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51.
Polypyrrole coatings were formed on stainless steel working electrodes in aqueous oxalic acid solution. The rate of formation of polypyrrole coatings on stainless steel increased proportionately with the current density but increased slightly with increased pyrrole concentration. Increasing oxalic acid concentration also had no significant change in the polymerization rate. The electropolymerization potential of pyrrole decreased significantly from 1.5 to 0.8 V versus SCE when the working electrode was polished. The polymerization potential, Ep, of pyrrole, increased however, with increased current density and decreased exponentially with the initial monomer and electrolyte concentration, respectively. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 66: 2433–2440, 1997 相似文献
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53.
Tailoring of conjugated monomers via copolymerization is a facile method to obtain tunable spectral, morphological and optical properties. To investigate the effect of copolymerization of pyrrole with o-phenylenediamine on the optoelectronic properties of the synthesized copolymers, the present work reports the synthesis of copolymers of o-phenylenediamine with pyrrole with varying mol ratios via chemical polymerization in methylene blue (MB) medium. Copolymerization was confirmed by Fourier transform infrared spectroscopy and ultraviolet-visible studies. Ultraviolet-visible spectroscopy revealed variation in the optical properties with the change in the monomer ratio. Fluorescence studies showed that the copolymer containing 80% poly(o-phenylenediamine) revealed highest quantum yield among all the copolymers. The emission color could therefore be tuned by careful selection of narrow band co-monomers, which could help in designing tunable fluorescence emitting materials for potential application in OLED devices. 相似文献
54.
Harry G. Sherman Jacqueline M. Hicks Akhil Jain Jeremy J. Titman Prof. Cameron Alexander Snow Stolnik Frankie J. Rawson 《Chembiochem : a European journal of chemical biology》2019,20(8):1008-1013
A model cancer cell line was used to initiate polymerisation of pyrrole to form the conducting material polypyrrole. The polymerisation was shown to occur through the action of cytosolic exudates rather than that of the membrane redox sites that normally control the oxidation state of iron as ferricyanide or ferrocyanide. The data demonstrate for the first time that mammalian cells can be used to initiate synthesis of conducting polymers and suggest a possible route to detection of cell damage and/or transcellular processes through in situ and amplifiable signal generation. 相似文献
55.
56.
Adherent polypyrrole films were electropolymerized from a tosylic acid solution onto an aluminium substrate and used for the reduction of Cr(VI). The reduction of Cr(VI) to the trivalent state was found to proceed by pseudo-first-order kinetics with an activation energy barrier of 15.13 kJ mol–1. This catalyst could be regenerated by reducing the composite at a sufficiently negative potential, in the absence of Cr(VI). However, it was found that the catalyst functioned also through a self-sustained regeneration mechanism. In this mechanism, Cr(VI) was reduced by PPy0 to generate PPy+, but the PPy+ was subsequently reduced to PPy0 by oxidation of the aluminium substrate, thus regeneration of the catalytic PPy0 surface giving rise to a synergistic action between the polypyrrole and the aluminium substrate. 相似文献
57.
报道了含钕硅钼杂多酸盐在水溶液中及其修饰到聚吡咯膜里的电化学性质,并对H2O2还原反应的催化作用进行了研究,提出了可能的机理。 相似文献
58.
利用电化学方法,在多通道神经微电极阵列芯片上制备聚吡咯氧化石墨烯薄膜材料,并对该材料的电化学行为进行了分析。对神经微电极阵列芯片采用计时电压法探究,确定了定向修饰聚吡咯氧化石墨烯薄膜的最佳电沉积条件。微电极阵列芯片为多通道实时检测神经细胞的电生理和电化学信号提供了一种新的器件,但其检测灵敏度、信噪比需进一步的提高。将聚吡咯氧化石墨烯的平面微电极阻抗值降低了92.1%,且提高了对多巴胺循环伏安响应的灵敏度,对神经电生理信号和电化学信号的检测具有重要意义。 相似文献
59.
通过乳液聚合法制备导电性聚吡咯/聚乳酸(PPy/PLA)复合膜。扫描电镜观察表明,复合膜中的聚吡咯粒子形成连续的小域分散在可生物降解的聚乳酸骨架中,红外光谱检测显示有PPy和PLA的典型吸收峰。使用自制的多通道直流电刺激系统对复合膜进行测试,结果表明,复合膜电导率衰减缓慢,导电性稳定,在560h~1146h电流持续保持在28μA~35μA之间。扫描电镜显示原代培养的成骨细胞能在导电性PPy/PLA复合膜上很好地粘附和铺展,说明复合膜具有良好的细胞相容性。 相似文献
60.
The sunflower‐like silica core‐polypyrrole (PPy) shell nanocomposites were prepared by using silica sulfuric acid as templates. The silica sulfuric acid was obtained by treating directly the silica nanoparticles with chlorosulfonic acid. The sulfonic groups (? SO3H) on the surface of silica sulfuric acid not only offered the active sites for formation of polypyrrole particles but also acted as dopant agents in PPy. The nanostructures of sunflower‐like silica/PPy nanocomposites and hollow PPy capsules were investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The molecular structure and content of PPy were determined by Fourier transform infrared (FTIR) and thermal gravimetric analysis (TGA), respectively. The highest conductivity of nanocomposites is 2.4 S/cm. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献