酚醛胺固化环氧树脂热降解动力学研究

利用市售酚醛胺PPA固化剂固化环氧树脂E-44,对固化产物热稳定性进行研究,用Flynn-Wall-Ozawa法建立了固化产物热降解动力学模型,得出热解活化能E=227.51 kJ/mol,lgA=14.34（A=2.19×1014 s^-1）。     

一种削弱振荡管内反射激波能量的方法

激波吸收腔是影响热分离机效率的重要结构,采用数值模拟和实验的方法对其进行研究,结果表明：数值模拟能够捕捉振荡管内激波和接触面两个间断;反射激波压力最大值随吸收腔直径比D/d增加而减小,随吸收腔长径比L/d增加而降低。提出一种实用的吸收腔结构——串联吸收腔,对比2个和3个吸收腔串联结构后,证明在膨胀比α＜6范围内2个吸收腔串联结构是最佳选择。     

热分析法研究SnSO4在催化剂制备中的分解行为

引言 热重分析（TG）是在程序控制温度下测量物质质量随温度变化的技术[1],其特点是简单、方便、快速、准确.将热失重曲线进行处理,可估算分解反应活化能,判断分解反应机理及影响因素,可为化学动力学的理论研究提供数据[2].     

乙烷裂解制乙烯过程反应动力学模型的研究进展

随着乙烯工业的不断发展及能源结构的不断调整,裂解乙烯原料呈现多样性.近年来,乙烷裂解制乙烯技术逐渐成为工业生产的热点.乙烷作为乙烯生产的优选原料,不仅具有收率高、纯度高、质量高的产品优势,同时具有投资低、成本低、能耗低的生产优势.作为裂解炉模拟的核心,研究乙烷裂解过程中的反应动力学模型可为工业生产提供精准预判.随工业应...     

火电厂用中水水质问题及改善措施的分析

针对火电厂用于循环冷却水和锅炉补给水的中水水质不稳定的问题,介绍通过改进污水处理阶段的工艺和深度处理必电厂初级阶段中水以提高中水水质的措施,对节能减排、保护环境吴有重要意义.     

膜生物反应器中污泥EPS的提取方法

采用七种方法（热、酸、碱处理等）提取MBR（Membrane Bioreactor）中污泥EPS（extracellular polymeric substances）,研究了这些方法对于污泥EPS的最佳提取条件。在综合考虑各种方法的精确性、操作简易度、提取效果、对污泥细胞的破坏程度后,确定EDTA二钠提取（浓度2%,3h）和热提取（80℃,45min）是最简便有效的两种提取方法。NaOH提取（1mol.L^-1,2h）对污泥细胞具有很大的破坏作用,投加甲醛（浓度2%,2h）之后提取核酸含量减少了21.5%,降低了NaOH溶液提取对于细胞的破坏作用。     

逆流式自然通风冷却塔的热力性能评价软件

在火电厂逆流式自然通风冷却塔的热力性能验收试验以及大修前、后的常规热力试验中,由于测试工况数目较多,原始数据处理的工作量大,稍有不慎,就会出现错误;同时为了分析结果,往往将模拟塔或其它电厂的相同型号的冷却塔与当前的试验塔进行对比评价。通过开发热力性能评价软件,实现:快速准确地计算出冷却塔的热力特性,将模拟塔和试验塔的热力特性曲线以及任务线绘制在双对数坐标图上,并对计算结果进行评价。     

Discharge Plasma Assisted Adsorbents for Exhaust Treatment： A Comparative Analysis on Enhancing NOx Removal

An analysis has been made on the discharge plasma coupled with an adsorbent system for NOx removal. The cascaded plasma-adsorbent system may be perceived as a better alternative for the existing adsorbent-based abatement system in the industry. In this study the exhaust is sourced from a diesel generator set. It was observed that better NO removal in a plasma reactor can be made possible by achieving higher average fields and subsequent NO2 removal can be improved using an adsorbent system connected in cascade with the plasma system. The paper describes various findings pertaining to these comparative analyses.     

服装接触舒适性与其织物手感的相关性研究

通过对贴身服用面料的主观接触舒适性和手感的检验,以及对面料客观物理机械性能的测量,综合评价了它们与服装接触舒适性的相关性。研究结果表明,主、客观测得的手感都与接触舒适显著相关,并呈负相关关系。同时建立了4个预测总体接触舒适性的模型:由冷暖感、接触痒感、局部压迫感、接触粘附感及湿冷感等5种舒适感知预测总体接触舒适性;由16项主观手感预测总体接触舒适性;由KES测得的16项客观手感预测总体接触舒适性;以及由主客观测得的显著因子预测总体接触舒适性。     

Directed Evolution of Phi Class Glutathione Transferases Involved in Multiple-Herbicide Resistance of Grass Weeds and Crops

The extensive application of herbicides in crop cultivation has indisputably led to the emergence of weed populations characterized by multiple herbicide resistance (MHR). This phenomenon is associated with the enhanced metabolism and detoxifying ability of endogenous enzymes, such as phi class glutathione transferases (GSTFs). In the present work, a library of mutant GSTFs was created by in vitro directed evolution via DNA shuffling. Selected gstf genes from the weeds Alopecurus myosuroides and Lolium rigidum, and the cereal crops Triticum durum and Hordeum vulgare were recombined to forge a library of novel chimeric GSTFs. The library was activity screened and the best-performing enzyme variants were purified and characterized. The work allowed the identification of enzyme variants that exhibit an eight-fold improvement in their catalytic efficiency, higher thermal stability (8.3 °C) and three-times higher inhibition sensitivity towards the herbicide butachlor. The crystal structures of the best-performing enzyme variants were determined by X-ray crystallography. Structural analysis allowed the identification of specific structural elements that are responsible for k_cat regulation, thermal stability and inhibition potency. These improved novel enzymes hold the potential for utilization in biocatalysis and green biotechnology applications. The results of the present work contribute significantly to our knowledge of the structure and function of phi class plant GSTs and shed light on their involvement in the mechanisms of MHR.