Optimal production of intermediate for zero—first and first—first order reaction sequences in fluidised bed reactors1

An analysis of zero—first and first—first order reaction schemes has been carried out in a fluidised bed with a view to optimising the production of intermediate R for a given bubble diameter. For the zero—first order reaction sequence, the gas residence time at which the maximum concentration of R occurs is shown to be fixed and independent of bubble size in the bed. On the other hand, for a first—first order reaction scheme, an optimum gas residence time exists for the concentration maximum to occur at the bed exit. This interaction between bubble diameter, gas residence time and maximum concentration of intermediate is resolved by recourse to a three dimensional diagram which optimises the production of intermediate for any given value of bubble diameter or gas residence time.     

溴碘化银核壳乳剂中电子的捕获和复合

本文应用双注仪制备了在核表面进行不同程度还原增感和一系列溴碘化银核壳乳剂，在没条件下测定了核表面形成的不同还原增感中心对乳剂微晶光电子衰减动力学及发光光谱的影响。结果表明：在一定增感温度和时间条件下，当Ｎａ２ＳＯ３用量低于５．４ｍｇ／ｍｏｌＡｇ时光电子衰减动力学为二级反应，而当Ｎａ２ＳＯ３用量超过２７ｍｇ／ｍｏｌＡｇ时，增感中心一部分作为穴陷阱，另一部分作为电子陷阱，光电子衰减速率决定了电子的捕获     

X-ray crystal structure of the dye 2-cyano-4-bromo-4′-N,N-diethylaminoazobenzene

The crystal structure and molecular conformation of 2-cyano-4-bromo-4′-N,N-diethylaminoazobenzene (C₁₇H₁₇N₄Br, mol. wt. = 357·2 a.m.u) has been determined from X-ray diffraction data; triclinic, P$\text{1}$ (No. 2), a = 10·132(11) Å, b = 12·216(16) Å, c = 6·966(11) Å, α = 104·21(9)°, β = 92·67(12)°, γ = 97·22(7)°, V = 826·5(9) ų, Z = 2, D_c = 1·436 g cm^?3, F(000) = 378, λ(MoKα) = 0·71069 Å, μ(MoKα) = 26·0 cm^?1. The structure was solved by the multiple solution direct method and refined by full-matrix least-squares to R = 0·059 for 1538 independent observed reflections. The azobenzene skeleton is planar to within 0·06 Å. Most significant bonding data are: NN, 1·290(8) Å; BrC, 1·866(6) Å; mean CN (azo) 1·380(8) Å; NNC, 113·6(4) and 115·3(4)°; NCC (cis relative to NN) 125·9(4)° and 126·7(4)°; NCC (trans) 116·8°(5)° and 116·1(4)°.     

Particle-fluid heat transfer and dispersion in fluidised beds

The dynamic response of a gas fluidised bed has been measured for a range of particle sizes of lead glass ballotini and a range of particle Reynolds numbers. A dispersion model has been formulated that includes the effects of gas and particle mixing, fluid-to-particle heat transfer and intraparticle thermal conductivity, and the dynamic thermal response in theory has been found by solving the partial differential equations in the Laplace transform domain. The coefficient of thermal dispersion, the particle-to-fluid heat transfer coefficient and the intraparticle thermal conductivity have been found for the experimental response by non-linear regression. The coefficient of axial dispersion was found to be large and the particle to fluid heat transfer coefficients agreed with an established correlation for fixed and fluidised beds. The intraparticle thermal conductivity agreed with literature values for lead glass, the estimates showed no trend with flowrate, and the standard deviation of the estimate was three times smaller than the deviation found from similar experiments in fixed beds.     

