MAXIMUM ENTROPY DECONVOLUTION OF XPS PEAK

Necessity of XPS spectrum,deconvolution,disadvantages of the traditional Fast Fourier Tranderm decon-volution method(FFT),princtple,method and advantage ofMaximum Entropy Deconvolution Method (MEM) are de-scribed.Criteria for determing the number of data points sam-pled in MEM are the main point disccussed in the paper,someXPS deconvolution applications of our MEM software showthat the MEM makes XPS deconvolution much easier than thetraditional FFT method.     

天然糖甙类化合物^13C—NMR位移范围规律的计算机解析方法

本文从糖甙类化合物的数据特点出发,用较严格的数学推导总结出原则上适用于任何类型的~(13)C-NMR 图谱化学位移范围规律计算机自动解析的方法,并从多方面说明了该方法的研究及实现对实际的~(13)C-NMR 图谱解析工作的意义和重要作用。     

Machine translation of non-literary texts: Some Canadian experiences

A survey was carried out of past and current Canadian experiences with machine-aided translation (MAT) systems of non-literary texts in one government institution and three industrial settings. Each organization requires a great deal of translation and had conducted several experiments in the use of MAT. The survey supports positive conclusions about the prospects for expanded use of computers in translation.The authors express their thanks to all those who helped in the preparation of this paper. We are particularly grateful to the staff of the translation departments of the organizations mentioned in the paper for their kind cooperation and their willingness to answer our questions: Chantal Delorme ofIBM Canada, Lorraine Desmarais and Mr. Plamondon of Bell Canada, Pierre Tellier of the Department of the Secretary of State, Maria Russo and Raymond Lapointe of the Xerox Corporation. Furthermore we thank Prof. Graeme Hirst for helpful discussion.     

基于TMS320C6x实现多载波QPSK信号全数字化整体解调

提出并证明了一种群路FDMA/QPSK(频分多址/正交相移键控)信号全数字化整体解调的新方法,该方法根据信道构成特点和信号调制方式,将直接分路法和常规多相FFT(快速傅里叶变换)分离法相结合,构成了一种简化的等效多相FFT分路方法,再将输出的数字信号送到数字式解调器,实现了多载波信号的全数字化整体解调,其特点是软件和硬件结构简单、系统计算量小,且易于DSP实时实现,现已用该算法进行了32路FDMA/QPSK信号整体解调的计算机仿真实验,结果表明该方法是可行的.     

Cover Picture: Toward Large‐Scale Alignment of Electrohydrodynamic Patterning of Thin Polymer Films (Adv. Funct. Mater. 15/2006)

By integrating lithography and self‐assembly via electrohydrodynamic instabilities, Russel and co‐workers are able to guide initially flat polymer films to evolve into periodic arrays of pillars over regions much greater in extent than their natural domain sizes, as detailed on p. 1992. Novel structures that involve a combination of linear ridges and pillars are also produced, mainly as as result of the dynamic merging among preformed pillars. To pattern thin polymer films via electrohydrodynamic instabilities, we design and utilize two different kinds of mask patterns to guide pillars into alignment over regions much greater in extent than their natural domain sizes. First, narrow protruding ridges that intersect to form regular patterns on the mask trigger the growth of pillars beneath. Later, square and triangular packings of pillars develop in the regions enclosed by those ridges, preserving the registry from one domain to the next over a much larger area than within individual domains in unpatterned portions of the mask. Second, small square protrusions that are prealigned into a large regular array on the mask guide the formation of square packings of pillars in domains that conform to the mask, forming a large array of pillars. Novel structures involving a combination of linear ridges and pillars are also produced mainly due to the dynamic merging among preformed pillars. Finally, we find vertex symmetry of the mask pattern is necessary for generating and preserving ordered patterns on the polymer film.     

