Si基薄膜太阳电池绒面ZGO透明导电膜的研究

采用孪生对靶直流磁控溅射的方法在室温下制备高质量的Ga掺杂ZnO(ZGO)透明导电薄膜,用HCl腐蚀的方法获得满足光散射特性的绒面ZGO薄膜。制备的ZGO样品为具有六角纤锌矿结构的多晶膜,具有(002)方向的择优取向。腐蚀后,绒面ZGO薄膜的晶粒度减小,电阻率基本不变。在可见光范围内,绒面ZGO的反射率比平面ZGO的反射率下降了10%左右。将绒面ZGO薄膜应用于p-i-n型非晶Si薄膜太阳电池中,有效提高了太阳电池性能,使得电池的短路电流提高到17.79 mA/cm2,电池的转换效率增加到7.23%。     

正置倒置异质结有机小分子太阳能电池

以MoO3为阳极修饰层,以Rubrene/C60为活性层,制备了正置和倒置异质结有机小分子太阳能电池。实验结果表明倒置器件的开路电压Voc、短路电流密度Jsc、填充因子FF和功率转换效率η比正置结构的器件分别提高了34%、20%、25%和102%。当插入BCP阴极缓冲层后,阻挡了热的Al原子对C60层的破坏,对倒置器件的性能没有明显的影响,但却显著改善了正置器件的性能,并分析了MoO3和BCP对倒置和正置器件的作用。     

溶剂处理对烟梗梗丝内在质量的影响

为比较溶剂处理梗丝和常规工艺生产的梗丝的差别,采用溶剂处理烟梗梗条后在烟梗制丝线上制备梗丝,研究溶剂处理对梗丝内在质量的影响.通过仪器分析与感官质量对比,结果表明:与传统制备工艺相比,溶剂处理对烟梗的持水性、耐加工性和梗丝结构的影响较小,梗丝的填充值增加11.4%;其主要化学成分及致香成分含量有较大变化,对梗丝内在质量有一定程度的改善.     

基于MATLAB/Simulink的染料敏化太阳能电池输出特性仿真

根据染料敏化太阳能电池(DSSC)的等效电路,应用MATLAB/Simulink工具建立仿真模型,对DSSC的输出伏安特性及输出功率进行仿真,讨论串联电阻和分流电阻对DSSC性能的影响.仿真结果表明,随着串联电阻的增加,开路电压不变,短路电流密度、最大输出功率及填充因子降低;随着分流电阻的增加,开路电压、短路电流密度、...     

Ultra-low power dissipation of improved complementary pass-transistor adiabatic logic circuits based on FinFETs

With the technology scaling down, low power dissipation has become one of the research focuses in the field of integrated circuit design. Various types of adiabatic logics have been invented for low-power applications. However, the expanding leakage current degrades the performance of conventional adiabatic logics. In this article, a novel improved complementary pass-transistor adiabatic logic （ICPAL） based on fin-type field- effect transistor （FinFET） devices with ultra-low power dissipation has been presented. The proposed ICPAL takes full advantage of different FinFET operating modes, that is, shorted-gate mode, independent-gate mode, and low-power mode, to make a tremendous reduction in power dissipation. For explication and verification, the power dissipation of different ICPAL standard cells has been investigated and compared with other types of adiabatic circuits based on FinFETs. The results show that the ICPAL circuits have ultra-low power dissipation in a wide range of clock frequencies（30-800 MHz） under the condition of similar number of transistors, and the average reduction in power dissipation is about 23.1%, 75.0%, and 50.0% relative to 2N-2N2P, improved pass- transistor adiabatic logic, and complimentary pass-transistor adiabatic logic, respectively. Furthermore, ICPAL supports a better pre-evaluation of system power dissipation in VLSI design and has an intrinsic characteristic for the resistance to some types of side channel attacks.     

Proton conducting acid-base mixed materials under water-free condition

In recent years, a lot of attentions have been paid for a development of water-free polymer electrolyte membranes fuel cells (PEMFC) at intermediate temperatures (above 100 °C) because of many technological advantages of higher temperature operation. However, the proton conductivity of conventional polymer membranes under water-free condition is usually very low and the polymeric membranes are not stable at higher temperatures. So, the development of non-hydrous proton conducting membrane under water-free condition has been a state of the art issue in the advanced PEMFC technology. In this study, non-hydrous protonic conducting material was prepared by the mixing of acidic surfactant of mono-dodecylphosphate (MDP) and organic base of benzimidazole (BnIm). The proton conductivity and thermal stability of MDP-BnIm mixed material increased with the mixing ratio of BnIm. Maximum proton conductivity of MDP-BnIm mixed material (BnIm mixing ratio of 200 wt.%. vs. MDP) was found to be 1×10⁻³ S cm⁻¹ at 150 °C under water-free condition.     

