全文获取类型
收费全文 | 126篇 |
免费 | 5篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 1篇 |
综合类 | 1篇 |
化学工业 | 115篇 |
机械仪表 | 1篇 |
轻工业 | 6篇 |
无线电 | 3篇 |
一般工业技术 | 5篇 |
出版年
2023年 | 1篇 |
2021年 | 1篇 |
2019年 | 3篇 |
2018年 | 1篇 |
2017年 | 3篇 |
2016年 | 4篇 |
2015年 | 2篇 |
2014年 | 2篇 |
2013年 | 3篇 |
2012年 | 8篇 |
2011年 | 8篇 |
2010年 | 5篇 |
2009年 | 8篇 |
2008年 | 10篇 |
2007年 | 6篇 |
2006年 | 12篇 |
2005年 | 10篇 |
2004年 | 10篇 |
2003年 | 19篇 |
2002年 | 5篇 |
2001年 | 3篇 |
1999年 | 2篇 |
1994年 | 1篇 |
1992年 | 3篇 |
1991年 | 1篇 |
1989年 | 1篇 |
排序方式: 共有132条查询结果,搜索用时 15 毫秒
31.
In this study, the effects of thermally conductive filler type (α‐Al2O3, SiC), volume fraction of the filler, and filler particle size distribution on the thermal conductivity and viscosity of room‐temperature‐vulcanized (RTV) silicone rubber and silicone grease were investigated. We were interested to find that silicone grease (or the RTV silicone rubber) had a maximum thermal conductivity (~1.48 W/mK) and a minimum viscosity (~3.4 × 104 mPa s), with a definite total volume fraction of the filler (0.55) when the distribution of filler sizes (the number ratio of two different particles sizes, i.e., 0.8 and 6 μm) was 600–700. We were able to increase the thermal conductivity of the RTV silicone rubber and silicone grease beyond 2 W/mK by increasing the total volume fraction of the filler with adequate filler size distributions. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2397–2399, 2003 相似文献
32.
Hideo Sawada Hitomi Horiuchi Tokuzo Kawase Kazuya Oharu Hideki Nakagawa Isamu Kaneda 《应用聚合物科学杂志》2005,96(4):1467-1476
Fluoroalkyl end‐capped cooligomers containing polydimethylsiloxane and polyoxyethylene segments were prepared under very mild conditions by the cooligomerizations of fluoroalkanoyl peroxides with methacrylate monomers containing the corresponding segments and comonomers such as dimethylacrylamide and acryloylmorpholine. These obtained fluorinated cooligomers exhibited amphipathic characteristics and became soluble in water and common organic solvents. In particular interest, fluoroalkyl end‐capped cooligomers containing polyoxyethylene units were soluble not only in poly(methylphenylsiloxane) (silicone oil) but also in water, including common organic solvents except for hexane. Additionally, these fluorinated cooligomers were able to reduce the surface tension of water and m‐xylene quite effectively, to around 15 and 20 mN/m levels, respectively. In these fluorinated cooligomers, fluoroalkyl end‐capped acryloylmorpholine cooligomers containing polyoxyethylene segments were applicable as a novel emulsifying agent against water and silicone oil. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 1467–1476, 2005 相似文献
33.
Ultraviolet (UV)/moisture dual‐curable polysiloxane acrylates (PSAs) were prepared from N,N‐bis[3‐(triethoxysilyl)propyl]amine (G402) and ethoxylated trimethylolpropane triacrylate (EB160) through Michael addition. The obtained prepolymers were characterized by 1H‐NMR and FTIR. The rheological behavior of the prepolymers exhibited the properties of a Bingham fluid and the apparent viscosity was directly correlated with molecular weight. The photocuring kinetics of PSA were studied using photo‐DSC and all the polymerization conversions were high. With increasing content of tertiary amine in the prepolymer, the photocuring rate in air increased as well. The moisture‐curing kinetics of the prepolymers was studied using FTIR. It was found that the curing mechanism may be described as the transforming of Si O C into Si O Si structure, which was consistent with the theoretical expectation. DSC and TGA were used to characterize the glass‐transition temperatures and the thermomechanical stability of the prepolymers. Measurements of physical properties showed excellent gloss, impact strength, and high electric resistance for both UV‐ and moisture‐cured films, but poor adhesion for UV‐cured films and lower hardness for moisture‐cured films. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 846–853, 2005 相似文献
34.
