Three-dimensional atom localization in a five-level M-type atomic system

By using three mutually perpendicular standing-wave fields, we propose a scheme for three-dimensional (3D) subwavelength atom localization in a five-level M-type atomic system. Based on the electromagnetically induced transparency, position probability distribution of the atom in 3D space could be determined via measuring the probe absorption which is proportional to the filter function. It is shown that patterns of 3D atom localization depends sensitively on the coupling schemes of the standing-wave fields. When the standing-wave fields couple three different transitions, the same atom localization patterns are formed in the eight subspaces of the 3D space. While all the standing-wave fields are applied on one transition, we can realize different atom localization patterns in the eight subspaces. From the view of the xy plane, various symmetric or asymmetric atom localization patterns could be formed at different z positions by adjusting the parameters of the laser fields.     

Synthesis of highly soluble and transparent polyimides

A novel aromatic diamine, 3,3′‐diisopropyl‐4,4′‐diaminophenyl‐4″‐methyltoluene with a 4‐methylphenyl pendant group and isopropyl side groups, was designed and synthesized in this study. Then it was polymerized with various aromatic dianhydrides including pyromellitic dianhydride, 3,3′,4,4′‐biphenyltetracarboxylic dianhydride, 4,4′‐oxydiphthalic anhydride, 3,3′,4,4′‐benzophenone tetracarboxylic dianhydride and 4,4′‐(hexafluoroisopropylidene)diphthalic anhydride via a one‐pot high temperature polycondensation procedure to produce a series of aromatic polyimides. These polyimides exhibited excellent solubility even in common organic solvents, such as chloroform and tetrahydrofuran. The flexible and tough films can be conveniently obtained by solution casting. The films were nearly colorless and exhibited high optical transparency, with the UV cutoff wavelength in the range 302–365 nm and the wavelength of 80% transparency in the range 385–461 nm. Moreover, they showed low dielectric constants (2.73–3.23 at 1 MHz) and low moisture absorption (0.13%–0.46%). Furthermore, they also possessed good thermal and thermo‐oxidative stability with 10% weight loss temperatures (T_10%) in the range 489–507 °C in a nitrogen atmosphere. The glass transition temperatures of all polyimides are in the range 262–308 °C. Copyright © 2012 Society of Chemical Industry     

Spin‐Transparency of the Fullerene Shell of Endometallofullerene La@C82

Abstract

For La@C₈₂ embedded into the polycarbonate film, an intensive ¹H‐electron‐nuclear double resonance (ENDOR) has been revealed. Since La‐EMF does not contain hydrogen atoms, it evidences for the electron spin density on the matrix protons. Furthermore, for the solutions of La‐EMF in hexamethylphosphoramide (HMPA), the paramagnetic shift of the ³¹P NMR signal of bulk solvent molecules has been revealed. These findings testify the partial localization of unpaired electron outside the fullerene cage. The “transparency” of the fullerene shell to the electron spin density may serve the important factor in designing the fullerene‐based materials.     

工作面复杂构造坑透及反射槽波透明化探测研究

煤矿井下工作面内部发育的复杂地质构造是威胁安全回采的重要因素,为保证工作面安全回采,提高探测精度,达到透明化探测目的,采用坑透和反射槽波两种物探手段相结合对工作面进行了探测研究.首先讨论了坑透和反射槽波的相关理论,分析了电磁波收敛成像算法和弹性波偏移成像算法,研究了坑透场强衰减规律和衰减系数.然后,对反射槽波探测数据进...     

Excellent Mechanical and Transparency Properties of Cationic Waterborne Polyurethane Films Modified by Boehmite Sol

The strategies for nanosol from metal alkoxide have enabled production of ultratransparent and mechanically robust polymer nanocomposites at extremely high loading. Herein, a simple approach to fabricate high‐performance polyurethane‐based nanocomposites via unmodified boehmite nanoparticles is reported. Evaluating their physical properties, the uniform dispersion of boehmite in the matrix caused nanocomposites retains ultrahigh transparency. Hydrogen bonding and intermolecular entanglement between boehmite and polyurethane brings about the mechanical properties of the nanocomposites material enhanced, i.e., strength, stiffness, and toughness. Optimized strength, stiffness, and toughness of Boehmite/Cationic waterborne polyurethane at 40 wt% (BNC40) are up to 58.1 MPa, 1096.7 MPa, 249.5 MJ m^?3, respectively. Furthermore, the feasibility and mechanism of polymer strengthening and toughening by inorganic rigid nanoparticles is explored from the aspects of crystallinity and micromorphology.     

自制纸张透明剂的应用性能研究

采用复配法制备了纸张透明剂,并对透明剂的性质及其应用性能进行了系统研究。透明剂的性能可以在常温和较长时间内保持稳定,不会出现溶液分层或浑浊等现象。采用优选出的透明剂处理纸张后,纸张透明度可达到70%以上,相比原纸,透明度提高30个百分点以上,但同时纸张强度性能有所下降。透明剂可在常温下快速渗透,最佳浸渍时间为5 ｓ。扫描电镜分析表明,透明剂可有效存留于纸张内部,填充纤维间的空隙,黏附在纤维表面。     

磷酸单酯淀粉糊透明度影响因素的研究

研究了磷酸单酯淀粉的透明度以及NaCl、蔗糖、柠檬酸等食品成分和老化作用对透明度的影响。结果表明，NaCl对淀粉糊的透明度影响不大，而蔗糖、柠檬酸则能提高糊液的透明度，老化使淀粉糊的透明度下降，初期下降迅速，中后期下降减缓。     

高透明抗冲击聚苯乙烯树脂的研制 Ⅰ.结构与性能

用自由基接枝聚合法研究了不同增韧剂制备透明抗冲聚苯乙烯,发现只有采用高苯乙烯含量的丁二烯、苯乙烯嵌段共聚物作为增韧剂,才能得到透明性好的抗冲击聚苯乙烯。所得高透明抗冲击聚苯乙烯的透光率与K树脂相当,抗冲击性能优于K树脂。     

高透明抗冲聚苯乙烯中试研究

在连续本体聚苯乙烯中试装置上对高透明抗冲聚苯乙烯树脂进行了研究。结果表明,中试产品冲击性能与增韧剂相当,比小试产品稍差。小试产品、中试产品及增韧剂具有相似的互穿网络结构。     

氰基胍作为PVC热稳定剂的应用

用刚果红法和烘箱变色法比较研究了以干混料和塑化料为试样时氰基胍(CG)、硫醇辛基锡(OTM)、硬脂酸钙(CaSt2)和硬脂酸锌(ZnSt2)对PVC的热稳定性能,结果表明:以干混料和塑化料为试样的测试结果存在明显差别,也就是说,以干混料为试样得到的热稳定性能测试结果不能反映实际应用条件下的表现,要获得对实际应用具有指导意义的热稳定性能结果,应以塑化料作为试样进行测试。根据以塑化料为试样的测试结果,CG单独使用时效果不明显,与CaSt2、环氧大豆油(ESBO)并用存在明显的协同效应;CG的热稳定性能与1,3-二甲基-6-氨基尿嘧啶(DMAU)相比还存在较明显的差距,电绝缘性能相当,但透明性能则优于后者。