汽轮机高压主汽门螺栓断裂失效分析

采用宏观检验、紧固工艺分析、化学成分分析、力学性能试验、金相检验和断口分析等对抚顺发电有限责任公司1号机组高压主汽门断裂螺栓进行了失效分析,结果表明:螺栓硬度偏低,断口附近金相组织存在偏析且有混晶现象,断口边缘有蠕变空洞及裂纹,断裂从螺栓根部向另一侧扩展,无明显塑性变形属于蠕变脆性断裂。     

副井提升系统安全回路及上位机优化改造

针对煤矿副井提升系统安全回路软硬件及上位机中存在的不足进行了优化改造,改进了过卷试验方式,将闸系统紧停信号引入安全回路,并将安全回路各节点状态信号引入RSView32人机界面,实时显示安全回路状态;根据现场检修需要,在上位机增加了复位显示功能及行程偏差大报警信号。实际应用表明,该优化改造可迅速定位故障节点,实现软硬件互查。     

XPS Characterization of reduced LaCoO3 perovskite

Three samples of LaCoO₃ were prepared by two different methods and calcined at 800 or 1000 °C. They had BET areas of 1, 12, and 16 m²/g and all of them showed pure perovskite X-ray diffraction patterns with identical unit cell dimensions. In a series of experiments the oxide, having larger surface area, was stepwise reduced in hydrogen at temperatures between 60 and 500 °C. The XPS spectra, taken at room temperature after evacuation at 400 °C at each reduction level, showed that the surface concentration of Co° was very low up to 300 °C but increased sharply between 300 and 350 °C (9–75%). This concentration further increased to 100% after 10 min reduction at 450 °C, but upon heating in hydrogen for an additional 10 min at 500 °C it decreased again to 75%. In another series of experiments the mixed oxide was reoxidized after each reduction. A fresh sample was reduced to 350 and 400 °C by contacting with hydrogen for 1 hr and evacuated at temperatures between 400 and 500 °C. Both high evacuation temperatures and reduction at 400 °C during 1 hr produced a sharp decrease in Co° surface concentration. These results are consistent with the catalytic behavior of this perovskite reported earlier by E. A. Lombardo et al. (4–7). A model is proposed to interpret the reduction of LaCoO₃.     

An analytical model for freeboard and in-bed limestone sulfation in fluidized-bed coal combustors

A new model, which combines in-bed and freeboard sulfation, significantly improves the ability to predict sulfur capture by limestone sorbents in fluidized-bed coal combustors. In this model, the in-bed hydrodynamics are described in terms of a bubble phase and an emulsion phase while the freeboard region has only a diluted emulsion phase. The solids, which are in the emulsion phases, are considered to be completely back-mixed; the gaseous bubble phase travels in plug-flow but exchanges with the emulsion phase. The sulfation reaction occurs principally in the emulsion phase and the reaction rate is a direct function of the sulfur dioxide concentration, the extent of the calcium oxide conversion (as measured by a thermogravimetric analyzer), and the amount of limestone present in the bed and in the freeboard. The amount present, or holdup, in the free-board is calculated from empirical correlations for elutriation and from particle-time trajectories as predicted from equations of motion.The model indicates that a significant amount of sulfur capture can occur in the freeboard region, especially with high superficial gas velocities and small particle sizes, both of which lead to increased freeboard holdup. For an overall sulfur retention of 90%, approximately 9% of the sulfur is predicted to be captured within the freeboard above a combustor bed 1.8 m by 1.8 m by 1.2 m high of 1200 μm diameter limestone particles that are fluidized at 2.4 m/s. The model also predicts that the sulfur captured by the entrained particles is negligible. These predictions compare favorably with the actual sulfur retentions experienced in similar sized pilot-scale combustors.     

半球型动压气体轴承陀螺电机设计及性能测试

针对高精度三浮陀螺用半球型动压气体轴承陀螺电机的启停寿命问题,对半球型动压气体轴承的设计理论以及保证轴承在电机工况下能可靠启停的一些关键技术进行研究.其中轴承间隙和螺旋槽结构参数是影响轴承可靠启停以及其力学性能的关键因素,将螺旋槽结构参数作为变量,通过改变变量参数来分析轴承力学指标的变化趋势,得出螺旋槽各关键参数与轴承刚度的关系曲线;通过有限元法仿真分析并校核了电机在工况下轴承的稳定性,证明了轴承间隙参数设计合理.在此基础上研制了半球型动压气体轴承陀螺电机样机,并进行专项的电机启停寿命试验,启停次数满足陀螺不少于3 000次指标要求,满足高精度三浮陀螺的使用要求.