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51.
A Oyane M Kasahara N Ichinose Y Yokoyama M Uchida A Ito 《武汉理工大学学报(材料科学英文版)》2005,20(B12):220-222
A synthetic polymer with a laminin-apatite composite layer on its surface would be useful as a percutaneous device. The preparation of such a composite was attempted in the present study using poly( ethylene terephthalate ) (PET) and polyethylene (PE) as the synthetic polymer. PET and PE plates and those pretreated with an oxygen plasma were alternately dipped in calcium and phosphate ion solutions, and then immersed in a metastable calcium phosphate solution supplemented with laminin ( LCP solution ). The PET and PE plates pretreated with an oxygen plasma formed a uniform and continuous layer of a laminin-apatite composite on their surfaces. In contrast, the PET and PE plates that had not been pretreated with an oxygen plasma did not form a continuous layer of a laminin-apatite composite on their surfaces. The hydrophilic functional groups on the PET and PE surfaces introduced by the plasma treatment were responsible for the successful laminin-apatite coruposite coating. 相似文献
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Novel polyurethane insulating coatings were prepared from the reaction of glycerin‐terminated polyurethane prepolymers (GPUPs) and a blocked isocyanate curing agent (BIC). The GPUPs were prepared from the reaction of one equivalent of polycaprolactone polyol (CAPA 210) with an excess amount of 4,4′‐methylene bis(phenyl isocyanate) (MDI) and subsequent reaction of the NCO‐terminated polyurethane with glycerin. The BIC was prepared from the reaction of trimethylol propane (TMP), toluene diisocyanate (TDI) and N‐methylaniline (NMA). The polyols and curing agent were characterized by conventional methods while the curing condition was optimized via gel content measurements. The curing kinetics of the polyurethane coating were investigated and the kinetic parameters derived. The crosslink densities of the samples were determined via the equilibrium swelling method, using the Flory–Rehner equation. The relationships between the crosslink density and the electrical, physical, mechanical and dynamic mechanical properties of the coatings were also studied. Copyright © 2005 Society of Chemical Industry 相似文献
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In order to improve the physical properties and slag corrosion resistance of refractory materials for hot metal pretreatment, different contents of composite metal powders (CMP) were introduced into Al2O3-SiC-C refractory castables. The effect of CMP on the microstructure, physical properties and slag corrosion resistance of Al2O3-SiC-C refractory castables were studied. The results show that the multi scale reinforcing phases including flake crystals, rod shaped fibers, filamentous fibers and whiskers are in situ formed in the samples with addition of CMP, which result to the improvement of the cold modulus of rupture and cold crushing strength. When the addition of CMP is 6 wt.%, the high temperature modulus of rupture increases by 231%, the thermal shock resistance increases by 77% after thermal shock by water cooling 5 times and the percentage of the slag resistant area reduces by 37.2%. 相似文献
56.
以C9油与甲基丙烯酰氧乙基三甲基氯化胺的共聚物P(C9-DMC)为乳化剂制备苯/丙阳离子乳胶粒,并以其为模板,利用直接包覆法制备了由17 nm左右微晶体堆成的ZrO2空心微球。所制得的样品采用FT-IR、XRD、TEM和SEM等进行了表征。 相似文献
57.
研究了用固体润滑石墨、碳化硅、二硫化钼等填料改性的聚苯硫醚 (PPS)涂层的耐磨性能。实验结果表明 ,聚苯硫醚复合涂层具有优良的耐磨性 ;加入适量 ( 3 0 % )的石墨、碳化硅等固体润滑剂 (石墨 :碳化硅 =2∶3 ) ,可以有效提高涂层的耐磨性能 ,而二硫化钼和三氧化二铬的减摩效果更佳 相似文献
58.
N. A. Kochetov B. S. Seplyarskii S. G. Vadchenko 《International Journal of Self-Propagating High-Temperature Synthesis》2008,17(3):206-209
Combustion of bulk density Ti powder (containing 20 wt % TiN as a diluent) in a coflow of N2-Ar mixture was investigated upon variation in the nitrogen content of the gaseous mixture. The obtained data are believed
to open up new horizons for fabrication of layered and composite ceramics by infiltration-mediated combustion.
相似文献
59.
Skim and whole milk powders were manufactured at lab scale by spray freeze drying (SFD), using liquid nitrogen as the cryogen. The polydispersity of droplet/particle sizes was limited using an encapsulator nozzle to atomize the feed. Particle morphology was examined using a scanning electron microscope. Samples were compared with equivalent spray-dried powders in tests of wettability and dissolution in water. The spray freeze-dried powders were found to be highly porous, with a uniform structure of pores throughout the entire particles. When tested in water, SFD skim milk powders wetted roughly three times as fast as industrially spray-dried agglomerated skim milk powders and were observed to dissolve rapidly by breaking down into smaller particles. 相似文献
60.
Effects of thermal and mechanical treatments on a titanium-based conversion coating for aluminium alloys 总被引:1,自引:0,他引:1
The influence of mechanical deformation and heating on the protective performance of a chromium-free conversion treatment for aluminium alloys has been assessed by polarisation and AC impedance measurements. Protection is unlikely to be seriously compromised by typical production operations. 相似文献