Poly(2‐hydroxyethyl methacrylate‐co‐ethylene dimethacrylate) as a mouse embryonic stem cells support

A series of swellable ethylene dimethacrylate‐crosslinked poly(2‐hydroxyethyl methacrylate) (PHEMA) sheets of homogeneous (nonporous) structure or with different degrees of swelling and porosities was produced by bulk polymerization in either the absence or the presence of various diluents (porogens). Calculations performed by use of the solubility parameter δ of the reaction components indicate that the solvation conditions of the polymerization system change, depending on the solvating power of the diluent, which thus controls the porosity. Pore volume also seemed to be sensitive to the presence of the linear polymer diluent. Polystyrene (PS) showed, compared with poly(methyl methacrylate) (PMMA), a higher precipitating ability to form porous PHEMA sheets with an increased pore size because of its higher noncompatibility with newly formed crosslinked PHEMA. Given that PHEMA hydrogel is well known for its biocompatibility, it was used here as a potential carrier of cells in transplantation therapies. Attachment and growth of mouse embryonic stem (ES) cells on gelatin‐coated transparent PHEMA hydrogel substrates were examined. Two days after plating, survival and morphology of ES cells were largely similar on both PHEMA hydrogel sheets and in petri dishes as controls. This suggests that PHEMA hydrogels are likely candidates for application in transplantation therapies involving ES cells. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 425–432, 2003     

WuT3无血清培养上清中单克隆抗体纯化工艺的建立

目的对WuT3杂交瘤细胞生物反应器无血清培养上清中单克隆抗体进行分离纯化,建立中试分离纯化工艺。方法采用两步离子交换层析法结合硫酸铵盐析法分离纯化WuT3单抗。在通过小量试验优化纯化参数后,进行中量试验和中试放大。结果建立的纯化方法可以放大到中试规模,每批投料30000ml培养上清,可收获单抗达1.5g,单抗总回收率大于60%。经分离纯化后,单抗IgG纯度大于95%,采用免疫荧光法检测抗体活性合格。结论建立了一条生物反应器无血清培养杂交瘤细胞大规模分离纯化单抗的工艺路线。     

Gel polymer electrolyte based on poly(acrylonitrile-co-styrene) and a novel organic iodide salt for quasi-solid state dye-sensitized solar cell

A gel polymer electrolyte based on poly(acrylonitrile-co-styrene) as polymer matrix and N-methyl pyridine iodide salt as I⁻ source was prepared. Controlling the concentration of polymer matrix of poly(acrylonitrile-co-styrene) at 17.5 wt.%, mixing the binary organic solvents mixture ethylene carbonate and propylene carbonate with 6:4 (w/w), and the concentration of N-methyl pyridine iodide and iodine with 0.5 and 0.05 M, respectively, the gel polymer electrolyte attains the maximum ionic conductivity (at 30 °C) of 4.63 mS cm⁻¹. Based on the gel polymer electrolyte, a quasi-solid state dye-sensitized solar cell was fabricated and its overall energy conversion efficiency of light-to-electricity of 3.10% was achieved under irradiation of 100 mW cm⁻².     

Sintering behaviour of La1−xSrxFeO3−δ mixed conductors

The sintering properties of La_1−xSr_xFeO_3−δ (x = 0.1, 0.25) mixed conductors have been investigated with particular emphasis on the effect of secondary phases due to cation non-stoichiometry (±5 mol% La excess and deficiency). Secondary phases, located at grain boundaries in cation non-stoichiometric materials, increased the sintering temperature compared to single-phase materials. Extensive swelling in final stage of sintering was observed in all materials, which resulted in micro-porous materials. The swelling was most pronounced in the phase pure and two-phase materials due to La-deficiency, while refractory secondary phases in La-excess materials inhibited both sintering, grain growth and swelling. In La-deficient materials, formation of molten secondary phases resulted in rapid swelling due to viscous flow. The present findings demonstrated the importance of controlling sintering temperature and time, as well as careful control of the cation stoichiometry of La_1−xSr_xFeO_3−δ in order to achieve fully dense and homogenous La_1−xSr_xFeO_3−δ ceramics.