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11.
12.
L. Rutigliano D. Fino G. Saracco V. Specchia P. Spinelli 《Journal of Applied Electrochemistry》2008,38(7):1035-1041
This paper describes the results obtained from an electrokinetic treatment of a real soil polluted by lead acetate. Powdered
soil samples were pressed with a consolidometer till 100 kPa to obtain cylindrical specimens with the same characteristics
as a subsoil. Tests were carried out in a Perspex electrochemical cell where soil specimens were introduced with a hollow
punch. A low intensity direct current was applied in order to remove contaminants, due to electrophoresis and electroosmosis
phenomena. The water flow, conductivity, apparent electroosmotic coefficient, as well as other characteristic parameters,
were measured throughout the test. The water content and degree of pore saturation were estimated at the beginning and end
of the test. The soil slab was divided into four slices and the Pb concentration profile determined. The main factor governing
the extraction of contaminant was found to be the pH in the acidic range. Indeed, under these conditions high removal efficiencies
could be reached. These results could lead to the design of a new electrochemical treatment cell equipped with a cationic
membrane to expand the region of favourable pH within the soil. 相似文献
13.
The dielectric behavior of sol-gel derived Ba0.80Sr0.20(ZrxTi1−x)O3 (0.0 ≤ x ≤ 0.50) thin films is studied. A relaxor behavior is observed for x ≥ 0.35. The degree of relaxation increases with Zr content. The frequency dependence of the polar regions follows Vogel-Fulcher relation with a characteristic cooperative freezing at freezing temperature (Tf). Below Tf, a long range polarization ordering is likely to take place. The plausible mechanism of the relaxor behavior of BSZT thin films with Zr contents ≥ 0.35 has been proposed based on the measured temperature as well as frequency dependent dielectric data. The solid solution system is visualized as a mixture of Ti+ 4 rich polar regions and Zr+ 4 rich regions; with the increase in Zr content the volume fraction of the polar regions is progressively reduced. At and above 35.0 at.% Zr substitution the polar regions exhibit typical relaxor behavior. 相似文献
14.
15.
A numerical study of the transport phenomena arising in a single-screw extruder channel is carried out. A non-Newtonian fluid
is considered, using a power law model for the variable viscosity. Chemical reaction kinetics are also included. Finite difference
computations are carried out to solve the governing set of partial differential equations for the velocity, temperature and
species concentration fields, over a wide range of governing parameters for the case of a tapered screw channel.
The numerical treatment for this combined heat and mass transfer problem is outlined. A marching procedure in the down-channel
direction is adopted and the validity of the scheme for practical problems discussed. For large viscous dissipation, the material
heats up considerably due to the prevailing shear field, affecting the viscosity significantly, and results in large changes
in the pressure development at the end of the channel. The rate of reaction controls the mass diffusion rate which in turn
affects viscosity and the flow significantly. The dimensionless throughput,q
v
, is one of the most important parameters in the numerical solution. The dimensionless pressure variation is very sensitive
toq
v
, and orders of magnitude changes are possible for small variations inq
v
. Schemes for dealing with other important effects such as back flow, heat transfer by conduction in the barrel, and the effect
of the die are also outlined.
A list of symbols is given at the end of the paper
This is publication No. F-10544-4-91 of the New Jersey Agricultural Experiment Station supported by State Funds and the Center
for Advanced Food Technology (CAFT). The Center for Advanced Food Technology is a New Jersey Commission on Science and Technology Center. This work was also
supported in part by the US Army Research Office. 相似文献
16.
The condition of the surfaces is of crucial importance for the deuterium permeation through materials. In this work a study of the surface constants for the adsorption (σk1) and release (σk2) of deuterium under different surface conditions on the martensitic steel DIN 1.4914 (MANET) has been carried out. The growth of an oxide surface layer (Cr2O3) of about 25–30 nm in a MANET sample, heat treated in an oxidizing environment, compared to the bare MANET that have a ‘natural' oxide of about 5 nm has provoked a reduction of both the permeation rate and the recombination coefficient (about 3 orders of magnitude). In addition, the permeation governing process has changed from diffusion-limited to surface-limited. The measurements of the permeation rate of deuterium were performed by a gas-phase permeation technique over the temperature range 574–746 K and for deuterium driving pressures in the range from 3 to 105 Pa. 相似文献
17.
18.
On the basis of the isomorphism of critical phenomena, the behavior of transport properties of binary mixtures in the vicinity of the vapor-liquid critical line is considered. In particular, the renormalization of the singularity of the thermal conductivity in dilute critical solutions has been analyzed in detail. It is shown that the behavior of the thermal conductivity is determined by the critical background, i.e., the fluctuation-induced regular part, which diverges at the critical point of a solvent. 相似文献
19.
3D GIS最重要的特征之一就是虚拟现实表现,其本质是可视化技术与GIS数据库的整合,以满足各种应用如生态农业、灾害预测等方面的需求。以GIS数据库的环境数据和气象数据为基础,通过对雨雪的效果模拟,将GIS气象数据以实时的可视化形式逼真地表现出来。实验方法采用粒子系统,对单个点元赋予利用Photoshop制作的大面积纹理,这样采用的粒子数减少到普通粒子系统的十分之一,渲染速度为普通粒子系统的十倍以上,以较小的系统资源消耗达到了更加实时逼真的效果,对雪的动态堆积和雨水地面效果采用GPU加速3维渲染,原型系统同时能接受用户对实验环境如粒子纹理、雨雪量的设置。提出根据气象数据进行天气模拟的自适应策略,从而更加适应实际应用需要。 相似文献
20.
The specific heat at constant volume cv shows a weak singularity at the critical point. Renormalization group techniques have been applied, predicting a universal critical behavior which has to be experimentally confirmed for different systems. In this paper an experiment is presented to measure the specific heat of SF6 along the critical isochore (c=0.737 g·cm–3), applying a continuous heating method. The results cover a temperature span of –1.5×10–2< <1.70×10–2 [=(T–T
c)/T
c] and were strongly affected by gravity effects that emerge in the sample of 1-mm hydrostatic height near the critical point. Using regression analysis, data were fitted with functions of the form c
v/R=A × ¦¦– + B for the one-phase state and c
v/R=A × ¦¦– + B for the twophase state. Within their error bounds the critical values (==0.098, A/A=1.83) represent the measurements for the temperature span 3.5×10–5< ¦¦<2.0×10
–3, in good agreement with theoretical predictions. In order to exclude density profiles in the specimen, which are unavoidable in terrestrial experiments due to the high compressibility of fluids at the critical point and the gravity force, a space-qualified scanning ratio calorimeter has been constructed, which will permit long-term cv measurements under microgravity (-g) conditions. The experiment will be part of the German Spacelab mission in October 1985. The significant features of the apparatus are briefly sketched.Paper presented at the Ninth Symposium on Thermophysical Properties, June 24–27, 1985, Boulder, Colorado, U.S.A. 相似文献