全文获取类型
收费全文 | 19465篇 |
免费 | 1528篇 |
国内免费 | 480篇 |
专业分类
电工技术 | 620篇 |
综合类 | 1046篇 |
化学工业 | 9202篇 |
金属工艺 | 240篇 |
机械仪表 | 326篇 |
建筑科学 | 1332篇 |
矿业工程 | 148篇 |
能源动力 | 2639篇 |
轻工业 | 1605篇 |
水利工程 | 158篇 |
石油天然气 | 488篇 |
武器工业 | 19篇 |
无线电 | 282篇 |
一般工业技术 | 2636篇 |
冶金工业 | 313篇 |
原子能技术 | 121篇 |
自动化技术 | 298篇 |
出版年
2024年 | 73篇 |
2023年 | 351篇 |
2022年 | 670篇 |
2021年 | 821篇 |
2020年 | 733篇 |
2019年 | 640篇 |
2018年 | 445篇 |
2017年 | 580篇 |
2016年 | 512篇 |
2015年 | 513篇 |
2014年 | 1009篇 |
2013年 | 996篇 |
2012年 | 1501篇 |
2011年 | 1457篇 |
2010年 | 1190篇 |
2009年 | 1100篇 |
2008年 | 951篇 |
2007年 | 1250篇 |
2006年 | 1023篇 |
2005年 | 942篇 |
2004年 | 807篇 |
2003年 | 733篇 |
2002年 | 531篇 |
2001年 | 452篇 |
2000年 | 424篇 |
1999年 | 368篇 |
1998年 | 297篇 |
1997年 | 233篇 |
1996年 | 184篇 |
1995年 | 127篇 |
1994年 | 140篇 |
1993年 | 122篇 |
1992年 | 89篇 |
1991年 | 61篇 |
1990年 | 36篇 |
1989年 | 16篇 |
1988年 | 22篇 |
1987年 | 12篇 |
1986年 | 13篇 |
1985年 | 8篇 |
1984年 | 5篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 1篇 |
1980年 | 5篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1951年 | 19篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
本文以全氟羧酸离子交换膜为支撑体、乙二胺(EDA)为活性络合剂、制备促进传质膜。在常用的工业条件下,测定了纯CO_2以及CO_2/N_2二元混合物在该膜内的渗透通量。实测结果表明,此膜对CO_2的促进因子可达13.8,而对CO_2/N_2的分离因子高达316。本文假设促进传质过程的控制步骤为气体在膜相的扩散,据此导出了相应的机理模型,该模型与实测结果吻合良好。 相似文献
62.
The state of water in water-swollen poly(vinyl alcohol-co-itaconic acid) membranes, having various water contents from 0.31 to 0.83, was investigated by d.s.c. measurements and compared with those in water-swollen poly(vinyl alcohol) membranes. The amount of freezing water in the membranes was estimated by use of a relationship between the phase transition temperature and the enthalpy of the crystallization of supercooled water. The melting temperature of the water in the membranes immersed in urea and NaCl 0–2 mol l?1 aqueous solutions was also determined by d.s.c. analysis. The present study proposes a method for estimating the solubilities of urea and NaCl in both of the freezing and the non-freezing water using the melting point depression of the freezing water in the membranes immersed in the solute solution. 相似文献
63.
介绍了快速高效隔膜压滤机的主要性能参数和特点 ;分析了压滤机在煤泥水处理系统中的应用情况和运行结果 ;应用快速高效隔膜压滤机对煤泥水处理系统进行改造后获得了较好的经济及社会效益 相似文献
64.
F. Frusteri E. N. Savinov A. Parmaliana E. R. Savinova V. N. Parmon N. Giordano 《Catalysis Letters》1994,27(3-4):355-360
Selective partial oxidation of ethane to ethanol and acetaldehyde by in situ generated H2O2 has been achieved under cathodic current passing through a carbon supported Nafion-H catalytic membrane. A correlation between H2O2 generation rate and reaction rate has been found. 相似文献
65.
Methane has been selectively converted to synthesis gas using a two-zone fixed bed of a Ni/Al2O3 catalyst inside a modified ceramic membrane. The first zone of the reactor was surrounded by an impervious wall, and therefore behaved as a conventional fixed bed reactor. In the second zone, some of the reaction products could preferentially diffuse out of the reactor, which yielded higher than equilibrium methane conversions. The influence of the different operating conditions has been studied, and the performance of the membrane reactor has been compared to that of a fixed bed reactor. The membrane reactor has also been used at pressures above atmospheric (2 bar), with good conversions and selectivities. 相似文献
66.
