Intramolecular crosslinking of poly(vinyl alcohol)

Poly(vinyl alcohol) is crosslinked in dilute solution (c=0.1 wt%) with glutaraldehyde. The reaction product is characterized by viscometry and gel permeation chromatography (g.p.c.). The intrinsic viscosity decreases with increasing degree of crosslinking and does not depend on temperature. G.p.c. reveals that the reaction product is not homogeneous, but consists of a mixture of particles with different sizes, possibly both intra- and intermolecularly crosslinked molecules. The intramolecularly crosslinked molecules are smaller in size than the initial polymer molecules and their size depends on the degree of crosslinking. They possess a narrow particle size distribution even if the initial polymer sample had a broad molecular weight distribution.     

振动力场作用下聚合物挤出制品结构与性能的质量控制与优化

利用实验数据，分析与研究振动场振动参数对聚合物挤出制品质量的影响，对聚合物挤出制品的熔体流动速率，微晶结构，拉伸强度等主要性能质量指标，建立以振动频率为主要控制变量的神经网络模型，并引入信息分配模型，探讨了一个网络输入节点下神经网络学习样本的特征提取与优化。实验结果表明，经过信息预处理的学习样本，可以使网络有更好的收敛效果。     

Breakdown characteristics of oil and paper insulation for a very fast transient voltage

This paper describes the dielectric breakdown characteristics of oil and oil‐impregnated paper for very fast transient (VFT) voltages. Blumlein circuits generate VFT voltages of 60 and 300 ns in a pulse width that simulates disconnecting switching surges in gas‐insulated switch gears. We measured the breakdown voltages of needle‐to‐plane, plane‐to‐plane oil gaps and several pieces of paper between plane electrodes for VFT and lightning impulse voltages. The measured data were formulated in V‐t characteristics and Weibull probability distributions. The inclination n of V‐t characteristics of insulating paper is 150, which is less than n = 13.7 of the plane‐to‐plane oil gap in the VFT time range. The shape parameters of Weibull distribution obtained in this study show that the scattering of breakdown voltages of paper is much less than that of oil. © 2002 Wiley Periodicals, Inc. Electr Eng Jpn, 141(4): 16–24, 2002; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.10043     

等偏移距自动初至静校正

茅金根 ,梁秀文 ,杨午阳 ,冯有奎 .等偏移距自动初至静校正 .石油地球物理勘探 ,2 0 0 2 ,37(5 ) :4 6 9～ 4 72　　本文提出一种自动计算静校正量的新方法。它首先在等偏移距道集内对相邻道的初至波采用高精度相关构建一个关于炮、检时差的超大矩阵方程 ,然后采用优化统计迭代算法求解炮点和检波点的静校正量 ,并用概率分布函数确定精确的炮、检静校正量 ,最后用误差校正函数消除炮、检静校正误差。实际资料处理结果表明 ,本方法自动、省时、精度高。     

NO emission characteristics in counterflow diffusion flame of blended fuel of H2/CO2/Ar

Flame structure and NO emission characteristics in counterflow diffusion flame of blended fuel of H₂/CO₂/Ar have been numerically simulated with detailed chemistry. The combination of H₂, CO₂ and Ar as fuel is selected to clearly display the contribution of hydrocarbon products to flame structure and NO emission characteristics due to the breakdown of CO₂. A radiative heat loss term is involved to correctly describe the flame dynamics especially at low strain rates. The detailed chemistry adopts the reaction mechanism of GRI 2.11, which consists of 49 species and 279 elementary reactions. All mechanisms including thermal, NO₂, N₂O and Fenimore are taken into account to separately evaluate the effects of CO₂ addition on NO emission characteristics. The increase of added CO₂ quantity causes flame temperature to fall since at high strain rates a diluent effect is prevailing and at low strain rates the breakdown of CO₂ produces relatively populous hydrocarbon products and thus the existence of hydrocarbon products inhibits chain branching. It is also found that the contribution of NO production by N₂O and NO₂ mechanisms are negligible and that thermal mechanism is concentrated on only the reaction zone. As strain rate and CO₂ quantity increase, NO production is remarkably augmented. Copyright © 2002 John Wiley & Sons, Ltd.     

千米桥东潜山天然气地球化学特征及成因探索

通过地化分析，结合地质条件等，对千米桥东潜山天然气地球化学特征进行了剖析，并对其气藏的形成进行了探索，结果认为：千米桥东潜山天然气为无机二氧化碳、偏腐殖型有机气，腐泥型有机气的复合气，主源为东部歧口凹陷沿岩带深层（偏）腐殖型气，烃类气体聚集时间晚，为更新世明化镇沉积时其，而无机二氧化碳聚集时间早于烃类气体；与千米桥凝析气藏不同的是该气藏CO2含量高。     

产品数据管理(PDM)实施中的存在问题与对策

论述了产品数据管理（PDM）技术发展的历史，讨论了实施PDM的两种目标，并指出PDM在制造业信息化中的地位与作用，阐述了PDM重在实施的原因，根据作者经验，总结了我国企业在实施PDM中存在的4个问题，并从用户和软件厂商两个角度提出了解决这些问题的对策。     

工业建筑多层框架的活荷载不利布置

以设防烈度为8度的框架厂房为例，详细分析了活荷载不利布置对框架梁、柱内力的影响，得出何时需要考虑活荷载不利布置、何时不需要考虑活荷载不利布置的结论，可供工程设计参考。     

云南省磷肥工业产品结构的现状及发展建议

分析了国内外磷肥工业产品的市场形势及发展趋势，同时对云南省磷肥产品的发展提出建议。