40Cr钢复合热处理强韧化

用光学及电子显微镜(SEM.TEM)观察不同热处理的40Cr 钢的冲击及断裂韧性断口、及金相组织,阐明其间相互关系;断口结构可反映断裂特征,组织情况;细化晶粒提高强度、塑性和冲击韧性,但却减少脆断的特性距离 l 因而降低 K_(1c)模;减少碳(杂质)偏聚而使其呈较均匀地分布,从而减少可诱发塑坑的较粗大的碳(杂质)化合物的析出,即增加塑坑的间距 di 以及增加塑断组成物。从而都可增加断裂临界应变 ef,都可以提高 K_(1c)40Cr 复合热处理既靠先超高温淬、回火以减少碳(杂质)偏聚,改善其分布,以反增加位错马氏体从而提高 K_(1c),也靠后淬、回火细化晶粒而提高强度、塑性和冲击韧性,各自发挥长处达到强韧化。     

锗酸铋（Bi4Ge3O12）单晶热物理性质的研究

本文用不同的测试技术和方法测定了锗酸铋(BGO)单晶的比热(300～800K)热膨胀系数(100～1100K)和导温系数(140～700K),进而导出了 BGO 单晶不同温度下的导热系数、定容比热、德拜温度和格虑内森数。本文还对 BGO 单晶热物理性质的变化规律作了理论解释。     

Hydrolytic stability and protective properties of polyurethane oligomers based on polyester/ether/polyols

The present study deals with effect of the type and chemical character of incorporated polyester/polyether blocks on the hydrolytic stability of crosslinked polyurethane oligomers. Diffusion parameters of the investigated polyurethane oligomers, giving information concerning chemical changes taking place in neutral, basic and acidic aqueous environments, have also been determined.     

Cold Gelation of β-lactoglobulin in the Presence of Iron

ABSTRACT: To protect and transport iron, we investigated the trapping properties of a network formed from β-lactoglobulin. We studied the influence of different parameters—pH, iron, and protein concentrations—on gel properties (optical and mechanical properties, WHC, and microstructure). For all conditions tested, the results show the formation of a cold gel in the presence of iron. The mechanical properties reveal that the elastic behavior and the strength of rupture increase with higher protein concentrations and decrease with higher iron concentrations. The water-holding capacity is high for low iron concentrations. The microstructure shows that, at low iron/protein ratios, a homogeneous filamentous network is obtained whereas, at high iron/protein ratios, more random aggregated particles are present.     

Thermophysical properties data: Government-university-industry cooperation in multidisciplinary research

Historical developments regarding the realization of the importance of reliable thermophysical properties data in engineering applications are presented. The events leading to the establishment of the Symposium on Thermophysical Properties in 1959 and the accomplishments of the symposia series since then are discussed. Contributions of the National Bureau of Standards to the thermophysical properties field are described.Welcoming address presented at the Ninth Symposium on Thermophysical Properties, June 24–27, 1985, Boulder, Colorado, U.S.A.     

Mechanical properties of poly(ether-ether-ketone) for engineering applications

An outline of the characteristics of PEEK and the versatility of its compositional forms (micro and macro composites) are given to illustrate its wide potential for success in engineering applications. Although it is necessary to have particular tabulations of mechanical properties for engineering design, these are seldom available and consequently it is argued that an understanding of stiffness, toughness and strength properties are required to fully exploit available manufacturer's data and thus develop the full potential of PEEK and its composites. Stiffness characteristics are considered in terms of a modulus function which is dependent on time under load and temperature. In its composite forms, whether reinforced with short or continuous fibres, stiffness anistropy can be both considerable and complex, but some empirical ground-rules are apparent. For continuous fibre composites even in the form of complex lay-ups, it is also possible to attempt some stiffness prediction from certain pseudo-elastic constants. Toughness of PEEK and its composites is described in terms of both comparative and intrinsic properties. Instrumented falling weight impact data, particularly as a function of temperature enable some insight into ductile-brittle transitions for the unreinforced material, but crack initiation and crack propagation processes for the various fibre reinforced forms. Intrinsic toughness is described in terms of linear elastic fracture mechanics theory. Strength properties are described for static and dynamic loading configurations. In particular, PEEK and its composites are evaluated for increasing test severities for strength characteristics; stress concentration, loading form and test temperature are considered.     

已二醇二丙烯酸酯对真丝的接枝改性研究

研究了用二醇二丙烯酸酯为接枝单体、过硫酸铵（APS）为引发剂对真丝的接枝共聚反应，分析了接枝率的影响素，并测试了改性真丝的主要应用性能。结果表明：乳液和乙醇/水为溶剂的2种体系都能在真丝上获得较高接枝率。对于乙醇/水体系v(乙醇）：v(H2O）=1:1，接枝单体20～30g/L,2%甲酸4ml，引发剂APS 0.5g/L,65～70℃接枝60min的接枝率高。改性后真丝的断裂强度、延伸度、吸湿性能都可获得改善，对酸、碱的溶解性提高，但染色性能提高不明显，对泛黄性改善一般。     

Synthesis and Spectral Properties of Mixed-Ligand Complexes of Lanthanide Perchlorate with Bis-(phenylsulfinyl)ethane and Organic Lewis Bases

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Recent developments of high-performance NEOMAX magnets

For further improvement in achieving extremely high magnetic properties of Nd- Fe- B sintered magnets, extensive investigation has been done to densify the magnet up to the theoretical value, to increase the volume fraction of the Nd ₂Fe₁₄B matrix phase, and to achieve a high degree of alignment. By controlling chemical composition and the amount of constituent phases,improving particle size distribution, and adopting the isostatic pressing method to get better alignment of fine particles, we have succeeded in obtaining a high-performance magnet having residual flux density (B_r) of 1.495 T (14.95 kG), maximum energy product [(BH)_max] of 431 kj/m³ (54.2 MGOe), and intrinsic coercivity (iH_c) of 845 kA/m (10.62 kOe).     

Development of ultra light magnesium-lithium alloys

Magnesium-lithium alloys are among the lowest density metallic materials. Addition of lithium, with a relative density of 0·53, in magnesium reduces the density of the alloy significantly. Furthermore, addition of nearly 11 wt.% lithium converts hexagonal close packed structure of pure magnesium to a body centered cubic lattice, markedly improving formability of the alloy. The development of these alloys, however, had been hampered due to the high reactivity of lithium and magnesium in the molten state and also, due to poor creep resistance and instability of mechanical properties at room temperature. In an attempt to indigenize these ultra light alloys for possible applications in Indian satellite programme, detailed research work was initiated in DMRL. The difficulties associated with producing sound cast ingots have been overcome by controlling melting and casting parameters of these alloys. Extensive work has been done on structure-property correlation of alloys with varying lithium content and minor alloying additions. Based on these work, advanced magnesium-lithium alloys have been developed with improved tensile properties, room temperature stability and creep resistance. Wrought products (plates/sheets) of magnesium-lithium alloy have been supplied to ISAC, Bangalore and are being used in their INSAT-2 programme. This paper describes the systematic studies carried out in the laboratory to indigenize these ultra light alloys.