Structure and magnetic properties of Ni0.11ZnxCo0.03Fe2.86-xO4 ferrite films deposited on Ag-coated glass substrates by wet chemical method

Ni_0.11Zn_xCo_0.03Fe_2.86-xO₄ spinel ferrite films with x = 0.00, 0.23, 0.34, 0.43 and 0.51 were prepared on Ag-coated glass substrates from nitrate and dimethylamine borane solution at 80 °C. The Ni_0.11Zn_xCo_0.03Fe_2.86-xO₄ ferrite films are singe-phased spinel ferrite. With the Zn content x increasing from 0 to 0.51, the lattice constant of the ferrite films increases from 0.8383 to 0.8425 nm. The Ni_0.11Zn_0.51Co_0.03Fe_2.35O₄ film is about 500 nm thick and composed of uniform equiaxed granules of about 40–50 nm. The Raman spectrum analysis indicates that the Zn²⁺ ions occupy the A sites. Saturation magnetization increases with x increasing from 0 to 0.35, reaches a maximum value of 460 kA/m at x = 0.35, and then decreases with further increase of x. Coercivity decreases monotonically from 12.3 to 1.7 kA/m with x increasing from 0 to 0.51. The change in magnetic properties may be explained by the decrease of A–B interactions and the anisotropy constant due to the incorporation of non-magnetic Zn²⁺ ions.     

膨胀石墨对纯油的吸附性能

以硫酸为插层剂、过氧化氢为氧化荆,用化学法制备了膨胀石墨。用扫描电子显微镜（SEM）分析了膨胀石墨的孔状结构,测试了膨胀石墨对纯油的吸附量。结果表明：膨胀石墨具有明显的三级孔状结构,膨胀石墨对原油、齿轮油、液压油和汽油的最大吸附量分别为80、85、60和50g／g,这种结果与油品的粘度有关。     

球磨La2Mg17与Ni复合合金的电化学贮氢性能研究

利用机械合金化法制备了La2Mg17+200%(质量分数)Ni复合储氢合金,并对不同球磨时间时合金的微观结构和电化学性能进行研究。结果发现,在球磨过程中Ni粉诱导了La-Mg-Ni非晶/纳米晶结构的形成。XRD和HRTEM结果共同表征了球磨80h时,合金中有Ni金属的存在,且XRD衍射峰强度较低,宽化严重,SAD为宽化的多环,表明形成非晶结构。电化学及其反应动力学测试结果发现,不同球磨时间的电化学反应的动力学控制机理是不同的。球磨60和80h后合金中不仅存在La-Mg-Ni非晶相,同时也有催化剂金属Ni,使合金的表面电荷转移反应电阻较小,氢在合金体相内的扩散系数D和极限电流密度I L均最大,最终导致80h的放电容量为最大值948.3mAh/g。然而,当合金的球磨时间为100和120h时,合金粉化到纳米级,100h的电荷转移反应电阻R ct最大,合金表面电化学反应缓慢,且合金体相内的极限电流密度和氢扩散系数均最小,属于合金电解液表面间的电荷转移和氢向体相内扩散联合控制的过程,必然导致其放电比容量较小。     

应用灰色关联度分析检测结构损伤的位置和程度

开发结构健康监测系统是结构损伤识别的一个重要课题。由于建筑结构具有很多不确定因素,通过模 态分析识别结构损伤的精度很难保证。提出一种灰色关联度分析应用于结构损伤检测的数值方法。通过测量结构的频 率,建立可能损伤频率和实际损伤频率的关联度的关联序,并找出最优序列,逐次迭代逼近来确定结构的损伤位置和损 伤程度。对多种工况进行了框架结构模型的数值模拟。结果表明:对于层间剪切结构,通过测量结构频率变化运用本方 法可以准确地确定结构的损伤位置和损伤程度。     

V-型皱褶夹芯板与隔声性能实验

设计并制作了5个不同几何特征参数和构型的皱褶芯材夹层板试验件，采用混响室一消声室法进行了标准隔声试验。通过对比试验，分析了褶皱芯材夹层板的隔声性能的基本规律，给出了隔声性能与其特征参数及构型之间的基本关系。试验结果表明；复合材料皱褶芯材夹层板的隔声性能随高度和面密度的增加而提高；复合材料皱褶芯材夹层板的隔声性能不完全服从质量定律；重量相同时．板的构型对其隔声性能有很大影响；在低、高频段，双层芯材垂直叠放夹层板的隔声性能比单层芯材夹层板好。     

无限大多层层合板隔声量分析

多层层合板结构被广泛应用于隔声结构设计中.为探究多层层合板的隔声性能,在无限大单层薄板隔声量计算公式的基础上,通过引入由经典层合板理论所得出的弯曲刚度,提出一种用于计算无限大多层层合板结构隔声量的理论方法——等效薄板法,并分别计算三层、四层和五层层合板的隔声量,通过与统计能量法仿真结果进行比较,表明等效薄板法在质量控制...     

Postponement: an inter-organizational perspective

In view of the slow rate of postponement applications, this paper attempts to examine postponement strategies from an inter-organizational perspective. The paper first reviews the literature on different postponement strategies (including logistics postponement, production postponement, purchasing postponement, and product-development postponement) mainly within the context of the supply chain or supply network. Then, two research questions are formulated. This is followed by the investigation into the inter-organizational structure and capacity planning in postponement applications. The paper concludes with some suggestions for further research.     

Creation of Faceted Polyhedral Microgels from Compressed Emulsions

Compressed monodisperse emulsions in confined space exhibit highly ordered structures. The influence of the volume fraction and the confinement geometry on the organized structures is investigated and the mechanism by which structural transition occurs is studied. Based on the understanding of ordering behavior of compressed emulsions, a simple and high‐throughput method to fabricate monodisperse polyhedral microgels using the emulsions as the template is developed. By controlling the geometry of the confined spaces, a variety of shapes such as hexagonal prism, Fejes Toth honeycomb prism, truncated octahedron, pyritohedron, and truncated hexagonal trapezohedron are implemented. Moreover, the edge sharpness of each shape is controllable by adjusting the drop volume fraction. This design principle can be readily extended to other shapes and materials, and therefore provides a useful means to create polyhedral microparticles for both fundamental study and practical applications.     

CuInS2/ZnS核壳结构量子点的水相制备与性能研究

因不含Cd、Pb、Te等有毒元素, 且具有在可见光至近红外光波段可调的发光性能, 铜铟硫(CuInS₂)量子点作为一种新型的I-III-VI型三元半导体材料, 广泛应用于分析检测和生物成像等领域。本研究采用一种低毒低温的方法快速合成CuInS₂量子点及其ZnS核壳结构量子点, 不仅利用ZnS带隙较宽且表面缺陷少的特点, 弥补了CuInS₂量子点的劣势, 提高了CuInS₂量子点的发光性能; 同时由于低毒性ZnS壳层的包覆, 进一步降低生物毒性。当Cu∶In摩尔比为1∶1时, CuInS₂量子点于530 nm处出现明显的发射峰, 且随着In含量的增加, 发光峰逐渐红移。包覆ZnS壳层后, CuInS₂量子点的发光强度明显增大, 且谱峰明显红移。当Cu∶Zn比为1∶1, 回流时间为45 min时, 合成的CuInS₂/ZnS量子点发光性能最优。该合成方法节省能源、生产效率高、绿色环保, 具有较大的应用前景。