Evaluating Ozone as a Remedial Treatment for Removing RDX from Unsaturated Soils

Years of wastewater discharge at the Department of Energy’s Pantex Plant have contaminated the vadose zone and underlying perched aquifer with hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX). Because the vadose zone is acting as a continual source of groundwater contamination, removing RDX from the unsaturated zone is paramount to prevent further contamination. We determined the efficacy of ozone to degrade and mineralize RDX. Solution experiments showed that ozone (27?mg?L?1; 150?mL?min?1) was effective in mineralizing 80% of the RDX (30?mg?RDX?L?1) provided that some Pantex soil was present to buffer the solution pH. Soil columns treated with ozone produced 50% RDX mineralization within 1 day and >80% within 7 day. Experiments designed to evaluate aerobic biodegradation following partial ozonation of a RDX solution showed that ozone-generated RDX products were much more biodegradable than untreated controls in aerobic microcosms (35 versus <0.3% cumulative mineralization). These results support the use of ozone as a remedial treatment for the contaminated vadose zone at the Pantex facility.     

基于数字运算的PSD调理电路设计

介绍了基于数字运算的PSD调理电路思想及具体线路构造,该电路避免了模拟运算的缺陷,提高了精度和可靠性.     

真空技术在污水处理中的若干典型应用

介绍了真空技术在污水处理中的几种典型应用，真空结晶法在以分离污水中具有结晶性能的固体溶剂；真空过滤脱水用于初沉池和消化池污泥脱水，真空浮选法通过制造负压条件加速浮选过程；还有真空搅拌、真空脱气等等。这些足以说明真空技术在污水处理乃至环境保护中占有重要的一席之地。     

可节约生产成本的湿处理工艺技术

从传统意义上来讲，针织物及对张力敏感的梭织物的湿处理生产线（包括漂白、染色、柒色后水洗）通常是利用染缸来完成的，而这正是高水耗、高蒸汽消耗和高能源消耗的症结所在，同时带来一些质量问题（如折痕、起毛球和刮印等）。随着现代连续式平幅湿处理线技术的发展，整体生产成本可以下降到最多这50％。介绍了德国欧宝泰克生产的敏感织物连续式平幅湿处理线设备。     

洛阳热电厂主厂房地基处理方案的论证

通过对洛阳热电厂拟选择的地基处理方案进行比较,并结合该电厂施工实例论证了φ800/1600扩底钢筋混凝土灌注桩是最适于该电厂及相似地区的地基处理方式。     

A coordinated reverse logistics system for regional management of multi-source hazardous wastes

This paper presents a coordinated reverse logistics (CRL) management system for the treatment of multi-source hazardous wastes in a given region, in this case, a specific high-technology manufacturing zone. A linear multi-objective analytical model is formulated that systematically minimizes both the total reverse logistics operating costs and corresponding risks. In addition to inter-organizational logistics operating factors, environmental concerns are considered and formulated as corresponding risk-related constraints. Using the proposed model, results of numerical studies indicate that when the aspect of risk-induced penalties is not considered, the operational costs of regional hazardous-waste management can be efficiently reduced by 58%, compared to the existing operational costs at the study site. In addition, it is also observed that the corresponding weight associated with the risk-induced objective function embedded in the proposed model seems to have a significant effect on the CRL costs.     

一种有机硫类絮凝剂DTC的合成及性能评价

讨论了由有机伯胺或仲胺和CS2合成二硫代氨基甲酸盐DTC的反应及副反应,简介了合成工艺。根据红外光谱确认了由三乙烯四胺合成的二硫代氨基甲酸盐（以下简称DTC）的结构。以含原油350 mg/L、含悬浮固体55.1 mg/L,含Fe^2＋10.0 mg/L的模拟污水为实验水样,考察了该DTC的絮凝性能,在40℃、pH=6-7、沉降时间30分钟条件下DTC的适宜加量为20 mg/L,此时污水含油量为9.0 mg/L;使用DTC的适宜pH范围在4-8,pH=6为最佳值,适宜温度范围为10-45℃,温度高于45℃时DTC可发生热分解;DTC的除油效果随污水中Fe^2＋浓度增大而改善。在含油89.1 mg/L、含悬浮固体55.1 mg/L、含Fe^2＋13.2 mg/L的油田污水中,DTC的除油率最高,远高于常用絮凝剂PFS,PAC,CPAM,HPAM和PAM。当污水中不含Fe^2＋时,DTC无絮凝除油效果。讨论了DTC在Fe^2＋参与下的絮凝过程。图5表1参8。     

壳聚糖和粉煤灰对间甲酚的吸附处理

用壳聚糖和粉煤灰对含间甲酚的废水进行吸附处理,考察了壳聚糖的用量、振荡时间、振荡速度以及粉煤灰与壳聚糖的混合比对处理效果的影响.结果表明:在常温下,对于初始质量浓度为56 mg/L的间甲酚,当壳聚糖用量为3 g/L,以170 r/min的转速吸附振荡0.5 h,去除率可达到88%以上;在上述条件下,加入质量比4:1的粉煤灰与壳聚糖混合物5g/L时,间甲酚的去除率可达到91%.     

高效铣环在胜科1井事故处理中的应用

胜科1井是中国石化的一口重点科学探井,在钻至井深5001m时因井眼缩径发生了卡钻事故。由于井底存在直翼扩大器、PDC钻头等含有硬质合金的落鱼,普通铣鞋无法完成套铣打捞作业,为此,专门设计了一种高效铣环。该铣环的切削元件选用了一种硬度达93.2 HRA的钛合金,经铣槽镶焊在本体上;本体选用了40CrNiMo厚壁管材,并进行了调质处理;连接螺纹选用了双级梯形同步螺纹。在胜科1井的应用表明：切削元件的强度满足了切削扩大器切削翼和PDC钻头胎体的需要,其齿形、布齿方向和出刃高度设计合理,提高了切削速度;本体性能高,切削元件焊接性能较好;双级梯形同步螺纹有效增加了连接部位的强度,具有较高的上扣扭矩,承受冲击载荷能力强。高效铣环在该井的成功应用,为今后同类型井的事故处理提供了借鉴。     

高青樊107联合站污水处理技术应用研究

根据胜利油田樊107区块低渗透油藏注水开发的需要，开展了高青樊107联合站污水处理技术研究，与辽宁华孚环境工程‘有限公司联合研发了一套适合樊107区块注水水质指标的污水处理工艺设备。结合高青樊107区块的地质特点、注水水质指标要求，介绍污水处理室内试验研究、工艺流程、工艺设备选型、现场试验、存在问题和整改措施。