The phosphorous level fine structure in homoepitaxial and polycrystalline n-type CVD diamond

The application of very sensitive photocurrent-based spectroscopic techniques have led to the detection of new levels for the electronic structure of the phosphorous donor in n-type CVD diamond. By combining quasi-steady-state photocurrent measurements (PC), photothermal ionisation spectroscopy (PTIS) and the highly sensitive Fourier transform photocurrent spectroscopy (FTPS) technique at different temperatures, ranging from liquid nitrogen temperature to 170 K, the resulting spectra point to a richer structure than assumed up to now. This is the consequence of the improved sample quality over the last years, opening up to a much larger attainable doping window. By using doping levels, ranging from 10¹⁹ cm⁻³ down to 10¹⁶ cm⁻³ on 111 -oriented Ib HPHT substrates, still giving rise to measurable n-type conductivity, spectra showed less line broadening and more fine structure. Finally, the results will be compared with spectra measured on active P-doped polycrystalline n-type films.     

磷铝酸盐水泥浆体的抗冻性研究

抗冻性是砼耐久性的重要方面,尤其影响北方地区砼工程的使用寿命。引气能提高砼的抗冻性,但同时又存在气泡的稳定性问题和砼其他性能的受损问题。若能提高砼中水泥浆体的抗冻性,则对提高砼耐久性更有意义。作者从宏观和微观两方面研究了磷铝酸盐水泥浆体的抗冻性,同时与硅酸盐水泥、硫铝酸盐水泥浆体进行了比较;采用压汞测孔方法测试了三种水泥浆体冻融前后的孔结构,并用分形理论分析了各自特征。结果证实:磷铝酸盐水泥具有优越的抗冻融性能,其自身优良的水化特性以及体系的低碱度是良好抗冻性的内在原因。     

料温对RIM交联型聚氨酯脲结构与性能的影响

采用便携式微型反应注射成型机制备了一组料温分别为３０，４０，５０，６０℃的交联型聚氨酯脲。用ＤＳＣ和力学性能对试样进行表征的结果表明：料温提高有利于软、硬微相的混合，而硬链段微区的有序性变差。反映在宏观力学性能上则表现为：试样的拉伸强度提高，伸长率在５０℃料温时出现极大值，弯曲强度和弯曲模量则出现最小值。料温为３０℃时，物料混合不充分，随着料温升高，混合逐渐均匀，试样透明度提高。     

传热设备自动清洗纽带的开孔结构优化研究

对设有开孔结构的自转清洗纽带进行了传热特性及流阻特性研究。结构优化试验的结果表明 :摩擦阻力和传热强化都随开孔面积比率的增大表现出先上升后下降的趋势 ,传热强化的幅度在 2 %— 18%之间 ,摩擦阻力系数在开孔率 18%时最大 ,其中 7#开孔比率纽带的综合性能最佳。因此 ,这种开孔结构的纽带更宜用于中低Re工况下应用 ,在 2 .0m/s以上的高流速工况下应采用高开孔率结构的纽带或螺旋带     

聚氯乙烯／蒙脱土复合材料的结构与性能研究

采用熔融共混法制备得到PVC／蒙脱土复合材料。通过X射线衍射和透射电镜对复合材料的结构进行了表征。研究了钠基蒙脱土和烷基季铵盐改性的有机蒙脱土对聚氯乙烯／蒙脱土复合材料的结构、加工热稳定性、光学性能、力学性能和结构流变性能的影响。     

聚合转化率对硫调型氯丁胶结构与性能的影响

研究了硫调型氯丁橡胶乳液聚合中转化率对产晶结构与性能的影响.结果表明,随单体转化率的提高,聚合物的凝胶量及其交联密度增大,致使断链速度减慢,所得断链胶的门尼粘度上升,残存凝胶量增加,分子支化程度增大,分子量分布变宽,焦烧时间缩短。而相应硫化胶的拉伸强度、撕裂强度、冲击弹性和硬度等提高,扯断伸长率和永久变形下降。这些变化一般在转化率为80——85％时有明显转折.综合考虑产量与质量,聚合转化率控制在82±2％较为适宜。     

高层级轮胎各层帘布裁断角度的计算方法

提出一种新的确定高层级轮胎内外各层帘布裁断角度的方法。根据各层帘布在成品胎内部的材料分布图和在成型机头上的材料分布图，计算该层所在的机头宽度，比较计算的机头宽度和实际的机头宽度，通过调整帘布裁断角度使两者近似相等。以此确定各层帘布的裁断角度，达到内外层帘线均匀伸张的目的。     

Detailed Molecular Structure Modeling – A Path Forward to Designing Application Properties of ldPE

Summary: This paper describes a step on the ambitious aim to “design” application properties of ldPE by first simulating the detailed molecular structure of a high‐pressure tubular reactor product. The reactor of a certain configuration produces under well‐defined operating conditions. The next step is to correlate the structure with the application properties. Finally, the sequence will be reversed in order to deduce the operating conditions, which lead to the desired product quality. Two‐dimensional distributions, in molecular weight and branching frequency, as well a two compartment models with a core and a shell stream were simulated and compared with experimental results. Therefore, CFD simulations were carried out to discretize the reaction medium. Samples were taken from both pilot and commercial plants. The TREF‐SEC analytical method was successfully applied in order to measure the microscopic structure of the material. The tremendous numerical problems were solved with the help of the software PREDICI .

Detailed MWD for a pilot scale reactor product.     

阀门内漏单声波传感器监测方法研究

针对阀门内漏模拟和阀门内漏监测问题，提出了阀门内漏模拟和阀门内漏非介入式单声波传感器监测方法。设计了由法兰、薄纸片和带孔铝片组成的虚拟阀门，可真实地模拟阀门内漏瞬态过程，克服了传统阀门内漏模拟方法中存在的各种缺点。分析、比较了不同条件下阀门上下游声波传感器输出信号的频域特征，验证了阀门上游声波传感器设置的冗余性和基于单声波传感器实现阀门内漏监测的可行性。分析、比较了不同条件下单声波传感器输出信号的时频域特征，提出了基于峰值系数和小波包能量分率的阀门内漏时频域特征提取方法，并以阀门密封良好状态下的声波信号为样本，建立了基于SVDD的阀门内漏诊断模型。测试结果表明：本文提出的单声波传感器阀门内漏监测方法可行、模型诊断准确，且具有较强的抗干扰能力和较高的阀门内漏检测灵敏度。