Selective partial oxidation of light paraffins with hydrogen peroxide on thin-layer supported Nafion-H catalysts

Thin-layer carbon supported Nafion-H catalysts were found to be active and highly selective (S>98%) for the partial oxidation of C₁-C₃ alkanes, in a three phase catalytic membrane reactor (3PCMR), under mild conditions and in the presence of H₂O₂. The influences of the catalyst teflon loading and H₂O₂ concentration on the reaction rate have been evaluated. A reaction pathway, based on the electrophilic hydroxylation of the C-H bond of alkanes with protonated hydrogen peroxide (H₃O ₂ ⁺ ), is discussed.     

Three‐dimensionally braided carbon fiber–epoxy composites,a new type of material for osteosynthesis devices. I. Mechanical properties and moisture absorption behavior

In recent years, three‐dimensionally (3D) braided composites have attracted a great deal of attention because of their high‐impact damage tolerance and fatigue life, superior fracture toughness, and so forth, and have been used in aeronautics, military, and transportation. These advantages make them strong candidates for osteosynthesis devices. In this study, 3D braided carbon fiber–epoxy (C_3D/EP) composites were produced via a simple vacuum impregnation technique. The load‐deflection curve, mechanical properties, and influence of fiber volume fraction, braiding angle, and axial reinforcing fibers were examined to determine their suitability for internal fixation devices. It is found that the C_3D/EP composites have excellent toughness and do not show brittleness when fractured because of their relatively high void content. The flexural, shear, and impact strengths of the C_3D/EP composites are excellent. It was shown that a C_3D/EP composite with a stiffness similar to load‐bearing bones can be made while maintaining enough strength. It is concluded that a relatively higher void content and braiding angle is more suitable for the C_3D/EP composites from the viewpoint of requirements of fracture fixation materials. The moisture absorption behavior and changes in mechanical properties caused by moisture uptake were evaluated. Results show that absorbed moisture slightly decreases mechanical properties of the C_3D/EP composites. Contrary to the unreinforced epoxy, the moisture absorption behavior of the C_3D/EP composites cannot be described with Fick's law of diffusion, probably because of the presence of voids and/or 3D fiber structure. The exact mechanisms should be proposed in further investigations. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 1031–1039, 2002     

A novel robust current control approach using adaptive line enhancer for three‐phase current‐source active power filter

An effective system control method is presented for applying a three‐phase current‐source PWM converter with a deadbeat controller to active power filters (APFs). In the shunt‐type configuration, the APF is controlled such that the current drawn by the APF from the utility is equal to the current harmonics and reactive current required for the load. To attain the time‐optimal response of the APF supply current, a two‐dimensional deadbeat control scheme is applied to APF current control. Furthermore, in order to cancel both the delay in the two‐dimensional deadbeat control scheme and the delay in DSP control strategy, an Adaptive Line Enhancer (ALE) is introduced in order to predict the desired value three sampling periods ahead. ALE has another function of bringing robustness to the deadbeat control system. Due to the ALE, settling time is made short in a transient state. On the other hand, total harmonic distortion (THD) of source currents can be minimized compared to the case where ideal identification of the controlled system can be made. The experimental results obtained from the DSP‐based APF are also reported. The compensating ability of this APF is very high in accuracy and responsiveness although the modulation frequency is rather low. © 2004 Wiley Periodicals, Inc. Electr Eng Jpn, 150(1): 50–61, 2005; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20014     

反偏移法三维波动方程正演

三维地震资料的处理与解释往往都需要三维正演模型给予验证，以得到准确的处理、解释结果。本文提出的三维正演方法是一种偏移算法的逆运算方法－有限差分反偏移法。这一算法具有算法简单、运算量小及深度方向分辨率高的特点，是一种快速、高精度的正演算法。反偏移法虽是偏移算法的逆运算法，却出现常规偏移算法中所没有的很多问题。为此，本文进行了三种不同反偏移方法试验，并采用了一种新的浮动坐标变换，使正演结果精度得到很大     

不用专门相移装置的三维面形测量

提出一种不需要专用相移装置实现相移，主要利用数字图像处理技术实现三维面形测量的方法，研究结果表明，用原干涉图像及1幅以上的移值条纹图主可能实现物体三维面形的测量。     

由三面投影图生成三维立体图的方法研究

针对创新设计中零部件的三维虚拟造型问题，提出了一种由二维投影图生成三维立体图的计算机化辨识方法。通过辨识简单三维立体的形状和空间位置，克服了二维图形中面的积聚性和零件之间不规则相贯和截交曲线的识别问题，进而实现了复杂组合形体的计算机化设计与造型。最后，以箱体类零件为例，在AutoCAD环境下利用VC 和ObiectARX开发工具编程验证了该方法的有效性。     

Homogenization of hardness distribution and distortion in high pressure gas quenching

Quenching with gases rather than oil or other liquid media has the advantages of reducing the risks concerning health and environment, while simultaneously homogenizing the quenching results and minimizing distortion due to a wide range of possible process parameter variations and the pure convective heat transfer. In this contribution, a coupled solution for increasing homogenization of quenching results within high pressure gas quenching will be presented. In the first stage, an experimental test facility was set up for flow investigations and in the second stage a numerical simulation model was generated. The numerical and experimental results of the flow through the chamber were compared for several boundary conditions. Finally, after complete verification of the simulation, the model may be used to assist in parameter variation for optimization of homogeneous high pressure gas quenching.     

高等级公路边坡防护设计

分析了影响边坡稳定的因素 ,对不同环境条件下采用的不同路基边坡防护类型进行了介绍 ,重点阐述了经济有效的三维固土网垫结合植被护坡的类型 ,指出边坡稳定是保障公路畅通的重要基础     

DW型单体液压支柱的大修工艺

老煤矿由于资金紧张 ,外购新柱补充很少。因此 ,现使用的单体液压支柱超期服役的较多 ,急需升井大修 ,以满足各矿采煤工作面的需要。采用校直外圆 ,油缸加衬套的大修方法 ,可满足使用要求。     

三维合成炮叠前深度偏移

对国际上标准的SEG/EAEG模型进行了三维合成炮叠前偏移研究。与三维单炮叠前深度偏移不同 ,三维合成炮叠前偏移有一个叠前数据的合成过程 ,由于合成后数据量大大减少 ,所以合成炮偏移的计算量要比单炮偏移小得多。阐述了三维合成炮叠前偏移的实现过程 ,给出了相应公式。对SEG/EAEG盐丘模型的一个数据集进行了MPI并行计算 ,取得了良好的成像效果。所作的较多计算表明了三维合成炮叠前偏移的正确性和有效性 ,这为野外实际数据的三维叠前深度偏移提供了另一条有效途径。