X-ray fluorescence spectrometry determination of open-hearth furnace slag by pressed powder briquetting

Chemical composition of open-hearth furnace slag isimportant for the metal and casting quality. The chemicalcomponents of slag need to be analyzed precisely andaccurately.For a long time the composition determination of slag ismade chemically, which involves complicated processes,long analytical cycle, high cost and tedious work. A greatmany successful applications of ores analysis by x-rayfluorescence spectrometry (XRF) have been reported[1-4].Powder-fused wafer is a sampling method used in…     

B2O3-CaO、CaF2-CaO对LATS钢包渣的调质处理实验

为减少LATS合金化精炼浸渍罩粘渣,分别采用B2O3-CaO和CaF2-CaO作调质剂对钢包渣进行调质处理实验.调质后熔渣物性研究结果表明:两种调质剂都有效地降低了钢包渣的熔点和粘度.硫在渣-金属间分配平衡实验表明,调质后的钢包渣不会引起钢液回硫,而且可使钢中的硫含量进一步降低.     

电工钢钢包渣结壳问题分析

针对电工钢生产过程中钢包渣结壳的现象,与不结壳渣进行对比,从物质的组成,物相和黏度等3个方面进行了分析。结果表明,随着温度的降低,炉渣中析出大量的高熔点物相如MgO、尖晶石(MgO·Al₂O₃)、2CaO·SiO₂等,在炉渣中起到“钉扎”强化作用的同时又能导致炉渣的黏度增加,失去流动能力,从而容易黏附在一起结块成壳。此外,提出了预防钢包渣结壳的有关措施。     

COUPLING PROCESS FOR Ti AND Si BETWEEN TITANIA SLAGS AND Cu MELTS AT 1500 ℃

ＣＯＵＰＬＩＮＧＰＲＯＣＥＳＳＦＯＲＴｉＡＮＤＳｉＢＥＴＷＥＥＮＴＩＴＡＮＩＡＳＬＡＧＳＡＮＤＣｕＭＥＬＴＳＡＴ１５００℃￥Ｘｕｅ，Ｘｉａｎｇｘｉｎ；Ｃｈｅ，Ｙｉｎｃｈａｎｇ（ＤｅｐａｒｔｍｅｎｔｏｆＦｅｒｒｏｕｓＭｅｔａｌｌｕｒｇｙ，Ｎｏｒｔｈｅａ...     

温度和气氛对CaO-SiO2-Al2O3-MgO-FetO渣系磷容量的影响

采用气-渣-金平衡法测定CaO-SiO2-Al2O3-MgO-FetO渣系的磷容量,用钼坩埚作为反应容器,Ag-0.2%P合金作为气-渣-金平衡的熔剂,CO-CO2-Ar混合气体提供体系的氧分压,分析了温度和气氛对该渣系磷容量的影响.结果表明,对于一定成分的炉渣,当体系CO、CO2、Ar组成一定时,随着温度由1 723 K增加到1 823 K,CaO-SiO2-Al2O3-MgO-FetO渣系的磷容量降低;在1 773 K,气氛中氧分压由3.6×10-5 Pa增大到7.2×10-4 Pa时,磷容量随着氧分压的增大而增大.     

硅渣中金属离子的分离和利用

本实验研究了硅渣用盐酸处理后，加入动物胶，分离出硅，然后通过调节pH值，让溶液中的钙、钠、铝分离开。钙、铝的化合物，过滤后回到氧化铝流程，进行再利用，溶液通过浓缩结晶，回到生产硅产品的流程中去，氧化钠回收利用。本试验为探索出硅渣处理，促进氧化铝生产的发展，搞好环境保护和提高经济效益，提供重要方法。     

含B2O3渣系的热力学计算模型

根据炉渣结构的共存理论和相图，推导了ＣａＯＢ２Ｏ３和ＦｅＯＦｅ２Ｏ３Ｂ２Ｏ３渣系的热力学计算模型。结果表明：（１）理论计算的ＣａＯＢ２Ｏ３渣系的作用浓度ＮＣａＯ及ＮＢ２Ｏ３与实测的活度ａＣａＯ及ａＢ２Ｏ３一致；（２）理论计算的ＦｅＯＦｅ２Ｏ３Ｂ２Ｏ３渣系的氧化能力ＮＦｅｔＯ与实测的炉渣ＦｅｔＯ的活度值相符合。这说明本文提出的热力学计算模型是合理的。     

钒铁渣在七星水库面板加固中的应用

钒铁渣作为水泥基材料的掺和料,有明显的补偿收缩和提高抗裂性作用。单掺粉煤灰、复掺钒铁渣和粉煤灰混凝土的压拉强度比（抗压强度／劈拉强度）均高于纯水泥混凝土,尤其以复掺钒铁渣和粉煤灰混凝土更优。将其应用于混凝土面板中,能够抑制收缩,减少裂缝,提高混凝土结构的耐久性。     

Phase Equilibrium studies in the system “FeO”–SiO2–Al2O3–CaO–MgO at 1200 °C and Po2 10-8atm

Iron oxides and silica are the major components of copper smelting slag. The oxides of aluminum, calcium and magnesium are also present in the slag that is introduced through copper concentrate, flux and refractories. Liquidus temperatures of the copper smelting slags are usually controlled by Fe/SiO₂. The concentrations of Al₂O₃, CaO and MgO, and FeO/Fe₂O₃ in the slag can also affect the liquidus temperatures where FeO/Fe₂O₃ is a function of oxygen partial pressure. High temperature equilibration under controlled oxygen partial pressure followed by quenching and electron probe microanalysis were used to determine the compositions of the liquid and solid phases at 1200 °C and Po₂ 10^-8 atm. The experimental results are presented in the forms of pseudo-ternary sections “FeO”-CaO-SiO₂ at fixed 2, 4 and 6 wt pct MgO, and 2 + 2, 4 + 4 and 6 + 6 wt pct MgO + Al₂O₃. Spinel and tridymite are the major primary phases in the composition range investigated. In addition, CaSiO₃, pyroxene, olivine, and melilite are also present. The isotherms in the spinel and tridymite primary phase fields move towards higher SiO₂ concentration directions with increasing CaO, Al₂O₃, and MgO concentrations. The experimentally determined results are compared with the FactSage calculations.     

Iron working at Zambana el Vato (TN), Italy

ABSTRACT

The workshop of Zambana el Vato (region Trentino, Northern Italy), is dated to the period between the 7th-6th and the 5th century BC. Iron working activities are clearly recognizable from the various finds. Among them there are working slag, heated clay, fragments of hearth or forge, hammerscale and more residues that can be referred to iron technology. A number of selected specimens were sectioned and mounted for photomicroscopy to identify the structure and some of the mounted samples were also examined by scanning electron microscopy (SEM) using both a back scattered electron detector and energy dispersive (EDS) x-ray analysis. This paper presents the results of these studies. The hearths were regularly repaired, as their fragments were found mixed with working slag. The hammerscale samples indicate that there were three iron-working areas. The fragments of forge with traces of tuyeres indicate that bellows were employed. Refining slag was identified among the debris. This is particularly significant as for the moment no iron refining centers are known in this area.