Direct atomic scale analysis of the distribution of Cu valence states in Cu/γ-Al2O3 catalysts

In this paper, the microstructure of a 1 wt.% Cu/γ-Al₂O₃ catalyst that was reduced in a 4% hydrogen/argon atmosphere at temperatures of 523, 773 and 1073 K, is studied by Z-contrast imaging and electron energy-loss spectroscopy (EELS) in a scanning transmission electron microscope (STEM). Results show that the copper species are well dispersed when the catalyst is reduced below 523 K. At 773 K, separated Cu(I) and Cu(0) species are found existing as ring-like and bulk-like particles. This appears to indicate that the copper has not been reduced to its metallic form due to the interaction between the copper oxide and the support. Large spherical particles having core-shell structures with Cu(I) in the shells and Cu(0) in the cores are generated when the catalyst is reduced at 1073 K. The formation of partially oxidized copper species upon reduction at 1073 K is attributed to the metallic copper interaction with the alumina support. This study also demonstrates that high-spatial resolution Z-contrast imaging and EELS performed simultaneously can provide unique information on the morphology and chemistry of metal species in supported metal catalysts.     

巷道最佳注浆加固时机的分析研究

对松散破碎以及软弱围岩巷道进行注浆加固巷道围岩时,注浆时机的选择对注浆效果具有很大的影响。有效地进行注浆加固的先决条件是浆液能够在围岩中均匀地流动渗透到一定范围,且注浆后能明显提高围岩强度和整体承载能力。在综合考虑围岩裂隙的发育程度、注浆加固体的强度、所需控制的围岩变形量及注浆工艺等因素的基础上,确定了最佳的注浆时机——滞后15d～25d。     

土钉支护在深基坑开挖中的应用

深圳某银行办公楼的深基坑支护采用了土钉支护，不但保证了施工质量，而且缩短了工期，减少了投资，以此工程为例介绍了土钉支护的土力学参数计算、结构设计、施工方案、技术措施和取得的显著效果。     

底支承对小口径反射镜镜面变形的影响

论述了运用有限元技术研究镜面变形的方法及分析底支承在不同口径，焦比、厚径比和相对支承半径时镜面变形的技术；在取得的相互关联的最大镜面变形数据基础上，研究了影响小口径反射镜底支承镜面变形的因素。     

天生桥梯级水电站联合调度决策支持系统建设经验

决策支持系统是水库优化调度实用化的发展方向，对于提高水电站生产效益和水库调度管理水平具有重要意义。结合国电公司重点科技项目“天生桥梯级水电站联合调度决策支持系统”的开发，阐述了开发水电调度决策支持系统实现水库调度实用化的经验:正确反映用户需求、增强用户对系统的控制、用模拟仿真弥补优化调度的不足、用数据库技术扩展水库优化调度实用化功能。     

ZZ3200-14.5/28型支架快速倒装的实践

根据桃园矿单翼相邻工作面倒装的实践,从加快综采设备的搬家速度、提高劳动效率方面,简述桃园矿综采快速倒装的几点主要做法。     

连轧管机轧辊轴承的调整、维护及保养

本文介绍了应用于MPM连轧机轧辊上的四列圆锥滚子轴承的结构特性及其调整、维护、保养，旨在提高轴承的使用寿命。     

Health promotion for women with physical disabilities: A pilot study.

Objective: To pilot test a health promotion intervention for women with physical disabilities. Design: Pre- and postintervention questionnaires. Participants: Two groups of women with physical disabilities (n=15). Intervention: Seven-session weekly workshop intervention grounded primarily in social-cognitive theory. Setting: Disability and rehabilitation settings. Main Outcome Measures: Indicators of health status. Results: Statistically significant positive changes between pre- and postintervention scores on measures of self-efficacy for dietary behaviors, medical decision making, social interaction, physical functioning, impact of physical limitation on role activities, and vitality. Conclusion: Women with disabilities who participate in this health promotion intervention may exhibit improvements on indicators of health status. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

童亭矿锚杆支护安全可靠性控制

简要介绍了煤巷锚杆支护技术在童亭煤矿的应用推广情况 ,重点介绍了童亭煤矿在安全可靠性控制方面强化管理、优化设计、提高工艺水平和质量保证体系建设的一些经验和做法 ,并对今后发展煤巷锚杆支护技术提出了看法。     

Excavation and support design of the Dicle–Kralkizi water tunnel: an overview

Tunneling projects have their uniqueness in terms of engineering problems. The expertise gained from analyzing these projects establishes a sound basis for future application. This paper conveys experiences gained during the construction and support of the design of the Dicle–Kralkizi water tunnel, Turkey. Tunnel stability problems including overbreaks and surface subsidence are evaluated. An analysis of the breakdowns, factors controlling advance rate and the overall performance of tunnel are covered. The accumulated information presented here is believed to be useful and reliable for a successful tunnel excavation in similar formations.