Effects of α‐form or β‐form nuclei on polymorphic crystalline morphology of poly(butylene adipate)

The effects of α‐form and β‐form nuclei on polymorphic morphology of poly(butylene adipate) (PBA) upon recrystallization from the molten state up to various T_max values were examined by differential scanning calorimetry (DSC), wide‐angle X‐ray diffraction (WAXD) and polarized light microscopy (PLM). In this study, PBA with complex melting and polymorphism behaviour was used as a model for examining different types and extents of residual nuclei. As the PBA initially containing the sole α‐crystal was brought to a molten state of various T_max, the extents of trace α‐form crystal nuclei varied and were dependent on T_max. Furthermore, it did not matter whether, initially, the PBA contained α‐ or β‐form crystals (or both) because only a single type of α‐nuclei could be left upon treatment to the molten liquid state at T_max. Therefore, only the α‐crystal in PBA had ‘memory capacity’ in the molten liquid state while the β‐crystal did not. This was so because the latter had been completely transformed into the solid state prior to being heated into a liquid. PBA crystallized before α‐nuclei could be packed into α‐crystal, regardless of the crystallization temperature (T_c). For recrystallization from molten PBA without any nuclei, the crystalline polymorphism was correspondingly influenced by T_c. Copyright © 2005 Society of Chemical Industry     

Adsorption and decomposition of H2S on Pd(1 1 1) surface: a first-principles study

Gradient-corrected density functional theory was used to investigate the adsorption of H₂S on Pd(1 1 1) surface. Molecular adsorption was found to be stable with H₂S binding preferentially at top sites. In addition, the adsorption of other S moieties (SH and S) was investigated. SH and S were found to be preferentially bind at the bridge and fcc sites, respectively. The reaction pathways and energy profiles for H₂S decomposition giving rise to adsorbed S and H were determined. Both H₂S_(ad) → SH_(ad) + H_(ad) and SH_(ad) → S_(ad) + H_(ad) reactions were found to have low barriers and high exothermicities. This reveals that the decomposition of H₂S on Pd(1 1 1) surface is a facile process.     

On the design of multiple key hashing files for concurrent orthogonal range retrieval between two disks

This paper concerns the following problem: given a set of multi-attribute records, a fixed number of buckets and a two-disk system, arrange the records into the buckets and then store the buckets between the disks in such a way that, over all possible orthogonal range queries (ORQs), the disk access concurrency is maximized. We shall adopt the multiple key hashing (MKH) method for arranging records into buckets and use the disk modulo (DM) allocation method for storing buckets onto disks. Since the DM allocation method has been shown to be superior to any other allocation methods for allocating an MKH file onto a two-disk system for answering ORQs, the real issue is knowing how to determine an optimal way for organizing the records into buckets based upon the MKH concept.

A performance formula that can be used to evaluate the average response time, over all possible ORQs, of an MKH file in a two-disk system using the DM allocation method is first presented. Based upon this formula, it is shown that our design problem is related to a notoriously difficult problem, namely the Prime Number Problem. Then a performance lower bound and an efficient algorithm for designing optimal MKH files in certain cases are presented. It is pointed out that in some cases the optimal MKH file for ORQs in a two-disk system using the DM allocation method is identical to the optimal MKH file for ORQs in a single-disk system and the optimal average response time in a two-disk system is slightly greater than one half of that in a single-disk system.     

冲击回波法检测隧洞混凝土衬砌厚度

冲击回波法是通过接收、分析在混凝土中传播的回波信号，判断结构混凝土厚度和内部质量的新型无损检测技术。室内试验和工程应用研究表明，该方法为隧洞混凝土衬砌厚度检测提供了一个有效的测试手段。     

三峡三期大坝工程大体积温控技术综述

葛洲坝集团公司在三峡三期大坝工程大体积混凝土施工中加强过程控制，采用优化减水剂参量、采用低热水泥和高效减水剂控制出机口温度，供料浅降温、仓面降温和保温，通冷水等。并应用新材料、新工艺，实行精细化管理，从2003年8月开工至今，浇筑了200万m^3大体积混凝土术出现一条裂缝，保证了施工质量。