PREPARATION OF SILVER POWDER FOR CONDUCTIVE PASTE

ＰＲＥＰＡＲＡＴＩＯＮＯＦＳＩＬＶＥＲＰＯＷＤＥＲＦＯＲＣＯＮＤＵＣＴＩＶＥＰＡＳＴＥＣｈａｉ，Ｌｉｙｕａｎ；Ｚｈｏｎｇ，Ｈａｉｙｕｎ；Ｗｕ，Ｈｕｉｙｕｎ（ＤｅｐａｒｔｍｅｎｔｏｆＮｏｎｆｅｒｒｏｕｓＭｅｔａｌｌｕｒｇｙ，ＣｅｎｔｒａｌＳｏｕｔｈＵｎ...     

AgNO3浓度对SPE电极镀覆纳米Ag的影响

采用浸渍还原法(I-R法)在Nafion离子膜上镀覆纳米Ag,并就AgNO3浓度对SPE电极镀覆纳米银的影响作了研究.研究表明采用I-R法可制得细致Ag镀层,有效增加Ag的分散度及电极的真实面积.在还原剂浓度为0.1mol·L-1,浸渍还原温度均为50℃及浸渍还原时间分别为40 min,60 min的条件下,调节浸渍液AgNO3浓度至3.5 mmol·L-1时,可获得致密、均匀的纳米级Ag/SPE电极.同时验证砂纸糙化的预处理有利于增加Ag的负载和附着力,有利于提高Ag催化层的有效面积.     

改善银首饰铸造质量的措施

斯特林银首饰铸造时经常会出现气孔、缩孔、砂眼、氧化物夹杂等,其原因主要来自2个方面,一是在铸造过程中各工序的操作不当,尤其是水线的设置、开粉操作、焙烧制度等关键工序,必须加强操作过程的控制;二是与银本身的性质有关,银在凝固时氧的溶解度骤减,气体容易析出导致气孔;斯特林银主要以铜作为合金化元素,容易氧化形成夹杂。在熔炼或铸造过程中要尽量避免金属液接触大气,采用真空、或使用惰性气体、还原性火焰、硼酸等进行保护,可以减少铸造缺陷的发生。     

低温烧结SrBi4Ti4O15／Ag复合材料的制备及其介电特性

摘要：采用固相烧结工艺制备了SrBi4Ti4O15(SBTi)／Ag铁电复合材料，通过X射线衍射、光学金相显微镜和扫描电子显微镜对材料的组成和微观结构进行了研究，并测量样品的介电温度谱。结果表明：复合材料是由SBTi和Ag两相组成。微量金属Ag的加入使SBTi铁电陶瓷的烧结温度从1120℃降低到950℃以下：可以适当提高铁电陶瓷从室温到200℃的介电常数，但对材料的介电损耗影响很小。同时Ag的加入压抑了介电温度曲线上的介电常数的Curie峰。     

Ageing characteristics and microstructure of Al-4Mg-1.5Cu alloys containing silver and lithium

1　INTRODUCTIONTheroleoftraceelementsonageingofAlalloyshasbeenextensivelystudiedandhasbeenrecentlyre viewedbyPolmear ,RingerandPrabhuetal[14 ] .Itwasfoundthatthesmalladditionofsilvercanstimu lateenhancedagehardeningincertainAl Cu Mgal loys,andthiseffectisevidentforawiderangeofcompositionsselectedinthe (α +θ) ,(α +S)and (α+S +T ) phasefieldsoftheternary phasedia gram[57] .TheadditionofAgtoAl Cu MgalloyswithhighCutoMgratiosstimulatestheformationofanhexagonal shaped precipitate pha…     

A novel electroless silver depositing method for magnesium alloys

Depositing silver on magnesium alloy by both electroless plating and organic coatings was studied. The organic coating was made by immersing samples in organosilicon heat-resisting varnish. In this method the organic coating acts as interlayer between the substrate and silver film. When the reaction starts, silver deposits directly on the interlayer. X-ray diffraction and SEM analysis were used to determine the composition and morphology of the interlayer and silver film. The potentiodynamic polarization curves for corrosion studies of coated magnesium alloys were performed in a corrosive environment of 3.5% NaCl（mass fraction） at neutral pH （6.9）. The results indicate that compared with the substrate, the corrosion resistance of coated magnesium alloys increases greatly. Moreover, the method proposed in this work is environmentally friendly, non-toxic chemicals were used. In addition, it provides a new concept for the corrosion inhibition of magnesium alloys.     

Influence of Silver Doping on Photocatalytic Activity of Liquid-Flame-Sprayed-Nanostructured TiO2 Coating

Silver ion was added to liquid feedstock to deposit Ag⁺-doped-nanostructured TiO₂ photocatalytic coatings through liquid-flame spraying. The coating microstructure was characterized by x-ray diffraction (XRD). The photocatalytic performance of coatings was examined by photodegradation of acetaldehyde. The XRD analysis showed that the phase structure of coatings was not significantly influenced by the silver ion doping. However, a shift was found for XRD peaks of anatase TiO₂. The photocatalytic activity of the TiO₂ coatings increased and then decreased with the increase of dopant concentration. The photocatalytic activity of doped coatings was higher than that of pure TiO₂ coating, regardless of the dopant concentration. The enhancement of photocatalytic performance of doped coatings is attributed to co-doping of Ag⁺ ion and metallic Ag. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.     

银纳米材料

简略介绍了各种形式银纳米材料的制备方法以及银纳米材料的热学、低温、电学、力学、光学和光电等性质，初步分析了银纳米材料作为微电子材料、光学材料、催化材料、环保材料及高强高导材料的现有和潜在应用。     

A new contact material—Ag／SnO2—La2O3—Bi2O3

A super-fine compound powder,Ag/SnO2 La2O3 Bi2O3,has been obtained using the chemical coprecipitation method.And a new contact material,Ag/SnO2 La2O3 Bi2O3,was produced by the powder metallurgy method.Its properties are as follows:the density is 9.75-9.93g/cm^3,the resistivity is 2.31-2.55μΩ.cm.the hardness is 880-985 MPa.Its microstructure shows that the fine oxides have a uniform distribution in the silver matrix.The results of make-break capacity and temperature rise testing show that the new material has better ability of anti-arc erosion and lower temperature rise than that of commonly used Ag/CdO.     

复合稀土银合金组织与性能的研究

试验制备了8种稀土银合金，研究了复合稀土银合金的组织与性能，提出了复合稀土对银合金组织与性能的影响有互补性，复合稀土元素在铸态下偏聚且共生在枝晶边界上，形成了Ag5RE金属间化合物及氧化物，对银合金有显著的强化作用和细化晶粒作用，提高了银合金的再结晶温度，增强了银合金的耐热性。这种合金经冷变形后退火，可以消除枝晶偏析，含稀土的第2相化合物呈团絮状分布在结晶组织上，有利于改善银合金的组织与性能。