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21.
In recent years biodegradable polymers, particularly polyesters such as the poly(lactic acid) (PLA) and polycaprolactone (PCL), have gained high interests for their applicability in the biomedical and pharmaceutical fields where they're used for manufacturing various different resorbable devices, from tissue engineering scaffolds to controlled drug release systems. Despite many positive characteristics, processability of these materials still remains a critical issue as they easily tend to degrade during manufacturing. In this article we aimed to assess microextrusion as a nondegradative process for manufacturing PLA and PCL. The results we experimentally obtained, that are hereby presented, set a new point in the on‐going debate on degradation during processing of resorbable polymers as they allow to affirm that microextrusion leaves unmodified molecular weight distributions without producing any evident reductions in mean molecular weight. Microextrusion thus represents a risk‐free high molecular weight polymer processing solution for obtaining nondegraded products within pharmaceutical and biomedical production lines, such as for scaffolds for tissue engineering applications or drug delivery. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
22.
Extruded collagen fibers constitute a promising biomimetic scaffold for tissue engineering applications. In this study, we compared the structural, thermal, and mechanical properties of fibers produced from either NaCl or poly(ethylene glycol) with a number-average molecular weight of 8000 (PEG 8K), the only two coagents that have been used in the fabrication process. As novel, we report the fabrication of fibers with properties similar to native or synthetic fibers using other coagents. NaCl derived fibers were characterized by higher thermal stability (p < 0.026), stress (p < 0.001), and modulus (p < 0.0025) values than PEG 8K, whereas the latter yielded more extendable fibers (p < 0.012). Poly(ethylene glycol)s with number-average molecular weights of 200 and 1000 produced fibers with similar mechanical properties (p > 0.05) that were thinner (p < 0.033), stiffer (p < 0.022), and less extendable (p < 0.0002) than those of PEG 8K. Poly(vinyl alcohol) (PVA) with a number-average average molecular weight of 9–10,000 and PEG 8K yielded fibers with similar diameters and stress-at-break values (p > 0.05); however, the poly(ethylene glycol) derived fibers were more extendable (p < 0.0003), whereas the PVA fibers were stiffer (p < 0.029). Gum-arabic- and soluble-starch-derived fibers were of similar tensile strength, extendibility, and stiffness (p > 0.05). In this in vitro study, the thickest (p < 0.011) and the weakest (p < 0.0066) fibers were produced in the presence of sodium sulfate. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
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The effect of FEF carbon black as filler on the thermal capacity c, diffusivity a, and thermal conductivity λ, of styrene butadiene rubber (SBR) composites in the temperature range 300–420 K was studied. The filler strongly increases the thermal diffusivity, whilst strongly decreasing the thermal capacity and the thermal conductivity (except at high FEF content ≥80 phr). The influence of the filler on the thermoelastic behaviour of the same composites was also investigated. It was found that the thermoelastic temperature change (ΔT) increased with carbon black concentration as well as the entropy change per unit extension. 相似文献
25.
马道章 《有色金属材料与工程》2007,28(3):129-131
哈兹列特铝板带连铸连轧工艺已被成功地用于铝和铝合金冲击挤压用坯料的生产。在对哈氏四个有关用户扫描的基础上,列举了其产品及其用途,并介绍了相关工艺及其优点。 相似文献
26.
根据啮合型同向旋转双螺杆挤出非充满熔融的理论模型,对描述非充满熔融过程的主要物理量:固相高度变化函数、熔融速率及熔融区总长等进行了计算分析,并对有关影响因素进行了讨论。 相似文献
27.
异型材挤出口模内的流动模拟 总被引:10,自引:1,他引:9
本文根据挤出机理,对口模内的流动行为进行适当的简化和假定,建立了挤出口模内流动分析的数学模型,并采用横截面/假想区域法实现了复杂异型材挤出口模内的数值模拟,数值分析结果与三维有限元解和解析解的对比,取得了满意的效果。 相似文献
28.
等径侧向挤压应变分析 总被引:6,自引:0,他引:6
对等径侧向挤压变形的应变进行了深入的分析,应用平面纯剪切变形应变分析的结果,得到了等径侧向挤压变形真应变和等效真应变的计算公式,分析了循环等径S型侧向挤压真空应变和等效真应变的变化规律。 相似文献
29.
THERMAL DEBINDING OF A NEW BINDER 总被引:6,自引:0,他引:6
Zhou Jicheng * Huang Baiyun Wu Enxi Yu Ligong Qu Xuanhui National Key Laboratory for Powder Metallurgy Central South University of Technology Changsha * Changsha Railway University Changsha 《中国有色金属学会会刊》1997,(4)
THERMALDEBINDINGOFANEWBINDER①ZhouJicheng,HuangBaiyun,WuEnxi,YuLigong,QuXuanhuiNationalKeyLaboratoryforPowderMetalurgy,Centra... 相似文献
30.