1,1'-二羟基-3,3'-二硝基-5,5'-联-1,2,4-三唑含能离子盐合成、晶体结构及性能

以1,1'-二羟基-3,3'-二硝基-5,5'-联-1,2,4-三唑(DNOBT)为原料,分别与3-氨基-1,2,4-三唑、草酰肼、二肼基四嗪反应合成了DNOBT的3-氨基-1,2,4-三唑盐(DNOBT-3-AT)、草酰肼盐(DNOBT-ODH)、二肼基四嗪盐(DNOBT-DHT)三种含能离子盐,用红外光谱、核磁及元素分析对其结构进行了表征;培养了DNOBT-3-AT的单晶,X射线衍射分析表明其晶体为单斜晶系,空间群为P2(1)/c;利用Gaussian 09程序和Kamlet-Jacobs方程计算了DNOBT-3-AT、DNOBT-ODH、DNOBT-DHT的物化与爆轰性能,采用差示扫描量热(DSC)研究了这三种化合物的热性能,结果表明,DNOBT-3-AT、DNOBT-ODH、DNOBT-DHT爆速分别为7736.4,7729.56,7974.64 m·s~(-1),爆压分别为26.8,26.74,28.56 GPa;第一个热分解峰温度分别为276.54,257.02,154.15℃,相较于DNOBT-ODH和DNOBT-DHT,DNOBT-3-AT具有更好的热稳定性。     

陆战平台综合电力系统及其关键技术研究

针对地面战斗平台电驱动、电武器、电防护以及其他多用电任务剖面需求,提出了陆战平台综合电力系统的理论构架,对系统概念、功能与特点进行了界定,并构建了一种基于多驱动特性能量源的系统分布式体系结构。在此基础上,以“系统容量”和“电能质量”为纽带,系统分析了能量源匹配计算、功率变换装置设计、能量分配与优化控制以及电能质量分析与管理等关键技术。研制了系统样机并应用于工程实践,为加快推进陆战平台全电化技术发展提供能源支撑与技术借鉴。     

Nitrosation and Nitration of Tetraacetyldibenzylhexaazaisowurtzitane

Tetraacetyldibenzylhitane (TADBIW) was subjected to debenzylation by nitrosating with inorganic materials available commercially to synthesize tetraacetyldinitrosohexaazaisowurtzitane (TADNSIW). TADNSIW was purified, and its structure was determined by FTIR, 1H NMR, MS and element analysis. The debenzylation reaction of TADBIW gave quantitative benzaldehyde as a by-product. This indicates that the reaction produces an imine cation as an intermediate. Hexanitrohexaazaisowurtzitane (HNIW) was prepared from unpurified TADNSIW with the yield over 96.0 % and the purity more than 98.0 %. And the mechanism of the reaction from TADNSIW to HNIW is proposed to be oxidation of nitroso and nitration of acetyl on the molecule of TADNSIW, This reaction system involved is simple, and the reaction can complete within a short time and under mild conditions. The product can be easily to separate and the waste disposed readily.     

QoE-aware video distribution mechanism in FiWi

The mismatch of transmission ability causes the discontinuous transmission of video services in fiber-wireless access network,aimed at this problem,an QoE-aware video distribution mechanism was proposed.According to the structural characteristics of fiber-wireless access network,link state information and scalable video coding structure was considered,a QoE evaluation mode was established,and the particle swarm optimization algorithm was used to select optimal video transmission rate.Then the node transmission capacity and the node matching degree was analyzed,transmission path for the services was selected,so as to ensure the reliable transmission of services.The results show that the proposed mechanism can effectively improve the utilization rate of network resources and reduce network congestion while improving the quality of the user experience.     

