A glue method for fabricating membrane electrode assemblies for direct methanol fuel cells

We present a simple glue method for fabricating membrane electrode assemblies (MEA) for direct methanol fuel cells (DMFC). Rather than the conventional “dry” hot-pressing method that relies solely on hot-pressing at a high pressure and temperature to form a MEA, the “wet” method developed in this work introduces a binding agent, consisting of Nafion^® solution, between a polymer electrolyte membrane (PEM) and an anode/cathode. The introduced binding agent can provide a better adhesion and stronger binding force between a membrane and an electrode, thereby facilitating a better interfacial contact between the electrode and the Nafion^® membrane, which has been proved by scanning electron microscopy (SEM) analyses to the cross-sectional morphology of the MEA after long-term operation. The cell performance characterization showed the MEA fabricated by the glue method was more stable in cell performance than that fabricated by the conventional hot-pressing method. Cyclic voltammetry (CV) results also demonstrated the MEA fabricated by the glue method exhibited a higher electrochemical surface area (ESA) as a result of the improved interfacial contact between the Nafion^® membrane and the electrodes. Finally, the DMFC with the MEA fabricated by the glue method was characterized by the electrochemical impedance spectroscopy (EIS).     

On the importance of some surface and interface characteristics in the formation of the properties of adhesive joints

The importance of some relative surface characteristics which determines the strength of adhesive joints: specific surface of substrate , relative contact area β and specific contact area β in the adhesion interaction process were emphasised. Existing and potential methods of experimental evaluation of these characteristics were shortly analysed. The durability of the adhesive joints in water media significantly increases with growth of specific surface ^* of chemically treated substrate evaluated from the SEM micrographs. Specific surface calculated from the experimental data of hexane adsorption measurements for iron particles (particulate model of steel substrate) is more then ten times greater than respective ^* values. The relative contact area β of the Al₂O₃ particles (in wide range of ) with PE melt was in a roundabout way evaluated by experimental determination of the affect of on kinetic of peel strength formation of adhesive joints: Al₂O₃ filled PE-steel. The speculation was based on the ability of Al₂O₃ to adsorb low-molecular products of contact oxidation of PE which takes place in the process of formation of adhesive joints and determines their strength. The ability of sorption in its turn is proportional to efficient value of β. The availability of the Al₂O₃ surface was evaluated.     

UNIX主机行为监控系统的设计与实现

该文介绍了Unix主机行为监控系统在大型网络中的应用及作用,并提出了具体的设计方案与实现方法。该系统主要采用透明的方式串接在工作区域和服务器群之间,利用网卡零拷贝的技术保障业务流量不会产生瓶颈,同时利用bypass的技术来保障服务器群的高可用性,既能保证服务器群的安全,又不会给网络带来附加的影响。     

Fissure evolution and evaluation of pressure-relief gas drainage in the exploitation of super-remote protected seams

Based on nonlinearity contact theory and the geological structure of the Xieqiao Coal Mine in the newly developed Huainan coal field, rock movements, mining fissures and deformation of overlying strata were simulated by using the interface unit of FLAC3D to evaluate the pressure-relief gas drainage in the exploitation of super-remote protected seams. The simulation indicates that the height of the water flowing fractured zone is 54 m in the overlying strata above the protective layer. The maximum relative swelling deformation of the C 13 coal seam is 0.232%,while the mining height is 3.0 m and the distance from the B8 roof to the C13 floor is 129 m, which provides good agreement with a similar experiment and in situ results. The feasibility of exploitation of a super-remote protective coal seam and the performance of the pressure-relief gas drainage in a super-remote protected layer are evaluated by comparisons with practice projects. It demonstrates that the relieved gas in the super-remote protected layers could be better drained and it is feasible to exploit the B8 coal seam before the C13 super-remote protected coal seam. The method is applicable for the study of rock movements, mining fissures and deformation of the overburden, using the interface unit to analyze the contact problems in coal mines.     

