Application of High Temperature Corrosion-Resistant Materials and Coatings Under Severe Corrosive Environment in Waste-to-Energy Boilers

Corrosion-resistant materials (CRMs) and coatings are key technologies to increase power generation efficiency and reduce maintenance in waste-to-energy (WTE) plants. Corrosion environment became severe as steam temperatures have increased. The steam condition of more than 400 °C/3.9 MPa became possible in WTE boilers by using highly durable corrosion-resistant coatings, such as thermal spray of Al/80Ni20Cr alloy, HVOF-sprayed NiCrSiB alloy, Alloy 625 weld overlay for waterwall tubes and also superheater tubes. Also, the use of 310S type stainless steels and high Cr-high Mo-Ni base and high Si-Cr-Ni-Fe alloys have progressed because of a better understanding of corrosion mechanisms. Furthermore, high durability coatings using cermet and ceramic materials were applied to high temperature superheaters. This paper describes the major developments and the application of CRMs and coating technologies in the last 30 years in WTE plants, the corrosion mechanisms of alloys, the deterioration mechanisms of spray coating layers, and future subjects for the development of corrosion-resistant materials and coatings.     

Effect of ultrasonic vibration on the dechromisation corrosion of a CuCr alloy in HCl solution

The effect of ultrasonic vibration on the dechromisation corrosion of a CuCr alloy in HC1 solution was studied and the corrosion mechanisms were analyzed. It is found that ultlasonic vibration reduces the dechromisation incubation time, accelerates the dechromisafion corrosion rate, decreases the temperature and concentration of HC1 solution, and when the dechromisation occurs it seriously weakens the microstmcture of dechromisation layer. It is concluded that ultrasonic vibration can accelerate destruction of the passivation film on the Cr surface and increase the activities of Cl^- and Cr.     

Hot dip fine Zn and Zn-Al alloy double coating for corrosion resistance at coastal area

A new hot dip Zn-7Al alloy coating was performed on a structural steel by double coating of fine Zn and Zn-7 wt.% Al alloy, to prevent severe corrosion in coastal area. The alloy-coated steels were exposed to seaside, quasi-industrial, and rural districts to compare with conventional Zn coating. Double coating was significantly effective in preventing corrosion, particularly in a seaside. It was estimated from the exposure test for 10 years that the life of the Zn-7Al alloy-coated steel would be almost four times that of the Zn-coated steel in the seaside. A bending test showed that no exfoliation occurred at the interface between the coated alloy and substrate steel. TEM observation revealed that the excellent adhesiveness of the doubly coated fine Zn and Zn-7Al alloy to the steel substrate was due to formation of the interface region consisting of heterogeneous fine phase mixture of zinc, aluminium and iron.     

蒸馏装置高含硫渣油部位的腐蚀失效分析

结合兰州某加工高硫高酸原油炼厂蒸馏装置渣油系统发生的腐蚀火灾事故，通过对失效设备进行元素含量分析、能谱分析、原子吸收光谱分析和表面形貌及断面形貌观察，认为高温渣油系统的腐蚀主要是高温硫的腐蚀。针对该系统的腐蚀特征，提出应重点采用耐蚀材质和腐蚀监测两项防腐对策。     

材料表面技术的研究及双辉技术在防腐蚀中的应用

文章简要介绍了化学气相沉积（CVD）、物理气相沉积（PVD）、高能束表面改性及其它表面处理技术的新进展,讨论了利用双辉离子渗技术处理后碳钢对酸液的耐腐蚀性能.经双辉技术处理后的碳钢试样在稀硫酸和富液中的耐腐蚀性能显著提高.     

热变形后低铬耐磨铸铁的组织与耐磨性的关系

研究了低铬耐磨铸铁经40％热变形及不同方式冷却后的组织与耐磨性的关系。结果表明：该铸铁经热变形后的组织与耐磨性有良好的对应关系，其耐磨性随硬度的增加而增大，同时也与组织中碳化物的形状、大小及分布有关。     

高温预析出对Al-Zn-Mg-Cu铝合金显微组织、强度和应力腐蚀抗力的影响

通过改变固溶条件 ,对Al Zn Mg Cu高强铝合金采用先高温后低温的两步固溶处理 (高温预析出 )来改善晶内和晶界的析出状态 ,研究了高温预析出对Al Zn Mg Cu铝合金的金相组织、强度和应力腐蚀性能的影响。结果表明 ,4 6 5℃高温预析出在保持较高强度和塑性的同时 ,可以改善合金的抗应力腐蚀性能     

热力管线中不锈钢波纹管破裂原因分析

采用金相显微镜和扫描电镜分析了热力管线中不锈钢 波纹管破裂原因.该波纹管破裂特征与一般环向开裂不同，裂纹沿轴向扩展.分析认为，破裂 属穿晶应力腐蚀.引起应力腐蚀的介质是土壤中的氯化物，而应力则来自环向工作应力和冷 加工残余应力，而环向工作应力起主导作用。     

一种用于高温无损检测的超声薄膜换能器

介绍一种新型压电薄膜换能器在400℃以上高温无损检测中的应用。压电薄膜的最大优点是可直接贴在金属工件上，也可贴在曲表面上，无需大量表面制备，无需声耦合剂，能实时监测在线高温设备的管壁腐蚀状态，为设备安全运行提供了有效保证。     

Optimization of spraying process and laser treatment of CoNiCrAlY

This article describes the investigation of a new generation of vacuum plasma sprayed CoNiCrAlY coatings on NiCr20Ti in the sprayed as well as the laser-treated condition. The aim of the study was the improvement of MCrAlY coating properties by modifying the microstructure through laser remelting with 5-kW Co₂: lasers. Parameter analysis and optimization was carried out for the vacuum plasma spraying process, as well as for the laser remelting technique. The effect of the laser treatment on microstructure, quality of the coatings, and oxidation as well as hot gas corrosion behavior are reported.