MgO－CoO－NiO氧敏材料的缺陷化学及电导特性研究

本文用点缺陷理论分析了ＭｇＯ－ＣｏＯ－ＮｉＯ系氧敏材料的缺陷模型．并测量了ＭｇＯ－ＣｏＯ－ＮｉＯ材料的高温电导与氧分压的关系．在实验的基础上，研究了该材料的缺陷化学及电导特性，对其禁带宽度及缺陷的热力学参数进行了理论估算．实验结果与理论分析吻合得较好．     

多孔材料缓冲吸能特性表征方法

分析了多孔材料缓冲吸能机理，综述了多孔缓冲材料吸能特性的几种表征方法：缓冲曲线、缓冲系数、Janssen因子、Rusch曲线、能量吸收率曲线和能量吸收图，并分析了各种表征方法的优缺点。能量吸收图汇集了应变率和材料结构特征等信息，且能够模型化，对于不同密度多孔材料吸能特性的表征具有一定的普适性。     

复合包装材料剥离强度的检测方法

本文介绍了包装复合材料的分类、包装复合包装材料剥离强度的定义、检测方法及注意事项。     

低温切削技术及其应用研究

低温切削是指在低温环境下进行的切削过程,它利用低温下材料的物理化学性质,实现特定的加工目的。分析了低温切削技术的特点及其制冷技术,阐述了机械制造领域中低温切削技术的研究成果及应用状况。     

Modeling Self-Rollable Elastomeric Films for Building Bioinspired Hierarchical 3D Structures

In this work, an innovative model is proposed as a design tool to predict both the inner and outer radii in rolled structures based on polydimethylsiloxane bilayers. The model represents an improvement of Timoshenko’s formula taking into account the friction arising from contacts between layers arising from rolling by more than one turn, hence broadening its application field towards materials based on elastomeric bilayers capable of large deformations. The fabricated structures were also provided with surface topographical features that would make them potentially usable in different application scenarios, including cell/tissue engineering ones. The bilayer design parameters were varied, such as the initial strain (from 20 to 60%) and the bilayer thickness (from 373 to 93 µm). The model matched experimental data on the inner and outer radii nicely, especially when a high friction condition was implemented in the model, particularly reducing the error below 2% for the outer diameter while varying the strain. The model outperformed the current literature, where self-penetration is not excluded, and a single value of the radius of spontaneous rolling is used to describe multiple rolls. A complex 3D bioinspired hierarchical elastomeric microstructure made of seven spirals arranged like a hexagon inscribed in a circumference, similar to typical biological architectures (e.g., myofibrils within a sarcolemma), was also developed. In this case also, the model effectively predicted the spirals’ features (error smaller than 18%), opening interesting application scenarios in the modeling and fabrication of bioinspired materials.     

在线办公环境下教学保障物料管理信息系统的设计与应用

介绍了利用vs2003．net和oracle设计基于网络Web环境下的物料管理信息系统。通过这个系统将物料管理的工作流和业务流实现了有效整合,改变了传统的登记管理模式,为教学物料的在线管理提供了一种新的网络化模式。     

Polyphenol-Enriched Composite Bone Regeneration Materials: A Systematic Review of In Vitro Studies

One of the possible alternatives for creating materials for the regeneration of bone tissue supporting comprehensive reconstruction is the incorporation of active substances whose controlled release will improve this process. This systematic review aimed to identify and synthesize in vitro studies that assess the suitability of polyphenolics as additives to polymer-ceramic composite bone regeneration materials. Data on experimental studies in terms of the difference in mechanical, wettability, cytocompatibility, antioxidant and anti-inflammatory properties of materials were synthesized. The obtained numerical data were compiled and analyzed in search of percentage changes of these parameters. The results of the systematic review were based on data from forty-six studies presented in nineteen articles. The addition of polyphenolic compounds to composite materials for bone regeneration improved the cytocompatibility and increased the activity of early markers of osteoblast differentiation, indicating a high osteoinductive potential of the materials. Polyphenolic compounds incorporated into the materials presumably give them high antioxidant properties and reduce the production of reactive oxygen species in macrophage cells, implying anti-inflammatory activity. The evidence was limited by the number of missing data and the heterogeneity of the data.     

A Systematic Study of Restorative Crown-Materials Combinations for Dental Implants: Characterization of Mechanical Properties under Dynamic Loads

This study aimed to find the optimum mechanical characteristics of the restorative materials for the manufacture of implant crowns subjected to impact loading when different combinations of materials are used for the inner and outer crown. Several combinations of external–internal crown restorative materials were analyzed. The dynamic stresses at eight different zones of a dental implant subjected to an impact load and the influence of several mechanical properties, such as the Young’s modulus, Poisson’s ratio, density, and initial velocity, were analyzed and compared. A detailed 3D model was created, including the crown, the retention screw, the implant, and a mandible section. The model was then built by importing the 3D geometries from CAD software. The whole 3D model was carefully created in order to guarantee a finite element mesh that produced results adjusted to physical reality. Then, we conducted a numerical simulation using the finite element method (FEM). The results of the FEM analysis allowed for evaluating the effect that different combinations of restorative materials and mechanical properties had on the stress distribution in various regions of the implant. The choice of restorative material is a factor to be considered in order to preserve the integrity of osseointegration. Restorative materials transfer more or less stress to the dental implant and surrounding bone, depending on their stiffness. Therefore, an inadequate Young’s modulus of the rehabilitation material can affect the survival of the implant over time. Eight interactive graphics were provided on a web-based surface platform to help clinical dentists, researchers, and manufacturers to select the best restorative materials combination for the crown.     

Al掺杂对锰酸锂结构与性能的影响

采用固相法合成了Al掺杂的尖晶石LiAlxMn2-xO4(x=0～0.4).通过X射线衍射对LiAlxMn2-xO4的物相进行了研究,并探讨了Al掺杂对材料的充放电性能和电子电导率的影响.合成的LiAlxMn2-xO4均为纯尖晶石相.随着Al的掺入,LiAlxMn2-xO4的充放电循环性能得到改善,Al含量越高,循环过程中的容量衰减越小.电子电导率测试结果表明:掺杂Al后,降低了材料的电子电导率,这与Al的掺入降低了晶体中电子的离域作用有关.     

Copper‐Free Clickable Coatings

The copper‐catalyzed azide–alkyne 1,3‐dipolar cycloaddition (CuAAC) is extensively used for the functionalization of well‐defined polymeric materials. However, the necessity for copper, which is inherently toxic, limits the potential applications of these materials in the area of biology and biomedicine. Therefore, the first entirely copper‐free procedure for the synthesis of clickable coatings for the immobilization of functional molecules is reported. In the first step, azide‐functional coatings are prepared by thermal crosslinking of side‐chain azide‐functional polymers and dialkyne linkers. In a second step, three copper‐free click reactions (i.e., the Staudinger ligation, the dibenzocyclooctyne‐based strain‐promoted azide–alkyne [3+2] cycloaddition, and the methyl‐oxanorbornadiene‐based tandem cycloaddition?retro‐Diels?Alder (crDA) reaction) are used to functionalize the azide‐containing surfaces with fluorescent probes, allowing qualitative comparison with the traditional CuAAC.