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31.
Mössbauer studies of Fe2+ in water-soaked nafion polymer membranes in the temperature range between 90 K and 250 K have been performed. Above a critical temperature (~ 180 K) the spectra exhibit both elastic narrow absorption lines and quasielastic broad lines. These spectra are typical of bounded diffusion phenomena observed by Mössbauer spectroscopy in macromolecular systems like haemoglobin, myoglobin and ferritin. Similar spectral shapes have been observed by quasielastic neutron scattering from water in nafion membranes. Within 50 K above the critical temperature the total Mössbauer absorption area decreases by an order of magnitude whereas the narrow absorption line decreases by two orders of magnitude. The results are interpreted in terms of bounded diffusive motion of the iron. Using a model based on overdamped harmonically bound Brownian motion, the essential parameters of the iron motion can be derived as a function of temperature. The iron motion most probably reflects the motion of a large Fe2+ complex, e.g. Fe(H2O)2+6, which is attached to the polymer side chains via the sulphonic group. 相似文献
32.
ABSTRACT: To protect and transport iron, we investigated the trapping properties of a network formed from β-lactoglobulin. We studied the influence of different parameters—pH, iron, and protein concentrations—on gel properties (optical and mechanical properties, WHC, and microstructure). For all conditions tested, the results show the formation of a cold gel in the presence of iron. The mechanical properties reveal that the elastic behavior and the strength of rupture increase with higher protein concentrations and decrease with higher iron concentrations. The water-holding capacity is high for low iron concentrations. The microstructure shows that, at low iron/protein ratios, a homogeneous filamentous network is obtained whereas, at high iron/protein ratios, more random aggregated particles are present. 相似文献
33.
34.
A. Rac 《Tribology International》1985,18(1):29-33
The wear of grey cast iron in dry sliding conditions has been studied with the aims of (1) finding the influence of working conditions on the wear rate, and (2) determining the region of speed and load where low wear is accomplished. Grey cast iron with flake and nodular graphite was submitted to investigation using a pin-on-disc machine. The results indicate that the flake graphite cast iron is more suitable for applications at speeds greater than 4 m s−1 and lower loads, while nodular cast iron has greater wear resistance at lower speeds in the range of loads investigated - from 50 N cm−2 to 200 N cm−2 相似文献
35.
羰基铁类随机混合吸波材料等效电磁参数的计算 总被引:3,自引:0,他引:3
本文为计及多重散射偶极子间的相互作用,引入参量εh和μh,导得一组公式。它不仅能计算铁氧体类也能计算羰基铁类的随机混合吸波材料的等效电磁参数,均与实验结果吻合良好。 相似文献
36.
Fatigue behaviour and endurance limit of graphite and of aluminium‐infiltrated graphite Fatigue properties of polycrystalline, isotropic graphite FU2590 and of FU2590 infiltrated with AlSi7Mg (FU2590/AlSi7Mg) were investigated in reversed bending tests at 25 Hz at numbers of cycles below 107 and in tension‐compression tests at 20 kHz below 109 cycles. The open porosity of Graphite (10‐11 Vol.‐%) was infiltrated with the aluminium alloy using the squeeze casting infiltration method, which led to an increase of the bending strength by 50 %, increase of tensile strength by 30 % and increase of stiffness by 15 %. Fully reversed tension‐compression loading of FU2590 delivers a mean endurance limit at 109 cycles at the normalized maximum stresses (i.e. maximum tension stress of a cycle divided by the static strength) of 0,65±0,03. Mean numbers of cycles to failure of 104 were found in fully reversed bending tests at the normalized maximum stress of 0,78. The infiltrated material shows approximately 30 % higher cyclic strength in reversed bending tests, and the mean endurance limit under tension compression loading increases by 15 %. The increased endurance limit of the infiltrated material is caused by the increased stiffness. The increased toughness of graphite due to the infiltration with aluminium is of additional beneficial influence at the higher cyclic stresses investigated in reversed bending tests and in static tests. 相似文献
37.
地下水污染修复的活性渗滤墙技术 总被引:15,自引:0,他引:15
活性渗滤墙是一种现场修复受污染地下水的新型技术,具有原理简单,施工方便,运行费用低廉等特点,活性渗滤墙垂直于地下水流动方向设置,当地下水流通过活性渗滤墙时,污染物与墙体材料发生化学反应,从而达到环境修复的目的。文中综述了活性渗滤墙技术的修复机理和实际应用,大量研究表明,应用金属铁作为活性渗滤墙材料,可以去除地下水中的重金属以及有机污染物,目前活性渗滤墙已经在世界各地应用,是一种非常有发展前景的环境污染修复技术。 相似文献
38.
MALHIREDDY INDUMADHAVI V. AGTE 《International Journal of Food Science & Technology》1992,27(2):221-228
The average diet in most developing countries is predominantly cereal based. Wheat, rice and millets are major staple foods. Although these diets are sufficient in iron, their low bioavailability is one of the most significant factors for iron deficiency anaemia. Traditional techniques like fermentation show promise in improving iron bioavailability. In vitro ionizable iron was estimated in 31 different combinations of rice, wheat, sorghum, black gram, bengal gram, green gram and coriander in five replicates with or without, fermentation in steamed products. Results indicate that in general cereal pulse combination and fermentation significantly ( P <0.05) increase the per cent ape of ionizable iron. Combination effects dominated in rice whilst fermentation dominated in sorghum. There was a significant reduction ( P <0.05) in phytate phosphorus on fermentation but no loss of tannin. 相似文献
39.
40.
H.K. Kuiken 《Journal of Engineering Mathematics》2003,45(1):75-90
Asymptotic solutions are presented for diffusion-controlled wet-chemical etching through a round hole in a mask. The three-dimensional diffusion field is assumed to be axisymmetric and fully developed. Two time regimes are considered. The first applies when the etched depth is small in comparison with the width of the mask opening. In the second, the depth of etching is much greater than the width of the mask opening. Explicit solutions are found for the shape of the etched surface as a function of the physical parameters. Among other things it is found that, as long as the etched pits are shallow, etching through small apertures is faster than through larger ones. The opposite is true for deep pits. 相似文献