全文获取类型
收费全文 | 11666篇 |
免费 | 1089篇 |
国内免费 | 1017篇 |
专业分类
电工技术 | 390篇 |
综合类 | 518篇 |
化学工业 | 3167篇 |
金属工艺 | 997篇 |
机械仪表 | 519篇 |
建筑科学 | 111篇 |
矿业工程 | 184篇 |
能源动力 | 653篇 |
轻工业 | 157篇 |
水利工程 | 19篇 |
石油天然气 | 155篇 |
武器工业 | 66篇 |
无线电 | 2563篇 |
一般工业技术 | 2396篇 |
冶金工业 | 1341篇 |
原子能技术 | 160篇 |
自动化技术 | 376篇 |
出版年
2024年 | 39篇 |
2023年 | 188篇 |
2022年 | 271篇 |
2021年 | 304篇 |
2020年 | 326篇 |
2019年 | 284篇 |
2018年 | 241篇 |
2017年 | 354篇 |
2016年 | 380篇 |
2015年 | 433篇 |
2014年 | 594篇 |
2013年 | 595篇 |
2012年 | 792篇 |
2011年 | 881篇 |
2010年 | 565篇 |
2009年 | 682篇 |
2008年 | 559篇 |
2007年 | 717篇 |
2006年 | 681篇 |
2005年 | 593篇 |
2004年 | 520篇 |
2003年 | 578篇 |
2002年 | 482篇 |
2001年 | 426篇 |
2000年 | 439篇 |
1999年 | 242篇 |
1998年 | 230篇 |
1997年 | 196篇 |
1996年 | 179篇 |
1995年 | 150篇 |
1994年 | 112篇 |
1993年 | 98篇 |
1992年 | 116篇 |
1991年 | 120篇 |
1990年 | 141篇 |
1989年 | 117篇 |
1988年 | 28篇 |
1987年 | 17篇 |
1986年 | 11篇 |
1985年 | 7篇 |
1984年 | 12篇 |
1983年 | 7篇 |
1982年 | 11篇 |
1981年 | 8篇 |
1980年 | 7篇 |
1979年 | 14篇 |
1978年 | 6篇 |
1977年 | 5篇 |
1976年 | 5篇 |
1975年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
A silicide coating was prepared on Ti3SiC2-based ceramic by pack cementation to improve the oxidation resistance of Ti3SiC2, which is a technologically important material for high temperature applications. The microstructure, phase composition and
oxidation resistance of the coated sample were investigated. The results demonstrated that the silicide coating was mainly
composed of TiSi2 and SiC. A single layer of a mixture of SiO2 and TiO2 was formed on the surface of the coated sample during isothermal oxidation at 1100 °C and 1200 °C for 20h. Compared to Ti3SiC2, the parabolic rate constant of silicide coated Ti3SiC2 decreased by 2~3 orders of magnitude. Furthermore, the coated sample showed much better cyclic oxidation resistance than
Ti3SiC2 during the cyclic oxidation at 1100 °C for 400 times. However, during the preparation of the coating, a number of fine cracks
formed in the outer layer of the coating. When these cracks penetrated the whole coating during the cyclic oxidation, the
oxidation rate was accelerated, which degraded the oxidation resistance.
Electronic Publication 相似文献
22.
In this paper we discuss the different models proposed to explain the visible luminescence in porous silicon (PS). We review
our recent photoluminescence and Raman studies on PS as a function of different preparation conditions and isochronal thermal
annealing. Our results can be explained by a hybrid model which incorporates both nanostructures for quantum confinement and
silicon complexes (such as SiH
x
and siloxene) and defects at Si/SiO2 interfaces as luminescent centres. 相似文献
23.
本文对氧化非晶硅磷掺杂的工艺条件进行了研究,得出掺磷氢化非晶硅的电导率随衬底温度、气体流量、气体压力、射频功率、淀积时间的变化关系,为非晶硅的有效掺杂和器件研究提供了依据。 相似文献
24.
Fracture toughness and fatigue crack propagation (FCP) of plain and modified anhydride-cured epoxy resin (EP) were studied at ambient temperature. Liquid carboxyl-terminated acrylonitrile-butadiene (CTBN) and silicon (SI) rubber dispersions were used as tougheners for the EP. The morphology of the modified EP was characterized by dynamic mechanical analysis (DMA) and by scanning electron microscopy (SEM). The fracture toughness, Kc, of the compositions decreased with increasing deformation rate. Kc of the EP was slightly improved by CTBN addition and practically unaffected by incorporation of the SI dispersion when tests were performed at low cross-head speed, v. Both modifiers improved Kc at high v, and also the resistance to FCP, by shifting the curves to higher stress intensity factor ranges, ΔK, by comparison with the plain EP. It was established that both fracture and fatigue performance rely on the compliance, JR, at the rubbery plateau, and thus on the apparent molecular mass between crosslinks, Mc. The failure mechanisms were less dependent upon the loading mode (fracture, fatigue), but differed basically for the various modifiers. Rubber-induced cavitation and shear yielding of the EP were dominant for CTBN, whereas crack bifurcation and branching controlled the cracking in SI-modified EP. The simultaneous use of both modifiers resulted in a synergistic effect for both the fracture toughness at high deformation rate and the FCP behavior. 相似文献
25.