It is common for crude oil from wells to be accompanied by gas and water because of the presence of natural surfactants in the oil that stabilize the associated water. This causes foaming during processing in gas/oil separators because of the constant agitation and shear forces, which reduce the efficiency of the process and require chemical control by the addition of defoaming additives, or antifoams. In this work, we evaluated the chemical and physicochemical properties of commercial antifoam products based on silicone polyethers along with their efficiency in inhibiting foaming and water/oil (W/O) phase separation. The commercial surfactants were characterized by NMR spectroscopy, size exclusion chromatography, determination of solubility in different solvents, and measurement of the surface and interfacial tensions. A method to test the formation of foam in oil was used to mimic the operating conditions in gas/oil separators. Finally, tests were performed with the addition of aliquots of the additive solutions (30% p/v) in oil to evaluate their efficiency in breaking up the foam under different conditions. The results show that the most polar additive (SL2) was the most efficient in breaking up the foam. Additive SP1, which formed a heterogeneous phase in the oil, was also an efficient foam inhibitor and helped to separate these phases. The antifoam tests showed that these additives did not stabilize W/O emulsions, so they could be used in gravitational separation tanks in the field. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
35.
Marco Cocconcelli 《The Journal of Adhesion》2017,93(8):585-598
The use of accelerometers to monitor the vibrations of either complex machinery or simple components involves some considerations about the mounting of the sensor to the structure. Different types of mounting solutions are commonly used, but in all cases they can be classified in one of these categories: stud mounting, screw mounting, adhesive mounting, magnetic mounting, and probe sensing. Indeed, each of them has a specific field of application depending on e.g. the mounting surface conditions, the temperature, the accessibility to the specific mounting point, etc. The choice of the mounting solution has an important effect on the accuracy of the usable frequency response of the accelerometer, since the higher the stiffness of the fixing, the higher the low-pass frequency limit of the mounting. This article specifically focuses on adhesive mounting of accelerometers, which includes a great number of different products from the temporary adhesives like the beeswax to the permanent ones like cyanoacrylate polymers. Among the variety of commercial adhesives, three specific products have been experimentally compared to assess their transmissivity and the results are reported in this article. A two-component methylmethacrylate (HBM X60), a modified silane (Terostat 737), and a cyanoacrylate (Loctite 454) adhesive have been used to join two aluminum bases, one connected to an accelerometer and the other to the head of electromagnetic shaker. A design of experiment (DOE) approach was used to test the system at several levels of amplitude and frequency of the external sinusoidal excitation supplied by the shaker. 相似文献
36.
The homogeneous dispersion of nanofillers and filler–matrix interfacial interactions are important factors in the development of high‐performance polymer materials for various applications. In the present work, a simple solution‐mixing method was used to prepare multi‐walled carbon nanotube (MWCNT)–graphene (G) (3:1, 1:1, 1:3) hybrids followed by their characterization through wide‐angle X‐ray diffraction, transmission electron microscopy and thermogravimetric analyses. Subsequently, MWCNT–G (1:1) hybrid was used as reinforcing filler in the formation of silicone rubber (VMQ) nanocomposites by solution intercalation, and their morphology and properties were investigated. Our findings showed that MWCNT–G (0.75 wt%)/VMQ composite exhibited significant improvements in tensile strength (110%) and Young's modulus (137%) compared to neat VMQ. The thermal stability of MWCNT–G (1 wt%)/VMQ was maximally improved by 154 °C compared to neat VMQ. Differential scanning calorimetry demonstrated the maximum improvement of glass transition temperature (4 °C), crystallization temperature (8 °C) and melting temperature (5 °C) for MWCNT–G (1 wt%)/VMQ nanocomposite with respect to neat VMQ. Swelling measurements confirmed that the crosslink density and solvent resistance were a maximum for hybrid nanocomposites. Such improvements in the properties of MWCNT–G/VMQ nanocomposites could be attributed to a synergistic effect of the hybrid filler. © 2013 Society of Chemical Industry 相似文献
37.
