymer-carbon black composites

A novel percolation phenomenon with inorganic nanoparticle loading in polyamide 6-carbon based nanoparticle hybrids was identified. Percolation threshold substantially shifts to lower carbon black (CB) volume fractions in the presence of optimum concentration of chemically modified montmorillonite (organoclay) while the effective organoclay concentration can be optimized to lower the slope of percolation curve maintaining electrical conductivity within static dissipative 10⁻⁶-10⁻⁹ S cm⁻¹ range. Organoclay/CB ‘nano-unit’ morphology was found in polyamide 6 ternary hybrids. It is composed of stacked organo-montmorillonite platelets that deform to wrap partially around one or two primary CB aggregates. This elementary nano-unit structure induces CB network self-assembly within polyamide 6 matrices. The structure was found to be prevalent throughout the polymer matrix. This morphology remains robust under wide range of thermal-deformation histories due to the strong preferred organoclay/polyamide 6/CB interactions that partially blocks the electron conduction and hopping mechanisms with clay ‘walls’ thereby reducing the slope of the percolation curve. Organoclay can be used as a dispersion control agent in these polymer-carbon systems to induce self-assembly of CB network at low CB content, simultaneously, partial blocking the electron hopping pathways to level the slope of percolation curves. High order exfoliation and nano-scale dispersion of organoclay is essential to induce this advanced percolation phenomenon.     

4,4′,4′′–三膦酸甲酯三苯胺的合成及应用

以三苯胺为原料，通过亲电取代反应制备得到中间体4,4′,4′′–三碘代三苯胺（TITPA），该中间体与亚磷酸三甲酯在Pd(PPh3)2Cl2催化下经Arbuzov重排得到目标产物4,4′,4′′–三膦酸甲酯三苯胺（TPTPA）。通过1HNMR、13CNMR、31PNMR、高分辨质谱和元素分析对目标产物进行了结构表征，并考察了催化剂种类与用量、反应温度、反应时间对目标化合物产率的影响。结果表明，最佳合成条件为： n（Pd(PPh3)2Cl2）∶n（TITPA）= 0.18∶1.00，反应温度150℃，反应时间5h。在该条件下，目标产物TPTPA的收率可达82.5%。接着，TITPA用于PVC的阻燃改性。结果表明，当TPTPA添加量为10%（以PVC树脂的质量为基准，下同），样品的极限氧指数可达29.6%、UL94垂直燃烧达V-0级，且力学性能保持良好。。     

复合型导电塑料的研究进展

介绍了复合型导电塑料的种类。特性与应用，讨论了它们的导电机理及影响导电性的因素。着重全叙述了国内外对添加抗静电剂、导电填料以及共混复合型导电塑料的研究现状与发展趋势。