Grafting poly(t‐butyl acrylate) to poly(allylamine) by inverse microemulsion radical polymerization: From comb‐polymer to amphiphilic shell crosslinked polymer nanocapsule

An interfacial grafting radical polymerization method for amphiphilic comb copolymer and shell crosslinked polymer nanocapsules was reported. Macropolyradicals on a water soluble long chain polyamine were generated with hydrogen peroxide in the water phase and subsequent grafting radical polymerization of a vinylic monomer at the water/oil interface proceeded at 65°C. In the presence of a crosslinker, the resulting graft copolymer formed a defined core‐shell structure with hydrophilic aqueous core functionalized by the polyamine and a hydrophobic crosslinked polymer shell. The structure of the core‐shell material was characterized by NMR, FTIR, DSC, TGA, SEM, TEM, and the mechanism of the graft polymerization is proposed. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 1905–1911, 2007     

大开口高承载网格加筋壳的设计与工艺

本文采用有限元法计算了承受高轴压和外压作用下的大开口复合材料纵横密加筋壳的稳定性，得出不同铺层角度、不同受力工况下的大开口圆柱壳的临界载荷，并采用1：1试验件进行试验验证，将计算值与实验值进行了比较；对大开口复合材料纵横密加筋壳的缠绕工艺进行了研究，解决了大开口网格加筋壳开口补强的一次成型技术和密筋及开口部分的多丝嘴、无增量、非线性机械化缠绕成型工艺技术。     

Morphologies and dynamic mechanical properties of core‐shell emulsifier‐free latexes and their copolymers for P(BA/MMA)/P(MMA/BA) and P(BA/MMA)/PSt systems in the presence of AHPS

Different poly(methyl methacrylate/n‐butyl acrylate)/poly(n‐butyl acrylate/methyl methacrylate) [P(BA/MMA)/P(MMA/BA)] and poly(n‐butyl acrylate/methyl methacrylate)/polystyrene [P(BA/MMA)/PSt] core‐shell structured latexes were prepared by emulsifier‐free emulsion polymerization in the presence of hydrophilic monomer 3‐allyloxy‐2‐hydroxyl‐propanesulfonic salt (AHPS). The particle morphologies of the final latexes and dynamic mechanical properties of the copolymers from final latexes were investigated in detail. With the addition of AHPS, a latex of stable and high‐solid content (60 wt %) was prepared. The diameters of the latex particles are ～0.26 μm for the P(BA/MMA)/P(MMA/BA) system and 0.22–0.24 μm for the P(BA/MMA)/PSt system. All copolymers from the final latexes are two‐phase structure polymers, shown as two glass transition temperatures (T_gs) on dynamic mechanical analysis spectra. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3078–3084, 2002     

Monodisperse polymer/metal composite particles by electroless chemical deposition: Effect of surface functionality of polymer particles

Micron‐sized polymer particles were coated with layers of nickel compounds by plating electrolessly in the presence of aqueous solutions of nickel chloride, sodium hypophosphite, sodium citrate, and ammonium chloride at elevated temperature. The uniform functional polymer particle could be obtained by seeded polymerization. To investigate the effect of surface functionality on the conditions for nickel deposition, the polymer particle was functionalized with the thiol group. From morphological observation, it was found that the mode of nickel deposition was greatly dependent on the surface functionality of the polymer particle. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 420–424, 2003     

关于从ORACLE迁移数据到GBASE浅谈

近些年来,国产数据库逐步迈向市场化运作阶段,但由于用户相对较少,导致数据迁移资料较少,本文主要讲述怎样实现从前台营业及计费账务等oracle数据库提取基础数据到日常经营分析的gbase数据库。     

管壳式蒸汽加热器CAD研究

将数值分析方法应用于管壳式蒸汽加热器的工艺计算,很好地解决了试凑法的盲目性和计算工作繁重的问题,并在此基础上用VisualBasic语言开发了管壳式蒸汽加热器工艺CAD软件。     

Toughening of vinylester–urethane hybrid resins through functionalized polymers

Liquid nitrile rubber, hyperbranched polyester, and core/shell rubber particles of various functionality, namely, vinyl, carboxyl, and epoxy, were added up to 20 wt % to a bisphenol‐A‐based vinylester–urethane hybrid (VEUH) resin to improve its toughness. The toughness was characterized by the fracture toughness (K_c) and energy (G_c) determined on compact tensile (CT) specimens at ambient temperature. Toughness improvement in VEUH was mostly achieved when the modifiers reacted with the secondary hydroxyl groups of the bismethacryloxy vinyl ester resin and with the isocyanate of the polyisocyanate compound, instead of participating in the free‐radical crosslinking via styrene copolymerization. Thus, incorporation of carboxyl‐terminated liquid nitrile rubber (CTBN) yielded the highest toughness upgrade with at least a 20 wt % modifier content. It was, however, accompanied by a reduction in both the stiffness and glass transition temperature (T_g) of the VEUH resin. Albeit functionalized (epoxy and vinyl, respectively) hyperbranched polymers were less efficient toughness modifiers than was CTBN, they showed no adverse effect on the stiffness and T_g. Use of core/shell modifiers did not result in toughness improvement. The above changes in the toughness response were traced to the morphology assessed by dynamic mechanical thermal analysis (DMTA) and fractographic inspection of the fracture surface of broken CT specimens. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 672–680, 2002; DOI 10.1002/app.10392     

高效节能换热器在氮肥工业中的应用

描述了新型折流杆换热器的强化传热和降低壳层压力降的原理 ,它与传统折流板换热器相比 ,传热效率高 ,材料及能耗小。介绍了这种新型换热器在合成氨变换工段和尿素装置中的应用情况及所起的节能降耗作用 ,指出该高效节能换热器在设计和生产中的关键技术。     

包覆式超细复合粒子的制备

综述了包覆式超细复合粒子的制备技术，包括机械法，异相凝聚法，种子异相聚合法，微乳液和沉积法等，主要介绍了每种制备技术的原理及过程中应注意的问题，并介绍了它们的新发展。     

基于MEMS声传感器的圆柱壳体振动陀螺振型检测技术

振动陀螺谐振子振型一般采用激光进行非接触式测量,这种方法存在设备成本高、操作复杂、效率低等问题,因此,提出了一种基于MEMS声传感器的圆柱壳体振动陀螺谐振子振型测试方法。该方法利用体积小,指向性高的MEMS声传感器对谐振子振动声场进行高分辨率测量,获得精确的谐振子振动分布情况,建立了谐振子声波测试实验系统,进行了测试实验,并与激光测振仪的测量结果进行比对。实验结果表明,该测试系统具有较高的振型测量精度。这种测试方法成本低,操作简便,测量精度高,可以实现谐振子振型的高精度快速测量,为后续的谐振子修形及陀螺控制提供重要基础。