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61.
B. Kwakye‐Awuah I. Radecka M. A. Kenward C. D. Williams 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(9):1255-1260
BACKGROUND: Metal‐exchanged zeolites have been reported to have significant limitations on cayalytic activity, such as counterbalancing the negative framework charges and limitation of active space. Alternative methods of incorporating silver ions into the framework of zeolites are therefore necessary. This paper reports on a technique for producing silver doped analcime by isomorphous substitution of silver ion into the framework of analcime. The amount of aluminium in the gel composition was reduced by a factor of 5%, 10% and 20% and an equivalent amount of silver was added to the gel and treated in a conventional manner for zeolite crystallisation. Some of the aluminium in the reaction gel was replaced with the silver. The silver‐doped analcime samples where characterised by X‐ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X‐rays (EDX), Fourier transform infrared (FTIR) spectroscopy and inductively coupled plasma‐atomic emission spectroscopy (ICP‐AES) analysis. RESULTS: The amount of silver ions loaded for each reduction of aluminium as determined by EDX were found to be (w/w) 0.29%, 1.41% and 2.10%, respectively. XRD pattern SEM images of the silver‐doped analcime showed the presence of zeolite P in addition to analcime. CONCLUSION: Silver‐doped analcime was successfully produced with different silver loadings and may exhibit higher anti‐microbial activities than silver‐exchanged counterparts. Copyright © 2008 Society of Chemical Industry 相似文献
62.
Bionanoparticles of starch obtained by submitting native potato starch granules to acid hydrolysis conditions. The resulted starch nanoparticles were used as core or macro initiator for polymerization of ε‐caprolactone (CL). Starch nanoparticle‐g‐polycaprolactone was synthesized through ring‐opening polymerization (ROP) of CL in the presence of Sn(Oct)2 as initiator. The detailed microstructure of the resulted copolymer was characterized with NMR spectroscopy. Thermal characteristic of the copolymer was investigated using DSC and TGA. By introducing PCL, the range of melting temperature for starch was increased and degradation of copolymer occurred in a broader region. X‐ray diffraction and TEM micrographs confirmed that there was no alteration of starch crystalline structure and morphology of nanoparticles, respectively. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
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65.
David P. Cormode Jason J. Davis Paul D. Beer 《Journal of Inorganic and Organometallic Polymers and Materials》2008,18(1):32-40
Disulfide and dithiocarbamate functionalized porphyrins have been synthesized and used as protecting ligands for gold nanoparticle
formation either via ligand substitution reactions or by direct synthesis. These nanoparticles have been shown to recognize
anions via changes in the absorbance spectrum of the surface adsorbed porphyrin moieties. Association constants, derived from
quantitative titrations, indicate a remarkable surface enhancement effect where the surface bound porphyrins bind anions much
more strongly than the free receptor in solution. 相似文献
66.
Alireza S. Sarvestani 《Materials Letters》2007,61(30):5278-5281
Oscillatory shear rheometry at small strains was used to investigate the effects of composition (concentration of macromer, crosslinker, initiator/accelerator, and filler) on the gel point and ultimate storage modulus of poly(l-lactide-co-ethylene oxide-co-fumarate) (PLEOF) hydrogels. PLEOF in situ polymerizing hydrogels can be used as biodegradable scaffolds for cell encapsulation and tissue regeneration. The time evolution of the viscoelastic properties of the polymerizing mixture during the sol-gel transition was monitored using mechanical rheometry. According to the results, while the ultimate storage modulus linearly increased with the concentration of methylene bisacrylamide (BISAM) crosslinker, the values of the storage and loss moduli at the gel point were insensitive to the concentration of BISAM. Similar behavior was observed for PLEOF hydrogels reinforced with hydroxyapatite nanoparticles. 相似文献
67.
本文对2002年国际国内白银市场做了全面分析,对2003年白银市场走势进行了分析预测。白银作为一种贵金属,同时又具有工业金属的特性,世界经济形势,世界政治局势的变化,都对白银价格走势产生影响。鉴于该金属的双重特性,本文就从白银的供应、需求、消费及世界经济的发展等方面论述白银市场前进趋势。 相似文献
68.
本文介绍利用x射线光电子能谱分析仪(XPS),对玻璃表面银的存在状态进行研究,实验结果表明银以Ag^0、Ag^+、Ag^++三种状态存在,而Ag^+的存在有利于玻璃光色性的提高。文中并提出了在工艺过程中应采用惰性或弱氧化性气氛。 相似文献
69.
载银无机抗菌剂变色抑制剂研发现状 总被引:31,自引:0,他引:31
介绍了载银无机抗菌剂变色抑制剂如甲基苯并三唑、天然水滑石和合成水滑石等的研发现状 相似文献
70.
银纪念币在大气环境中表面发生变色,失去原有的金属光泽。采用OM,SEM,EMPA,XPS,XRD等现代物理测试技术对变色的银纪念币进行分析。结果表明,银纪念币的变色部位呈均匀的浅褐色,并随机分布着深褐色的斑点。变色银纪念币表面沿着划痕密集分布着蚀孔。表面分析显示,除Ag外,还有S和O元素。XPS,XRD分析发现,变色银纪念币表面存在Ag2S,Ag2SO3和Ag2O。实验室加速变色试验毒明,在含S气体环境中,Ag被氧化生成A82S,导致银纪念币表面变色,从而验证银纪念币的变色是由电化学腐蚀引起的,S和O元素参与了腐蚀历程。 相似文献