Thermochemistry on coordination behavior of samaric chloride hydrate with diethylammonium diethyldithiocarbamate

The complex of samaric chloride lower hydrate-with diethylammonium diethyldithiocarbamate (D-DDC) was synthesized conveniently in absolute alcohol and dry N2 atmosphere. The title complex was identified as Et2NH2[Sm(S2CNEt2)4] by chemical and elemental analyses, the bonding characteristics of which was characterized by IR.T he enthalpies of solution of samaric chloride hydrate and D-DDC in absolute alcohol at 298.15 K and the enthalpies change of liquid-phase reaction of formation for Et2NH2[Sm(S2CNEt2)4] at different temperatures were determined by microcalorimetry. On the basis of experimental and calculated results, three thermodynamic parameters (the activation enthalpy, the activation entropy, and the activation free energy), the rate constant, and three kinetic parameters (the apparent activation energy, the pre-exponential constant, and the reaction order) of liquid phase reaction of formation were obtained. The enthalpy change of the solid-phase title reaction at 298.15 K was calculated by a thermochemical cycle.     

微量射出标签机数控系统的开发

提出了一种用于微量射出标签生产的自动加工设备,并重点介绍了其嵌入式控制器的研制.该嵌入式控制器硬件平台采用ARM7微处理器和AT89C52单片机,驱动芯片采用TA8435;软件平台采用ìC/OS-II实时操作系统,将控制软件划分成几个功能模块,并给出了各功能模块在系统中对应任务的优先级.该嵌入式控制器的软硬件划分及缓冲区的使用较好地满足了微量射出标签加工的实时性要求.实际应用表明该自动加工设备具有操作简单、稳定可靠、低成本、高性能的特点.     

库仑滴定法测定工业废水中微量砷

以库仑滴定法测定工业废水中微量砷，以死停终点法确定滴定终点，最后以EXCEL处理实验数据，本方法具有灵敏度高，准确，简便快速，仪器便宜，易于推广的特点，特别适用于工厂及县级以下环境监测站进行水中微量砷的检测，方法的回收率为99．3％。     

某网络设备EMC 测试超标的分析和结构优化

某设备带插卡EMC测试中辐射超标,文中从插卡PCB和机箱导槽的电容耦合效应入手,分析了EMC测试超标的原因,通过在机箱导槽和PCB之间设计一个铍铜弹性夹片零件,增强了PCB的单板地和机箱之间的电气连接可靠性,从而有效减少了电磁波的电容耦合效应,解决了EMC测试超标问题。同时运用有限元分析方法并进行样品实物测试对比,分析了该铍铜弹性夹片零件在实际生产应用中出现的夹持不可靠问题的原因,并通过更换合适的铍铜材料型号和选择正确的热处理方式解决了该零件的夹持不可靠问题。     

Trace amounts of impurities in electrolytic manganese metal by sector field inductively coupled plasma mass spectrometry

An analytical method, using sector field inductively coupled plasma mass spectrometry （SF-ICP-MS） for rapid simultaneous determination of Be, Na, Mg, Si, Ca, Ti, V, Cr, Fe, Co, Ni, Cu, Zn, As, Sn, Sb, Pb and Bi in electrolytic manganese metal, was described. At the beginning, the samples were decomposed by HNO3 and H2504, and then analyzed by SF-ICP-MS. Most of the spectral interferences could be avoided by measuring in different mass resolution modes. The matrix effects due to the excess of sulfuric acid and Mn were evaluated. Correction of matrix effects was conducted by using the internal standard elements. The optimum condition for the determination was investigated and discussed. The detection limit is in the range of 0.001-0.169 gg/L. The current method is applied to the determination of trace impurities in electrolytic manganese metal. And experiments show that good results can be obtained much faster, more accurately and conveniently by current method.     

稀土和微量元素玻璃肥料

玻璃肥料以玻璃态为基质,添加稀土和微量营养元素,具有合适的植物营养物释放速率。玻璃肥料有效地应用于水稻、水果、蔬菜、食用菌、花卉及其他植物,施用玻璃肥料可以促进植物生长,增加产量。综述了玻璃肥料成分与制备,并指出玻璃肥料存在的问题和发展方向。     

对增加铜塔入口气体中 CO_2分析之我见

《化工设计通讯》在1991年第3期上发表了一篇题为《增加铜塔入口气体中 CO_2分析的建议》的文章。该文系读者结合所在厂的生产实践所撰写的一篇读后文章,对增加铜塔入口气体中 CO_2分析提出了四条补充意见(①CO_2红外气体分析仪的位置选择;②增加 CO 含量自动分析的必要性和可行性;③改进压缩机直通阀;④增加精炼气中 CO+CO_2自动分析)。     

铍铜轴承轮可减少磨损、磨屑

美国蜜蜂机器人公司开发出一种铍铜构件，可以无需滑动环或电刷，而能向转动设备输入或输出电流。该项研究受到美国导弹国防局的资助。这种构件可应用于船用雷达、印刷机以及一些工业设备的机件装置。BeCu导电轮被压制成拥有增大的接触表面积，从而可直接传输大电流。     

微量溶氧表在我厂的使用情况

目前我国高压以上机组的热力系统均为无氧运行，在热力系统中除氧器承担了除去大部分溶解氧的任务，另外化学和真空除氧，也为热力系统无氧运行提供了保证。由于热力系统的严密性、除氧设备以及人员操作等方面的原因，热力系统中仍或多或少有微量氧的存在。如何做到准确测量微量溶解氧，是火力发电厂考核化学监督水汽的重要指标。     

上海光源同步光监测系统第一面萃取镜设计

本文介绍了上海光源(SSRF)同步光监测系统第一面萃取镜的设计.设计要求从同步光中尽可能不失真地分离出可见光.设计难点在于同步光中的高能X射线会致使萃取器件发热灼损,产生形变,影响可见光成分的波前和幅度.我们通过对同步光的功率谱分析和基于ANSYS程序的受热形变分析,设计出一面带水冷系统的铍镜用以反射可见光和透射X射线,以满足设计要求.