氨基硅油的合成和表征及应用 总被引:5,自引:0,他引:5
介绍了氨基硅油的各种合成方法(如本体聚合法、乳液聚合法和硅氢化加成法等)以及它们各自的特点;并概述了氨基硅油的表征方法;重点介绍了氨基硅油在纤维(如织物、纸张和皮革)的整理、树脂(如聚氨酯、环氧树脂和丙烯酸树脂)改性、脱模剂、个人洗护用品(如洗发香波、牙膏)和抛光剂等方面的应用;最后展望了氨基硅油的应用前景。 相似文献
38.
Impressive Rate Raise of the Hydrosilation Reaction Through UV‐Activation: Energy and Time Saving 下载免费PDF全文
Silicone materials are widely used in many fields such as electrical or food industries and their consumption is constantly growing. They are generally cured by vulcanization reaction for long time at high temperatures which requires high energy consumption. The possibility to achieve the polymerization of silicone rubbers by UV‐activation promotes the reduction of both time and temperature leading to an impressive energy saving. Indeed, this process is more than 30 times faster than the thermal one. Moreover, the properties of the two resulting materials are comparable, indicating that the low time of UV‐activated hydrosilation reaction is suitable for the formation of crosslinked silicone polymers.
39.
Epoxy‐terminated siloxane‐contained resin (BCDS/OBBA‐ETS) with high tensile strength and lap shear strength as well as good thermal stability was synthesized and characterized by 1H‐NMR and Fourier transform infrared spectroscopy. Carboxy‐capped disiloxane‐4,4′‐oxybis (benzoic acid) ester oligomer (BCDS/OBBA) was firstly prepared from the reaction between 1,3‐bis(chloromethyl)‐1,1,3,3‐tetramethyl‐disiloxane and 4,4′‐oxybis(benzoic acid) (OBBA) in N,N‐dimethylformamide in the presence of triethylamine. Then, the BCDS/OBBA oligomer was reacted with epichlorohydrin to obtain the title BCDS/OBBA‐ETS resin. Cured with liquid polyamide L‐651, or diethylenetriamine, the mechanical and thermal properties as well as the lap shear strength of the BCDS/OBBA‐ETS resin were evaluated. The results indicated that the BCDS/OBBA‐ETS resin exhibited good thermal stability below 200°C, and the glass transition temperature (Tg) was about 64°C after cured with L‐651. The tensile strength of same cured BCDS/OBBA‐ETS resin was 27.46 MPa with a stain at break of 42.11%, and the lap shear strength for bonding stainless steel was 18.59 MPa. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
40.
In a study about silicone contamination on surfaces, crosslinked polydimethylsiloxanes have been examined focusing on the curing process and the noncrosslinked part in the bulk of the material. Curing was studied by following the development of gel as a function of curing time and temperature using Soxhlet extraction and differential scanning calorimetry (DSC) measurements. Gas chromatography–mass spectroscopy (GC‐MS), size exclusion chromatography (SEC), and thermogravimetric analysis (TGA) analyses gave information about the composition and size of the noncrosslinked fraction. The experiments demonstrate that the curing kinetics are of Arrhenius type with a strong temperature dependence. Interestingly, we find that 5–20% of the material does not undergo crosslinking reactions, although only 0–1% of the total sample mass is volatile at ambient temperature and pressure. It is likely that the volatile components mainly give rise to problems when they are confined to closed compartments or when they are in direct contact with a cold surface so that condensation on the surface occurs. Most likely, surface contamination originates from the nonvolatile fraction of the noncrosslinked portion of the material. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 2073–2081, 2003 相似文献