《石油沥青纸胎油毡》国家标准的修订

《石油沥青纸胎油毡》国家标准进行了第三次修订。本文介绍了修订的理由、修订的内容与依据，并与国内外同类产品标准进行了比较。     

Synthesis of polyurethane resins and its improvement on dimensional stability and finishing performances of medium‐ and small‐diameter softwoods

This study analyzed the effects of polyurethane (PU) resin treatments on surface homogeneity, dimensional stability, and finishing performances of medium‐ and small‐diameter softwoods produced in Taiwan. Two‐pack PU resins were prepared by combing short castor oil‐modified alkyd resin serving as a polyol with polymeric 4,4′‐diphenymethane diisocyanate (PMDI) serving as a hardener, by the molar ratio of NCO/OH+COOH of 1.2. Four types of short oil‐modified alkyd resins with different polyhydric alcohols (glycerin and pentaerythritol) and polybasic acids (phthalic anhydride and isophthalic acid) were synthesized. Three kinds of medium‐ and small‐diameter softwoods, including China fir, Taiwanina, and Japanese fir with a diameter of 10–15 cm were obtained from Hui‐Sun Forest Station, Taiwan. The wood coating of nitrocellulose (NC) lacquer including sanding sealer and top clear was used. Results show that the surface hardness, homogeneity, moisture excluding efficiency, and antiswelling efficiency of woods were enhanced by PU resin treatments. Among all the PU resins, the isophthalic acid and pentaerythritol‐containing PU resin (IPA‐P‐MDI) achieved the best improved efficiency on dimensional stability of woods. Results of two types of finishing procedure, i.e. NC lacquer sanding sealer plus top clear and top clear only, applied onto the PU‐treated woods revealed that the hardness, adhesion, and durability of NC lacquer films on the PU‐treated wood were superior to those of untreated one, especially for top clear finishing alone. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Effect of Li+ ions on structure,properties, and actuation of cellulose electro‐active paper actuator

We have reported an electro‐active paper actuator from regenerated cellulose. After dissolving cellulose fibers with a solution of lithium chloride in N,N‐dimethylacetamide, cellulose was regenerated by combining distillation of cellulose solution along with washing with the mixture of deionized water, isopropyl alcohol, and running water. However, the effect of Li⁺ ions on structure, properties, and the actuation behavior of the actuator was not studied. This article describes the changes in these parameters when the Li⁺ ions are removed by subjecting it to different running water exposure time. The structure and properties of cellulose electro‐active paper and its actuation behavior were studied. As Li⁺ ions content reduced from 4354.17 to 10.26 ppm by increasing the exposure time of running water, crystallinity, Young's modulus, and bending displacement decreased. Details about the investigation have been explained. This elimination of ions is important to increase the piezoelectric effect in EAPap by decreasing the ion migration effect. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci 2008     

橡胶Mooney—Rivlin模型材料系数对轴向刚度影响分析

在橡胶小变形范围内，采用理论推断的方法，得到在相同硬度下橡胶Mooney—Rivlin模型材料系数由C2／C1决定的关系式。并采用ABAQUS有限元软件分析的方法，结合橡胶轴向刚度常规解，分析了C2／C1不同值对橡胶轴向刚度的影响进行，结果显示其影响呈现一定规律性。     

国内中小皮化企业如何适应激烈的市场竞争

总结了目前国内中、小皮化企业中存在的主要问题 :自主开发能力差 ,造成产品品种单一、配套性差 ;新产品市场推广能力也较差 ,造成即使有好的产品 ,也无法打开市场 ;而普遍存在的制革厂欠款 ,皮化企业自身体制陈旧及国外皮化公司的进一步本土化策略 ,使国内皮化企业面临更严峻的挑战。根据自身多年经营皮化材料的经验 ,提出了切实可行的应对措施     

过渡金属氮化物TinNm小团簇结构中的定域键

Ti、N形成的小团簇TinNm，当n＋m≤4时，一般出现线形和平面构型；当n＋m=5或6时，TinNm团簇异构体既有线形结构，也有平面结构，还有少数立体结构。线形结构大多形成强弱交替的定域键。平面结构中Ti—N键，随着原子数的增加，逐渐从共价键向离子键过渡，Ti失去电子增多，N得到电子也增多。而立体构型中大多形成离域键，验证了Anderson理论。     

中小型液压缸防漏结构工艺

气弹簧后端省去封头，而用缸体直接封口，杜绝了漏气，强化了结构。文章着重介绍了实现这一结构的径向进给封口工具及工艺。     

利用茚三酮或DFO加强显现热敏纸张上的潜在指纹

本文介绍一种新技术——利用茚三酮或DFO加强显现热敏纸张上的潜在指纹。大部分热敏纸张的热敏剂表面,使用DFO或茚三酮石油醚溶液(NPB)显影时将会变黑。显现的指纹和背景之间反差很小。新技术介绍了在指纹和热敏层之间,用丙酮水洗,可以去掉黑色污斑。其它新的化学试剂漂洗,显现的指纹有清晰的纹线和很高的反差。大量使用这种技术,可以使试剂优化,成本降低,短时间内能处理大量检材。工作试剂包括商用、不挥发、含氮的有机化合物,也使用象NPB这样的浸透性试剂。     

小容量机组保护监控一体化

以数字信号处理器(DSP)和复杂可编程逻辑器件(CPLD)为硬件平台,研制了新一代面向中、小型水电站的综合自动化模块.充分发挥MB40智能可编程逻辑控制器(iPLC)及MB100系列保护测控系统的技术优势,将小型水电站的保护装置做成模块插件,融入监控系统,降低了小型水电站自动化设备的成本,为推出真正意义上的面向小型水电站的"五合一"产品打下坚实的基础.     

济钢小板坯连铸机φ360mm拉辊优化改造

为解决小板坯连铸机φ360mm拉辊断颈、断辊问题，对拉辊原设计及现场使用条件进行了分析，将材质由55^#锻钢改为35CrNiMo，辊身与辊颈处改为圆锥台式，同时加大辊颈处过渡圆弧并磨削处理，延长水冷孔通过辊颈圆弧，从而使拉辊寿命由3～4个月延长到10～12个月，减少了事故损失，加快了生产节奏，年直接经济效益达49万元。