Joint admission control algorithm based on load transfer in heterogeneous networks

A load-transfer-based joint admission control (LJAC) algorithm in heterogeneous networks was proposed.The access requirements of users were admitted based on load balancing,the dynamic load transfer of traffics in the overlapping coverage areas of heterogeneous networks were introduced,and the influence of such factors as the layout of heterogeneous networks and the vertical handoff was considered in the algorithm.The integrated system of heterogeneous networks was modeled as a multidimensional Markov chain,the steady-state probabilities were obtained and the quality of service (QoS) performance metrics were derived.Based on the Poisson point process theory,the upper bound of capacity of the heterogeneous networks satisfying QoS limitations was obtained.The admission control parameters of the integrated system of heterogeneous networks were optimized in order to maximize the resource utilization rate as well as guaranteeing the QoS of users.The simulation results demonstrate lower traffic blocking probability,lower failure probability of vertical handoff requirements,and larger system capacity gain can be achieved by using the proposed LJAC algorithm.     

融合改进 Padim 建模和 ResNet 网络的 喷涂质量检测算法

为了满足喷涂机器人对于喷涂质量检测的需求,采用迁移学习对改进 Padim 建模和 ResNet 网络进行融合,构建自主喷 涂机器人喷涂质量检测一体化模型。 该模型提取一次图像特征可同时用于缺陷定位和分类。 在缺陷定位端,通过改进 Padim 模型以减少特征冗余所造成网络的计算消耗,首先将 ResNet-18 网络获取的 patch 嵌入向量语义层由原先前 3 层改为单 2 层,然 后特征表达由 100 维降维至 20 维,最后训练正样本得到正态分布模型与测试图像进行缺陷定位。 在缺陷分类端,对预训练 ResNet-18 网络进行负样本二次训练,得到 ResNet-18 分类模型对测试图像进行缺陷分类。 经过实验,将一体化模型移植在 jetson nano 移动端中,参数量仅为 11. 69 M,定位精度 94. 5%,分类准确率高达 99. 6%,在机器人位移速度 0. 02 m/ s 下检测时间 为 0. 730 s,不会出现缺帧漏检情况,满足实时检测的要求。     

改进 YOLOv5s 的风力涡轮机表面缺陷检测

针对传统方式检测风力涡轮机表面缺陷时出现的精度不足、泛化性较差问题,提出了一种改进YOLOv5s的风力涡轮机表面缺陷检测模型。在网络结构方面,首先在主干特征提取网络引入改进的MobileNetv3网络,用于协调并平衡模型的轻量化和精度关系;其次采用BiFPN式的融合方式,增强神经网络的多尺度适应能力,提高融合速度和效率;最后为轻量化的自适应调节特征权重,运用ECAnet通道注意力机制,进一步提高神经网络的特征提取能力。在损失函数方面,将边框回归的损失函数修改为αIoU Loss,进一步提升了bbox回归精度。实验结果表明,基于YOLOv5s的改进算法可以在复杂环境下快速准确地识别风机表面的缺陷目标,能够满足实时目标检测的实际应用需求。     

模糊聚类法在水环境质量评价中的应用

模糊聚类法通过数据标准化、平移及极差变换、确定最佳阈值和求解动态聚类图.该算法在长江芜湖段水环境质量评价中的应用,以选取对长江芜湖段水质影响较大的7个指标并建立其模糊相似矩阵,根据实测浓度值确定各因子的权重,结果可行.     

24-二硝基茴香醚基含铝熔铸炸药爆轰临界直径的实验研究

为了揭示2,4-二硝基茴香醚(DNAN)基高能钝感熔铸炸药的爆轰传播特性,加快DNAN基熔铸炸药的工程化应用,采用连续导线法测量了DNAN基含铝熔铸炸药的临界直径。结果表明：Al含量（质量百分比0~30%）增大、Al粒度d₅₀（分别为6 μm、12 μm、31 μm）减小均会降低爆轰传播的临界直径;黑索今（RDX）的粒度d₅₀（分别为19 μm、147 μm、751 μm）增大、RDX品质提高会增大爆轰传播的临界直径。研究结果为DNAN基含铝熔铸炸药的配方和战斗部结构设计提供基础的技术参数。     

实战化要求下国产新型红外探测器质量现状

从满足武器系统实际使用要求的角度出发,分析实战化要求下,当前国产新型红外探测器质量现状和质量问题归零存在的不足,并对检验工作实践中发现的问题进行探讨,尝试提出一些能保证武器系统质量,满足装备实战化要求的解决办法.该研究可为从事军品研究、设计、制造和管理的人员提供参考.