树脂热解炭制备碳化硅晶须 总被引:6,自引:1,他引:5
用自制的配合醛树脂热解和炭源,用SIO2超细汾作原,根据碳热还原原理,利用常规加热和微波加热两种方式,分别制备了直径在纳米级的SiC晶须,X射线衍射、透射电检测结果表明:制备工艺和条件对SiC晶须的性质有较大的影响。 相似文献
26.
驻极体声传感器及其储电材料的现状 总被引:1,自引:0,他引:1
综述了驻极体声传感器及其储电材料近年来的迅猛发展。传统的FEP(tetrafluoroethylene—hexa—fluoropropylene copolymer)极体电容式声传感器及以铁电聚合物PVDF(poly vinylidene fluoride)家族为芯片的声传感器和超声抉能器仍焕发着青春活力。Si基微型驻极体声传感器的理论和实验研究已经日趋成熟,而用空间电荷型多孔聚合物驻极体压电薄膜为芯片可望研制出新一代声电和电声传感器、压力传感器和驱动器。 相似文献
27.
At high temperatures in clean oxidizing environments, SiC forms a very protective SiO2 film, but, in environments containing low levels of gaseous alkali salt contaminants or where condensed salts may deposit on the surface, the resistance of the film is significantly reduced. Oxidation kinetics of SiC were measured by continuous thermogravimetric analysis in a controlled environment containing CO2 , H2 O, and O2 plus low levels of potassium-containing salts. Potassium was found to be incorporated into the SiO2 scale and to significantly change its transport properties and its morphology. The rate of scale formation was found to increase directly in proportion to K in the scale. A change in mechanism was observed when water vapor was added to the reacting gas stream. 相似文献
28.
David C. Apperley Robin K. Harris Gregory L. Marshall Derek P. Thompson 《Journal of the American Ceramic Society》1991,74(4):777-782
The 29 Si MAS NMR spectra of the 2H, 4H, 6H, and 3C polytypes of silicon carbide are presented. An attempt is made to correlate differences in the chemical shifts with local atomic environment. The results of the analysis of the spectra of pure polytypes are used as a basic for the interpretation of the spectra of mixed polytypes and a discussion of the crystallinity and impurity levels of different samples. Carbon-13 chemical shifts obtained from spectra of the same polytypes are also tabulated. 相似文献
29.
Y. Cohen K. Landskron N. Ttreault S. Fournier‐Bidoz B. Hatton G.A. Ozin 《Advanced functional materials》2005,15(4):593-602
The synthesis and characterization of a novel silicon–silica nanocomposite material are reported. A self‐assembly method allows the encapsulation of silicon nanoclusters within the channels of a periodic mesoporous silica thin film. The result is the formation of a silicon–silica nanocomposite film with bright, room‐temperature photoluminescence in the visible range, and a nanosecond luminescence lifetime. The properties of the nanocomposite material have been studied by several analytical techniques, which collectively show the existence within the channels of non‐diamondoid‐structure‐type silicon nanoclusters with various hydrogenated silicon sites. It is estimated that the silicon nanoclusters in the silica mesoporous films occupy up to 39 % of the accessible pore volume. The nanocomposite film shows improved resistance to air oxidation compared to crystalline silicon. The high loading and chemical stability to oxidation under ambient conditions are important advantages in terms of the development of silicon‐based light‐emitting diodes from this class of materials. 相似文献
30.
Scott C. Thompson Anjali Pandit Nitin P. Padture Subra Suresh 《Journal of the American Ceramic Society》2002,85(8):2059-2064
The processing of stepwise graded Si3 N4 /SiC ceramics by pressureless co-sintering is described. Here, SiC (high elastic modulus, high thermal expansion coefficient) forms the substrate and Si3 N4 (low elastic modulus, low thermal expansion coefficient) forms the top contact surface, with a stepwise gradient in composition existing between the two over a depth of ∼1.7 mm. The resulting Si3 N4 contact surface is fine-grained and dense, and it contains only 2 vol% yttrium aluminum garnet (YAG) additive. This graded ceramic shows resistance to cone-crack formation under Hertzian indentation, which is attributed to a combined effect of the elastic-modulus gradient and the compressive thermal-expansion-mismatch residual stress present at the contact surface. The presence of the residual stress is corroborated and quantified using Vickers indentation tests. The graded ceramic also possesses wear properties that are significantly improved compared with dense, monolithic Si3 N4 containing 2 vol% YAG additive. The improved wear resistance is attributed solely to the large compressive stress present at the contact surface. A modification of the simple wear model by Lawn and co-workers is used to rationalize the wear results. Results from this work clearly show that the introduction of surface compressive residual stresses can significantly improve the wear resistance of polycrystalline ceramics, which may have important implications for the design of contact-damage-resistant ceramics. 相似文献