This paper presents a mathematical model based on the reaction rate expressions to describe the displacement of methane conversion in the steam reforming. The effect of several parameters including weight hourly space velocity (WHSV), load-to-surface ratio, reaction pressure, hydrogen partial pressure in permeate side and reaction temperature were investigated. Simulation and experimental results showed that a conversion higher than 80% could be achieved in a palladium membrane reactor at reaction temperature of 500 °C relative to 850 °C in a conventional fixed bed reactor (FBR). Besides, the yield of CO (<2%) in membrane reactor was much lower than that (>50%) in the FBR, which indicated the significant depression of CO production in use of membrane reactor. 相似文献
67.
V.V. Zyryanov N.F. Uvarov V.A. Sadykov Y.V. Frolova G.M. Alikina A.I. Lukashevich M.I. Ivanovskaya J.M. Criado S. Neophytides 《Catalysis Today》2005,104(2-4):114-119
Nanopowders of LaGaO3- and LaMnO3-based complex perovskites (P) and ceria-based fluorites (F) were prepared by mechanosynthesis. Compatible nanocomposites F + P and P + P with mixed ion and electron conducting (MIEC) properties were prepared and sintered at moderate temperatures up to dense ceramics. The obtained materials were studied by means of XRD, SEM, TEM, electrical conductivity measurements, temperature programmed (TP) reduction/oxidation and preliminary estimations of permeability were obtained. A new strategy based on the advantages of the mechanochemical ceramic approach is proposed to design multilayer ceramic membranes for CMR. Casting technology and one-step sintering were used for the production of thin film membranes with MIEC properties on porous substrates. The coarse fraction of as-milled powders from agglomerates with density 70% was used for the porous substrate, and fine fractions of aggregates with sizes <1 μm were used in preparation of composites for thin dense films. Ceria-based composites prepared by the Pechini route and/or mechanochemical method are proposed as materials for protecting thin films. 相似文献
68.
69.
In this study the methyl tert-butyl ether (MTBE) decomposition over H3PW12O40 was carried out in a cellulose acetate membrane reactor. The permeability of methanol through the cellulose acetate membrane was about 30 and 300 times higher than that of either isobutene or MTBE, respectively. The isobutene selectivity in the fixed bed reactor was only slightly higher than the methanol selectivity due to the side reaction. In the cellulose acetate membrane reactor, however, the isobutene selectivity in the rejected stream was 68% and the methanol selectivity in the permeated stream was up to 97%. The MTBE conversion in the membrane reactor was about 7% higher than that in the membrane-free fixed bed reactor under the same reaction conditions. The enhanced performance of the membrane reactor in this reversible reaction was mainly due to the selective permeation of methanol which resulted in a methanol-deficient condition suppressing MTBE synthesis reaction. 相似文献
70.
Ethanol extraction of oil,gossypol and aflatoxin from cottonseed 总被引:7,自引:0,他引:7
R. J. Hron Sr. M. S. Kuk G. Abraham P. J. Wan 《Journal of the American Oil Chemists' Society》1994,71(4):417-421
Commercial processing of cottonseed requires hexane to extract and recover edible oil. Gossypol and aflatoxin are not removed
from extracted meals. A bench-top extraction process with 95% (vol/vol) aqueous ethanol (EtOH) solvent has been developed
that extracts all three of the above materials with a much less volatile solvent. In this process, cottonseed is pretreated
and extracted with ambient 95% EtOH to remove gossypol and then extracted with hot 95% EtOH to extract oil and aflatoxin.
Membranes and adsorption columns are used to purify the various extract streams, so that they can be recycled directly. A
representative extracted meal contained a total gossypol content of 0.47% (a 70% reduction) and 3 ppb aflatoxin (a 95% reduction).
Residual oil content was approximately 2%. Although the process is technically feasible, it is presently not economical unless
a mill has a continual, serious aflatoxin contamination problem. However, if a plant cannot meet the hexane emission standards
under the Clean Air Act of 1990, this process could provide a safer solvent that may expand the use and increase the value
of cottonseed meal as a feed for nonruminants.
Presented in part at the AOCS annual meeting, Toronto, Canada, May 1992. 相似文献