单晶高温合金DD3亚结构超细化定向凝固工艺研究EI

利用ＺＭ定向凝固装置研究了镍基单晶高温合金ＤＤ３在高温度梯度（７００～１２００Ｋ／ｃｍ）定向凝固条件下的微观组织演化特征及其对工艺参数的响应函数，结果表明：该合金在高界面温度梯度条件下，柱晶生长速度范围向高速区扩展，从而使单晶亚结构细化成为可能。所得单晶棒中亚结构一次间距可比传统ＨＲＳ法定向凝固籽晶中相应尺度减小５～１０倍。本文还对其组织演化机制进行了分析。     

Crystallization of glass in fireclay refractories; part III: Detailed study on the mullite crystal size in the ‘synthetic’ glass

Poor-grade fireclay products contain substantial amount of glass. A glass of similar composition was synthesized, nucleated and heat-treated for crystallization of mullite. The size and size-distribution of mullite crystals, the rate of change of size and the aspect ratio of the crystals were investigated in relation to the nucleating agents and temperature.     

Observation of atomic steps on CaCO3 crystal surface

By using scanning polarization force microscopy,the deliquescence process and the atomic steps on the cleavage surface of CaCO3 in air were studied in situ.Under an exposure to medium umidity(-57%),the sloiw step movement has been observed.     

In－BiCaVIG的晶体生长与性能

本文报导了用助熔剂法成功地生长大尺寸掺铟ＢｉＣａＶＩＧ晶体的方法以及实验结果，介绍了该单晶在近红外区的磁光器件中的重要应用。     

表面稳定模式铁电液晶的电光特性测试

采用一种改进的高分子膜摩擦定向法成功地实现了表面稳定模式铁电液晶的光学双稳态，对比度大于１４０，响应时间达１００微秒。     

Ce,Eu双掺BSO晶体光折变效应研究

在ＢＳＯ晶体中同时掺入Ｃｅ和Ｅｕ离子，生长了Ｃｅ：Ｅｕ：ＢＳＯ晶体，对晶体的二波耦合和四波混频性能了测试。结果表明，Ｃｅ和Ｅｕ离子对晶体的光折变效应起到了增强的作用。     

大尺寸氟化铅晶体的生长

描述了不用高真空条件，在通常的Ｂｒｉｄｇｍａｎ－Ｓｔｏｃｋｂａｒｇｅｒ炉中，用高温下的反应方法，消除了原料及生长炉内残存的Ｏ＾２－及ＯＨ＾－，生长出优质，大尺寸的β－ＰｂＦ２晶体。在晶体生长时，出现的主要问题是在晶体中的针状结构及开裂，但可通过控制条件来解决。     

Crystal orientation of β-phase isotactic polypropylene induced by magnetic orientation of N,N′-dicyclohexyl-2,6-naphthalenedicarboxamide

Melt crystallization of isotactic polypropylene (iPP), containing crystallites of N,N′-dicyclohexyl-2,6-naphthalenedicarboxamide (DCNDCA) as a nucleating agent of the the β-phase iPP crystal, is carried out under a magnetic field (6 T) to obtain the alignment of the iPP crystal induced by magnetic alignment of DCNDCA. In a previous paper, DCNDCA was reported to undergo magnetic alignment in a liquid suspension. The obtained iPP sample exhibits alignment of the β-phase crystal with the c-axis aligned perpendicular to the magnetic field. The comparison of this alignment of iPP with the reported magnetic alignment of DCNDCA indicates that the β-phase crystal grows epitaxially on the DCNDCA crystal. The (330)_β plane of the iPP crystal lies on the bc-plane of the DCNDCA crystal in which the direction of the c-axis of the iPP coincides with the direction of the b-axis of the DCNDCA crystal.     

New polymer syntheses: 59. Homo-and copolyesters of 4-(4′-hydrophenoxy)benzoic acid

The homopolyester of 4-(4′-hydroxyphenoxy)benzoic acid (poly(4-HPBA)), was prepared under two different reaction conditions and compared with a sample provided by another research group. Depending on the synthetic route, different melting points, d.s.c. traces and crystal lattices were found. However, after repeated heating and cooling, one thermodynamically stable modification with a melting point of 370–375°C can be obtained. Copolyesters of 4-hydroxybenzoic acid and 4-(4′-hydroxyphenoxy)benzoic acid were prepared with various molar ratios either in the melt (condensation in bulk) or in solution. These copolyesters were characterized by elemental analyses, ¹H n.m.r. spectroscopy, d.s.c. measurements, wide-angle X-ray scattering measurements at various temperatures, and optical microscopy. Whereas copolyesters prepared in solution do not melt below 500°C, those prepared by polycondensation in bulk show melting points down to approximately 260°C and form a nematic melt.     

自发参量下转换光场的实验研究进展综述

自发参量下转换(spontaneous parametric down-conversion,SPDC)光场是基于单色泵浦光子流和量子真空噪声对非线性晶体的综合作用而产生的,它固有的量子起源决定了在非经典光场研究中的重要地位和作用.对SPDC光场的相干特性和它在绝对测量光电探测器量子效率中的应用进行了深入而细致的研究和探讨.