电梯零速停靠的RBF神经网络预测算法

针对电梯运行过程中存在爬行距离的问题,提出了基于RBF(Radial Basis Function)神经网络的爬行距离预测模型.将预测的爬行距离增加到电梯速度曲线的匀速段,实现减小或消除爬行距离的目的,从而实现电梯的零速停靠.从电梯运行现场采集大量的原始数据,建立RBF神经网络预测模型,与BP(Back Propagation)预测方法进行仿真比较,结果表明RBF神经网络具有更好的预测效果.给出了应用零速停靠RBF预测算法前后电梯运行的速度曲线,爬行距离减小或消除,电梯的运行时间变短,实现了节能.     

对一种多重密钥共享认证改进方案的完善

通过分析一种多重密钥共享认证改进方案,指出其中存在的漏洞和防止成员欺骗中存在的问题,提出了自己的完善方案,使其在共享多个密钥、子密钥可以重复使用、防止管理者欺骗及参与成员欺骗等方面更加完善．     

蚯蚓体表与土壤接触界面动态行为仿真

应用离散元软件PFC2D建立了蚯蚓波纹体表与土壤界面动态行为仿真模型,对比分析了光滑和波纹试样的接触界面、接触力场和接触颗粒数以及滑动阻力,得出:当波纹表面的摩擦力与土壤颗粒对波纹凸起处的向后推力之和小于光滑表面的摩擦力时,波纹表面起到减阻作用;如果土壤颗粒对波纹表面凸起处的向后推力过大,波纹会起到增加阻力的作用。另外,试样运动时,波纹表面比光滑表面对土壤的扰动大。随着垂直载荷的增加,波纹表面和光滑表面的滑动阻力均增加,且波纹表面的降阻效果减弱;随着前进速度的增加,2种试样滑动阻力的增加,但波纹表面的滑动阻力的增长小于光滑表面,即速度高时波纹表面降阻明显。结果表明:蚯蚓非光滑表面的减阻能力与接触界面特性和外部条件有关。研究结果可为揭示非光滑表面的减阻机制提供研究方法和参考。     

BUCK—BOOST DC／DC变换器RHP零点研究

对于BUCK—BOOSTDC／DC变换器,如何获得较大的稳定裕度和良好的高频瞬态性能一直以来都是令研究人员棘手的问题。要使这种变换器稳定工作,往往需要在一个很低的频率下就滑离控制电路的增益,文章基于变换器的占空比控制方式与电流控制公式分析了右半平面零点的动态特性,为提高电源系统的稳定性提供了理论依据。     

基于零知识交互式证明和Bayesian信誉网的小世界P2P模型

针对当前P2P(Peer-to-Peer)系统在网络拓扑和信誉评估机制结合方面的不足,设计一种基于角色和信誉访问控制机制的可信小世界P2P(SW-R2P)模型.模型使用零知识交互式证明(ZKIP)算法,在不传输节点身份相关信息的前提下安全地验证对等节点的组信息,并以此作为构建小世界网络拓扑的基础.通过Bayesian信誉网对节点和组的多方面信誉进行评估,从而影响节点的各种操作和组之间连接的建立.仿真实验结果表明,SW-R2P模型在资源查找成功率、网络聚合度以及节点信誉偏差等方面的性能优于Chord和R2P模型.SW-R2P模型结合了ZKIP算法、Bayesian信誉网和小世界拓扑的优势,实现了一种可信、安全和高效的P2P网络架构.     

改性石英砂的润湿性能研究

对经过改性处理之后的普通石英砂的润湿性能进行了研究。实验采用滴水穿透时间法（WDPT）、酒精溶液入渗法（MED）、接触角测定法三种方法。通过这三种方法来定性和定量地描述其润湿性能。实验结果表明：直接经过酸化处理的石英砂与经过硅烷化处理的石英砂的润湿性能有着明显的改变,前者较普通石英砂表现更为亲水,而后者表现出斥水性。此研究为用石英砂模拟不同润湿性能土壤提供了表面改性方法以及前期的理论准备。