基于溶剂极性的双环戊二烯氢甲酰化反应探索研究

以三苯基膦改性的铁磁性氧化物担载的钴铑双金属为催化剂,考察了不同极性溶剂对双环戊二烯（DCPD）氢甲酰化反应合成三环癸烷不饱和单醛和三环癸烷二甲醛的影响。结果表明,溶剂的极性对反应速率和目标产物的选择性有较大的影响,三环癸烷不饱和单醛的生成速率随着溶剂极性的增加呈现增加的趋势;三环癸烷二甲醛的反应速率和选择性随着溶剂极性的增加先增加后降低。以极性值为5.4的丙酮作为溶剂时,合成三环癸烷二甲醛最佳,选择性达到了72%。     

对地震资料应用中几个常见问题的思考

地震技术在石油工业中已得到越来越广泛的应用。在地震资料的应用过程中,地质学家和地球物理学家经常会有相左的观点,不同的石油科技工作者对一些地震技术概念和方法也存在着不同程度的模糊认识,比如地震分辨率与构造成图精度、综合速度与速度的横向非均质性、波峰(波谷)与砂层的关系以及合成记录的制作和标定等问题,都影响了地震研究的深度和水平。本文力图用通俗的语言,站在应用的角度,从理论上对一些概念和技术进行探讨和澄清。     

铍材料精密电火花加工工艺研究

针对铍材料机械加工性能较差的缺点,进行了电火花精密加工工艺的探索;通过负极性和以较低放电能量的加工方式,突破了机械加工极限,得到了厚度为0.05mm左右的铍薄膜。     

镁合金变极性等离子弧焊接头的微观组织分析

采用变极性等离子弧焊接实现了AZ31B变形镁合金板材的优质连接,焊后利用光学显微镜、电子探针 (EPMA)和X射线衍射(XRD)仪对焊接接头的微观组织、元素分布以及相组成进行了分析。结果表明,镁合金变极性等离子弧焊接头中没有明显的热影响区存在,接头成形好,焊缝组织均匀,晶粒细小;接头中主要的合金元素 Al、Zn在焊缝中分布均匀,没有发现区域偏析;接头中没有发现明显的Mg17Al12或其他杂质相的存在;由于焊接过程中存在着镁的蒸发、烧损,导致接头硬度值在沿焊缝的横向和纵向两个方向上都稍有变化。变极性等离子弧焊方法能够改善镁合金焊接接头组织并提高接头的性能,是一种理想的提高镁合金焊接质量的方法。     

基于整体退火遗传算法的低功耗极性转换

针对n变量逻辑函数在不同极性下所对应REED-MULLER(RM)电路功耗和面积不问的特点,对信号几率传递算法、多输入XOR/AND(异或/与)门的低功耗分解算法和多成份极性转换算法进行了深入研究,成功地将整体退火遗传算法(whole annealing genetic algorithm,WAGA)应用于RM电路最佳极件的搜索.通过对8个MCNC Benchmark测试表明,算法搜索到的最佳极性,其所对应RM电路的SYNOPSYS综合结果,与极性0时相比,功耗、面积和最大延时的平均节省分别达到了77.2%,62.4%和9.2%.     

Optimal interval of periodic polarity reversal under automated control for maximizing hydrogen production in microbial electrolysis cells

Microbial electrolysis cells (MECs) are a promising approach for producing hydrogen gas from low-grade substrates with low energy consumption. However, pH increase in a cathode due to proton reduction and thus the need for buffering this pH increase remains a challenge for MEC operation. In this study, a previously reported operational strategy for pH buffer - periodic polarity reversal (PPR) was further studied by developing and applying an automatically control system. The effect of PPR interval on the hydrogen production was investigated and the optimal PPR interval was determined. With an optimal PPR interval of 40 min, the MEC had a significantly low pH increase rate of 0.0085 min^?1 in its cathodes, and this resulted in the highest current density of 1.58 ± 0.02 A m^?2, Coulombic efficiency of 130.3 ± 1.8%, hydrogen production rate of 1.65 ± 0.01 m³ H₂ m^?3d^?1, overall hydrogen recovery of 75.9 ± 0.4%, and energy efficiency relative to the substrate input of 140.8 ± 1.4%. Further analysis suggested that this optimal value of PPR interval was affected by both reaction time and hydrogen supply. When the PPR interval increased from 10 min to 40 min, a longer reaction time helped produce more protons and thus generated a stronger buffer capacity. Beyond 40 min, the mass transfer of the dissolved hydrogen gas could become a limiting factor, leading to a weaker buffer capacity with a longer PPR interval. Those findings have provided an effective pH control strategy with a convenient control system for maximizing hydrogen production in MECs.     

微机型主变差动保护调试中若干问题的探讨

差动保护是变压器运行中的关键保护，目前实际应用中大多数为微机型，重点讨论了几套不同装置的理论归算原理，并结合现场调试情况，介绍了一些装置的特点及调试时应注意的事项。     

应用射影变换解决透视反求问题

本文应用射影变换中正交配极对应原理,为解决透视反求问题提出了简便的作图方法。     

Polarity correspondence: A general principle for performance of speeded binary classification tasks.

Differences in performance with various stimulus-response mappings are among the most prevalent findings for binary choice reaction tasks. The authors show that perceptual or conceptual similarity is not necessary to obtain mapping effects; a type of structural similarity is sufficient. Specifically, stimulus and response alternatives are coded as positive and negative polarity along several dimensions, and polarity correspondence is sufficient to produce mapping effects. The authors make the case for this polarity correspondence principle using the literature on word-picture verification and then provide evidence that polarity correspondence is a determinant of mapping effects in orthogonal stimulus-response compatibility, numerical judgment, and implicit association tasks. The authors conclude by discussing implications of this principle for interpretation of results from binary choice tasks and future model development. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

负反馈放大器反馈类型及其判断

电子电路中,负反馈现象普遍存在,负反馈是模拟电子技术中的一个重要知识点,也是难以掌握的知识点.对反馈概念、反馈极性、反馈类型进行了讨论,归纳了反馈极性与反馈类型在分立元件电路和集成电路中的判断方法.