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41.
采用离子交换法制备Co-LsX催化剂,分子筛经Co2+离子交换后,其骨架结构没有发生变化。考察了反应温度、反应时间、催化剂用量、溶剂加入量及氧气通入速率等因素对苯乙烯环氧化反应的影响。得出最佳工艺条件:反应温度100℃,反应时间6 h,Co-LsX与苯乙烯质量比为0.16,混合溶剂与苯乙烯体积比为5;V(O2)∶V(苯乙烯)=1.3 min-1。在此条件下苯乙烯转化率达到62.5%,环氧苯乙烷的选择性达到57.1%。催化剂经6次循环使用后活性和稳定性都比较好。 相似文献
42.
Mesoporous molecular sieve MCM-41 with a Si/Al ratio of 35 was obtained by hydrothermal synthesis using a gel mixture with a molar composition of 6 SiO20.1 Al2O31 hexadecyltrimethylammonium chloride 0.25 dodecyltrimethylammonium bromide 0.25 tetrapropylammonium bromide0.15 (NH4)2O1.5 Na2O300 H2O. The MCM-41 sample was calcined in O2 flow at 813 K and subsequently ion exchanged with Ca2+. A small Pt cluster has been supported on the MCM-41 sample following a procedure using ion exchange of Pt(NH3)
4
2+
. The Pt(NH3)
4
2+
ion supported on MCM-41 has been activated in O2 flow at 593 K and subsequently reduced with Fh flow at 573 K, in the same way used for the preparation of a Pt cluster entrapped inside the supercage of zeolite NaY. The resulting Pt cluster supported on the MCM-41 shows hydrogen chemisorption oftotal two H atoms per Pt at 296 K (based on the total amount of Pt) and high catalytic activity for hydrogenolysis of ethane. The chemical shift in129Xe NMR spectroscopy of adsorbed xenon indicates that the Pt cluster is located inside the mesoporous molecular sieve. 相似文献
43.
44.
混合材对水泥与减水剂适应性的影响研究 总被引:11,自引:2,他引:11
通过对掺高效减水剂水泥净浆流动性及流动性损失的测定试验,研究了3种混合材(粉煤灰、水淬高炉矿渣和沸石)在不同替代率情况下对减水剂作用效果的影响。结果表明:水淬高炉矿渣有利于改善减水剂与水泥的适应性,而掺粉煤灰和沸石(尤其是沸石)则会导致减水剂塑化作用的降低,而且浆体流动性损失也有增大趋势。 相似文献
45.
A new CVD method without vacuum condition(CVDWV)was designed in this study,ithad been found that by modifying the flow rate of the carrier gas(N_2)and the temperature of sur-face reaction,silicon saturator and sample tube,the amount of silica deposited on the external sur-face of the zeolite could be precisely controlled,The changes in the physicochemical properties ofzeolite,such as pore-opening size,acidity and reaction property were investigated.The results ob-tained showed that:modification of the improved CVD method did not change the internal structureand acidity of the zeolite,but could bring about significant change of pore-opening size and reactionproperty as desired. 相似文献
46.
13X沸石吸附处理水中苯胺的性能及应用 总被引:6,自引:0,他引:6
用天然岩石矿物为原料,经过较简单的工艺过程合成13X沸石去除水中苯胺,模拟废水的实验结果表明:沸石对苯胺的吸附速率非常快,吸附时间为10min时,吸附基本达饱和;一般当沸石用量为10g/L时,水蝇苯胺的吸附率达95%,随着pH值的增加,苯胺在沸石上的吸附率较小;温度增加,吸附率有所增加。但常温下,苯胺的吸附率也能达到93%,13X沸石对苯胺的最大吸附量可达10mg/g,其吸附规律较好地符合Freundlich吸附等温式,饱和了苯胺的沸石,用质量分数为20%,温度为60℃的氯化钠溶液洗脱,解吸率近于100%,且解吸后的沸石在未经任何处理的情况下仍能吸附苯胺;对实际苯胺废水的处理结果,也表明13X沸石不仅可有效地去除苯胺,还可以有效地去除废水中的SS,CODCr,氨氮及油等。 相似文献
47.
48.
NO
x
reduction with a combination of catalysts, Pd catalyst, NO
x
storage reduction (NSR) catalyst and Cu/ZSM-5 in turn, was investigated to elucidate for the high NO
x
reduction activity of this catalyst combination under oxidative atmosphere with periodic deep rich operation. The catalytic
activity was evaluated using the simulated exhaust gases with periodically fluctuation between oxidative and reductive atmospheres,
and it was found that the NO
x
reduction activity with this catalyst combination was apparently higher than that of the solely accumulation of these individual
activities, which was caused by the additional synergic effect by this combination. The Pd catalyst upstream of the NSR catalyst
improved NO
x
storage ability by NO2 formation under oxidative atmosphere. The stored NO
x
was reduced to NH3 on the NSR catalyst, and the generated NH3 was adsorbed on Cu/ZSM-5 downstream of the NSR catalyst under the reductive atmosphere, and subsequently reacted with NO
x
on the Cu/ZSM-5 under the oxidative atmosphere. 相似文献
49.
Helen L. Ngo Alberto Nuñez Wenbin Lin Thomas A. Foglia 《European Journal of Lipid Science and Technology》2007,109(3):214-224
Branched‐chain (bc) saturated fatty acids (SFA) have potential as oleochemical intermediates since they have better oxidative stability than linear unsaturated fatty acids (UFA) and have better low‐temperature properties than linear SFA. Previous studies in converting UFA to bc‐FA using clay catalysts have resulted in only modest yields and conversions. Recent reports, however, have suggested that certain zeolites can be effective catalysts for converting UFA to bc‐FA in higher yields and conversions. In this work, we examined the scope and potential of the zeolite‐catalyzed synthesis of bc‐FA starting from readily available monounsaturated linear FA. Our results show that common UFA such as oleic acid can be converted to bc‐isomers using modified Ferrierite zeolite catalysts with high conversions (98%) and high selectivity (85%) and that the zeolite catalysts are reusable for at least three cycles. The positions of branching (methyl) on the FA chain were determined from the GC‐MS spectra of the picolinyl esters of the bc‐FA. 相似文献
50.
用于选择性催化还原法烟气脱硝的催化剂 总被引:14,自引:0,他引:14
论述了在使用不同催化剂和不同还原剂的条件下,选择性催化还原( SCR)脱除电站烟气中氮氧化物的基本原理.SCR催化剂有三种不同的类型:贵金属型、金属氧化物型和离子交换的沸石分子筛型,并讨论了三种不同催化剂在SCR反应过程中的活性特征.论述了在国外应用最广泛的V2 O5- WO3 - Mo O3 /Ti O2 类催化剂的成分组成以及各成分在反应过程中的作用.列举了在SCR催化剂的生产和使用过程中需要考虑和解决的主要问题. 相似文献