Some kinetic aspects of unsteady-state partial oxidation reactions. Dynamic processes on metal oxide surfaces

It is shown that steady-state kinetic data do not allow the discrimination between the redox and associated mechanisms of the partial oxidation reactions. A discrimination between these mechanisms was performed using transient experiments. The obtained rate expressions are in agreement with experimental kinetic data for catalytic partial oxidation of o-xylene.

An influence of the conjugate oxidation of a catalyst surface on dynamics and kinetics of the heterogeneous catalytic oxidative reactions is considered. Computing simulation of methane oxidative coupling of methane reaction at lowered temperature and elevated pressure has been performed. It showed that the reaction order with respect to oxygen exceeding unity is consistent with the chain branching mechanism of the reaction in the presence of TiSi₂ and TiB₂ and showed the important role of the branching chain cycles in the low-temperature OCM reaction at elevated pressure.     

Ecological aspects of the manufacture and application of highly pure liquid substances

The action mechanism for aggressive and highly pure media on fluoropolymer constructional elements is assumed to consist of two basic microeffects: destructive changes in the fluoropolymer and contamination of the environment. Our approach to a quantitative estimation of the physicochemical stability is based on logic similar to that of a thermodynamic model of a two‐component system. A fluoropolymer and changes in its microstructure are considered the first component of the system. The second component is composed of liquid media contaminated with fluoroorganic compounds extracted from the fluoropolymer. The proposed methods for delivering aggressive and highly pure fluids to consumers allow the exclusion of pollution from working areas with gaseous products through an exception to a number of intermediate stages of product transport. The discussed principles allow the creation of a modern, highly effective, and safe (with respect to the ecology and raw materials) production of aggressive liquid chemicals for consumers. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 906–910, 2002     

Effects of fluoropolymer addition to an epoxy on scratch depth and recovery

Samples were prepared by addition of a fluorinated poly(aryl ether ketone) (12F-PEK) to a commercial epoxy resin and curing at either 24 °C or 70 °C. The concentrations of fluoropolymer in the samples were 0, 5, 10, 20, 30, 40, and 50%. Phase inversion facilitates the formation of more and more smooth surfaces for scratch testing with increasing fluoropolymer concentration. A progressively increasing load from 0.03 N to 12 N was administered with a diamond tip to the surfaces of the samples; depths were determined within ±7.5 nm. The original scratch depth is a function of the fluoropolymer concentration. Scratch recovery (healing) reaches values up to 95%. Plots of the residual depth versus concentration of the fluoropolymer at 4, 6, 8, and 10 N reveal minima for all forces and both temperatures. Addition of only 5% or 10% 12F-PEK improves the scratch recovery significantly. The results are explained by changes of material morphology with the fluoropolymer concentration. Electronic Publication     

精密深孔表面环状硬挤条纹的产生机理与控制

本文建立了不同条件下环状硬挤条纹的生成模型,详细分析了其产生机理.用理论解析和试验验证了所建模型的可靠性,最后提出了控制其产生的方法.     

Influence of wood extractives on the photo‐discoloration of wood surfaces exposed to artificial weathering

Extracted and unextracted black cherry (Prunus serotina), red oak (Quercus rubra), and red pine (Pinus resinosa) wood specimens were exposed to artificial weathering, and their discoloration process was investigated to obtain basic understanding on the role of wood extractives in the weathering of hardwoods and softwoods. Color measurements were made with a spectrometer according to ISO 2470 standards, using the CIELAB system. Results obtained showed that the rate of whiteness was not significantly affected by extractives removed with organic solvents, but were significantly affected when organic solvent extraction was followed by water extraction. The total discoloration rate had the same pattern, and chromaticity coordinates were less affected by wood extractives. These results confirm the hypothesis that some extractives contained in wood act as antioxidants and are able to provide some protection to wood surfaces against weathering degradation. However, more work is needed to understand the chemistry and mechanism of action of these extractives so as to develop any practical use for this property. © 2006 Wiley Periodicals, Inc. Col Res Appl, 31, 425–434, 2006; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/col.20248     

In situ regeneration of the Ni-based catalytic reformer of a 5 kW PEMFC system

The paper reports the results of on-site regeneration catalytic bed of the natural gas reformer in a 5 kW PEM fuel cell system. The Ni catalyst previously poisoned by sulphur from the available natural gas, could be re-activated by injection of pure water steam, following the method developed for industrial reformers using the same metal catalyst: this method was shown to be perfectly efficient, provided no natural gas was fed during the operation. Results of the tests conducted are presented and discussed in relation to published data on S-sorption on Ni surfaces.     

Use of oxygen for the cleaning, passivation, and preservation of power-generating equipment at the Kharanorskaya SAPP

Studies conducted on two power-generating units at the Kharanorskaya SAPP relative to the steam-water-oxygen passivation, preservation, and partial cleaning of all boiler-heating surfaces, including the surfaces of the reheater, and passivation of the surfaces of the high-pressure heaters on the steam and water sides by the steam-oxygen method, as well as partial passivation, preservation, and cleaning of turbine blading are presented. __________ Translated from élektricheskie Stantsii, No. 6, pp. 56–64, May, 2006.     

A study on dynamic friction of different spun yarns

This article presents the results from a study of yarn-to-yarn (YY) and yarn-to-metal (YM) frictions conducted on ring, rotor, air-jet, and open-end friction (OE friction) spun yarns at different relative speeds and input tensions. The results indicate that the behavior of frictions for YY is different than that of YM. In case of YY friction, OE friction yarn shows maximum friction followed by rotor, air-jet, and ring spun yarns; however, a reverse order is noticed for YM friction. The relative speed and input tension have significant influence on the frictional behavior of spun yarns. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Parametric circles and spheres

Formulations for parametric circles and spheres in terms of rational Gaussian (RaG) curves and surfaces are introduced. With the proposed formulations, a full circle is generated by interpolating a closed RaG curve to the vertices of an equilateral triangle, and a full sphere is generated by interpolating a closed RaG surface to the vertices of an octahedron with equilateral triangular faces. Generation of circles and spheres in this manner is very intuitive and easy to remember as the weights are all 1 and the nodes are all unique and uniformly spaced.     

四坐标数控加工原理及算法研究

本文对四坐标数控加工原理和算法作了详细介绍，尤其对四坐标加工的刀轴矢量算法进行了研究，提出了用垂直于回转轴的平面与刀具运动方向和前导角形成的圆锥面求交，生成刀轴矢量的方法，该方法具有立意新颖、思路清晰，性能可靠，易于在微机上实现等特点，对复杂曲面零件的加工编程，具有重要的实用价值。