磷酸三丁酯在酸水溶液中溶解度的测定

在20~70℃之间,用浊点法测定了磷酸三丁酯在水、盐酸和硫酸溶液体系中的溶解度.水在TBP-煤油有机相中的溶解度D(H2O)是TBP在水中溶解度δ的60倍;随着温度升高纯TBP和煤油稀释的TBP在水相中的溶解度δ都增加,符合Apelblat溶解度模型,即纯TBP在水中的溶解度与温度的关系:lgδ=3.509 4-1 328.31/T;用煤油稀释TBP可以降低TBP在水相中的溶解度δ;随着盐酸和硫酸的浓度的增加,纯TBP在酸液中的溶解度也增加,盐酸的影响更显著.     

Direct reduction of carburized pre-reduced pellets by microwave heating简

A new iron-making process using carburized pre-reduced iron ore pellets and microwave heating is investigated. The pre-reduced pellets, with a porous structure, and fine particles are carburized homogeneously at 400-650 ℃ in a CO atmosphere. The carburized carbon not only acts reaction as a reduction agent, but also absorbs microwave in the reduction process. Hence, the carburized pre-reduced pellets can be rapidly reduced by microwave heating. There are three procedures involved in the process, namely, gas-based pre-reduction, low-temperatttre carburization and deep reduction by microwave heating. Carburized pre-reduced iron ore pellets show a rapid temperature rise that is twice as fast as the results for pre-reduced pellets in the laboratory. This not only improves the efficiency of the microwave heating, but also accelerates the reduction of iron oxides. The temperature of the pre-reduced pellets rises to 1050 ℃ in 45 min when the carburization rate is 2.02%, and the metallization rate and compressive strength reach 94.24% and 1725 N/pellet, respectively.     

SO_4~(2-)改性对Ce、Ti基催化剂NH_3-SCR脱硝性能的影响

采用共沉淀法制备了几种不同的金属氧化物催化剂(Ce-Pr-Ox、Ce-Y-Ox、Ti-PrOx、Ti-Y-Ox、Ti-Al-Ox),并对其进行了硫酸盐改性.实验同时考察了SO2-4改性对催化剂氨选择性催化还原(NH3-SCR)活性和催化剂结构组成的影响.经SO2-4改性的催化剂,NOx转化率在低温和高温均有显著提高,其中,活性最好的Ce-Pr-Ox在350~500℃范围内转化率接近100%.XRD、IR分析结果表明,催化剂经硫酸盐改性后,催化剂出现了结晶态硫酸盐;催化剂中存在M-SO2-4(M=Al,Pr和Y)键,表明了金属氧化物与硫酸盐发生了相互作用.而经SO2-4改性后催化剂优越的SCR脱硝性能与催化剂酸性位点增加密切相关.     

生球干燥过程及其数学模型

本文探讨了生球干燥过程,发现干燥速度与时间的关系曲线呈“双峰”状和“过渡”状等现象,分析了这种现象的原因,在此基础上,综合考虑了生球干燥过程的物质平衡和能量平衡,建立了生球干燥的全过程模型,实验证明该模型能很好地描述生球干燥的全过程。     

电镀废水综合治理技术

该项目包括含铬和含氰酸碱电镀废水处理两套系统，采用在酸性条件下用铁还原六价铬为三价铬．在碱性条件下用次氯酸钠氧化氰(破氰)，在一定pH值范围内使重金属离子生成相应的氢氧化物沉淀。废水处理系统和设备设计新颖，具有如下特点：(1)技术(设备)适应性强，具有几种治理功能，可处理单一工种和多工种混合废水。     

不锈钢,铜和铝合金酸性土壤腐蚀行为研究

研究了1Cr13,1Cr18Ni9Ti,H62黄铜和Ly11铝合金在酸性土壤中的腐蚀行为,结果表明,Ly11铝合金的腐蚀率比不锈钢的腐蚀率约大50倍,发现Ly11铝合金在不同种的酸性土壤中的腐蚀率与其腐蚀产物的相结构有一定的对应关系     

二安替比林甲烷分光光度法测定电镀废水中钛的含量

在酸性介质中,以抗坏血酸和焦磷酸钠共同作掩蔽剂,用二安替比林甲烷分光光度法测定电镀废水中钛的含量,方法简便,准确度高.     

304不锈钢在室温HCl+NaCl溶液中的应力腐蚀机理

304不锈钢在室温HCl+NaCl溶液中可发生活化态下的应力腐蚀开裂(SCC).XPS成分分析表明:在酸性氯化物溶液中,试样表面形成了一层富铬的吸附产物膜,应力腐蚀裂纹的形核与这层膜的形成和Cl一局部富集有关.     

Leaching of complex sulphide concentrate in acidic cupric chloride solutions

The chemical analysis of a complex sulphide concentrate by emission spectrometry and X-ray diffraction shows that it contains essentially copper, lead, zinc and iron in the form of chalcopyrite, sphalerite and galena. A small amount of pyrite is also present in the ore but does not be detected with X-ray diffraction. The cupric chloride leaching of the sulphide concentrate at various durations and solid/liquid ratios at 100 ℃ shows that the rate of dissolution of the ore is the fastest in the first several hours, and after 12 h it does not evolve significantly. If oxygen is excluded from the aqueous cupric chloride solution during the leaching experiment at 100 ℃, the pyrite in the ore will not be leached. The determination of principal dissolved metals in the leaching liquor by flame atomic absorption spectrometry, and the chemical analysis of solid residues by emission spectrometry and X-ray diffraction allow to conclude that the rate of dissolution of the minerals contained in the complex sulphide concentrate are in the order of galena 〉 sphalerite 〉 chalcopyrite.     

鞍钢与澳大利亚公司合资建球团矿厂

澳大利亚的gindalbie金属公司已经证实，将和中国的鞍山钢铁集团公司合资，在营口新建一座年产能为400万t的球团矿生产厂。该厂所用的矿石将由两家公司共同拥有、位于澳大利亚西部的Karara项目提供，该项目计划2008年开始投产，年产1000万t铁矿石。