2,6-二异丙基环己胺馏分测定

建立了馏分中 2 ,6 二异丙基环己胺的气相色谱方法。在弱极性的毛细管色谱柱上、1 1 0℃下用面积归一法测定 ,方法标准偏差为 0 .1 3 ,变异系数为 0 .40 % ,与化学法比较 ,相对偏差小于 2 %。     

Viscoelastic and Processing Effects on the Fiber-Matrix Interphase Strength. Part I. The Effects of Loading Rate, Test Temperature, Fiber Sizing and Global Strain Level

The effects of loading rate, fiber sizing, test temperature and global strain level on the adhesion strength between carbon fibers and a thermosetting epoxy (Epon 815) are studied using the single fiber fragmentation test procedure. Analytical methodology describing the viscoelastic behavior observed is also presented. The possibility of rate-temperature-interphase thickness superposition for the interfacial strength function is illustrated based on the analytical models discussed. Experimental data are discussed using Weibull statistics and also presented in the form of percent relative frequency histograms for the fiber fragments in a collective fashion. The use of histograms allows for interpretation of the skewness in the data population.     

水质分析仪表国内自主品牌与进口品牌产品对比

本文分别对进口和国产品牌不同种类的水质分析仪表的市场应用、市场份额、价格、技术指标等进行详细调研和比较,旨在为电站运行选用经济适用的水质分析仪表提供选择指导。     

单幅图像多尺度小波深度提取算法

针对浅景深图像中平滑前景区域深度提取误差大的问题,基于像素点分类思想对深度值进行修正,提出一种基于多尺度小波线索的、可同时面向单幅浅景深图像和广角图像的深度图提取算法.首先使用小波分析法在多个尺度下提取图像深度信息;然后提出自适应分类法并根据尺度与深度变化规律对像素点做深度修正,得到深度图;最后结合区域生长与边缘分割算法对深度图进行区域优化.为了加快深度计算,还提出了快速zerocount法以及多尺度加速法来满足标清视频实时处理要求.实验结果证明,采用文中算法获得的深度图相对深度正确,前景和背景区域深度一致性好.     

盐酸生产与分析中应注意的几个问题

对盐酸质量分析中出现的酸度低、酸度分析指示剂不显色等问题进行了讨论。     

TW-6000 COD自动监测仪与标准法的对照实验

采用普析通用公司生产的TW－6000自动水质监测仪测定COD，与标准法（GB11914－1989）进行对照实验，再应用数理统计方法对结果加以分析，证明仪器法和标准法的数据无显著性差异（显著性水平为0.05，样本数为15)，且两者具有相似的精密度和准确度。     

α-取代十四酸衍生物的合成

报道了三种α－取代十四酸衍生物的合成方法，通过元素分析及波谱分析确证了新化合物α－（对硝基苯氧基）十四酸的结构。     

IGA-DFNN在瓦斯浓度预测中的应用

为了准确预测采煤工作面的瓦斯浓度,提出免疫遗传算法优化的动态模糊神经网络瓦斯浓度动态预测方法。用无线传感网络系统采集工作面瓦斯浓度数据作为样本,通过小波分析对样本数据进行降噪滤波预处理。采用IGA算法对DFNN网络参数进行优化,建立了瓦斯浓度的预测模型。通过MATLAB仿真研究表明,所建模型对采煤工作面的瓦斯浓度演变趋势预测合理,并且经过IGA算法优化DFNN网络比单纯的DFNN网络具有更快、更准确的预测功能,可以为防治煤矿瓦斯积聚提供更好的理论支持。     

FC-AE-ASM网络的模糊可靠性研究

针对目前FC-AE-ASM(fibre channel avionic environment anonymous subscriber messaging)网络可靠性计算问题, 以网络任务模型为基础, 提出了FC-AE-ASM网络的模糊可靠性模型。该模型主要分析了FC-AE-ASM网络的三种基本拓扑, 得出了这三种结构的模糊可靠性表达式。同时, 结合串并联的推导方法, 推导出了FC-AE-ASM冗余网络的模糊可靠性计算式。对实例的计算结果表明, FC-AE-ASM网络模糊可靠性的改善取决于关键因素, 并且基本路径冗余网络在自身网络可靠性较高时与全网冗余网络性能基本相同。     

Isotopic Oxygen Exchange and EPR Studies of Superoxide Species on the SrF2/La2O3 Catalyst

By using the in situ IR spectroscopy, the superoxide species (O₂⁻), characterized by the O–O stretching peak at 1130 cm⁻¹, was detected on the SrF₂/La₂O₃ catalyst at temperatures up to 973 K. The introduction of ¹⁸O₂ isotope caused the 1130 cm⁻¹ peak to shift to lower wavenumbers (1095 and 1064 cm⁻¹), consistent with the assignment of the spectra to the superoxide species. A good correlation between the rate of the disappearance of the O₂⁻ species and that of the formation of C₂H₄ was observed, suggesting that O₂⁻ was the active oxygen species responsible for the oxidative coupling of methane (OCM) on the SrF₂/La₂O₃ catalyst. This conclusion was reinforced by the EPR experiments (g_xx = 2.0001, g_yy = 2.0045, g_zz = 2.0685), showing that O₂⁻ was the only paramagnetic oxygen species detectable on the O₂-preadsorbed SrF₂/La₂O₃ catalyst. These results suggest that superoxide O₂⁻ can be a stable active oxygen species, whose role in the OCM reaction cannot be overlooked.