英屿沟Ⅱ号天桥的设计

为推广预应力混凝土箱梁结构在桥梁方面的应用研究,结合英屿沟Ⅱ号天桥实例,介绍了该组合结构在桥梁方面具体应用的设计思路,介绍了英屿沟Ⅱ号天桥波形钢腹板PC组合箱梁桥主梁结构、预应力体系、波形钢腹板、连接件、防腐、施工流程等的设计,为波形钢腹板PC组合箱梁结构应用于桥梁工程提供了设计经验.     

新密市溱水路大桥波形钢腹板无背索斜拉桥总体设计

在桥型方案确定后,桥梁总体设计是设计者首先考虑的问题.新密市溱水路大桥波形钢腹板无背索斜拉桥的总体设计研究了桥梁结构受力特点,初拟了桥梁主要结构组成,对主体结构进行了初步的结构计算分析,并得出了初算成果,确认了桥型方案的可行性和结构的合理性.在该桥设计中,首次将波形钢腹板箱梁应用于无背索斜拉桥结构,为波形钢腹板箱梁组合结构在我国的推广应用奠定了基础.     

CuO-NiO/Al_20_2催化剂上N-甲基哌嗪合成研究

以共沉淀法制备铜、铝系复合氧化物作为催化剂,二乙醇胺和甲胺为原料,合成了N-甲基哌嗪.利用高压反应釜对其进行活性评价,发现CuO-NiO/Al2O3活性最高.并对铜、铝、镍摩尔比、沉淀剂种类、沉淀方式,焙烧温度等条件进行了优化.结果表明:催化剂中理想的Cu、Al、Ni摩尔比为1:1:3.2,沉淀剂为氢氧化钠,沉淀方式为并流,焙烧温度为500℃.该条件下N-甲基哌嗪的选择性为27.7%,二乙醇胺的转化率达89.8%.另外通过对使用前后催化剂进行表征分析发现催化剂失活原因为表面高聚物的附着和对孔道的堵塞.     

Intergranular oxidation of silicon in 20Cr-25Ni niobium-stabilized stainless steel at 1140–1230 K

The kinetics of intergranular oxidation of silicon in a 20Cr-25Ni Nb-stabilized stainless steel are reported, at temperatures in the range 1140–1230 K, in CO₂ at 40 bar pressure. The depth of attack increased parabolically with respect to time, with an activation energy of 335±30 kJ/mol. The mechanism of growth is discussed in terms of classical internal-oxidation theories, and an alternative explanation based on an available-space theory is developed. The internal oxidation rates in a number of different alloys are compared with diffusivities of metals in the base alloy. It is proposed that intergranular oxidation in the 20–25 Nb steel is controlled by the rate of outward diffusion of iron or chromium in the alloy.     

Effects of laser heat treatment on the fracture morphologies of X80 pipeline steel welded joints by stress corrosion

The surfaces of X80 pipeline steel welded joints were processed with a CO2 laser, and the effects of laser heat treatment （LHT） on H2S stress corrosion in the National Association of Corrosion Engineers （NACE） solution were analyzed by a slow strain rate test. The fracture morphologies and chemical components of corrosive products before and after LHT were analyzed by scanning electron microscopy and energy-dispersive spectroscopy, respectively, and the mechanism of LHT on stress corrosion cracking was discussed. Results showed that the fracture for welded joints was brittle in its original state, while it was transformed to a ductile fracture after LHT. The tendencies of hydrogen-induced corrosion were reduced, and the stress corrosion sensitivity index decreased from 35.2% to 25.3%, indicating that the stress corrosion resistance of X80 pipeline steel welded joints has been improved by LHT.     

马钢2号高炉中修后开炉达产操作实践

对马钢2号高炉中修后开炉达产操作实践进行了总结。通过制定科学的开炉方案,快速提高煤比、降低焦比,实现了顺利开炉、快速达产达效的目标。     

Immobilizing chromium in stainless steel slags with MnO addition

This work investigates the stabilizing impact of MnO on the leaching behavior of hazardous Cr-containing CaO-SiO₂-Al₂O₃-Cr₂O₃-MnO stainless steel slags after equilibrating at various elevated temperatures and evaluates the potential immobilization of Cr into a MnCr₂O₄ spinel phase from the existing Cr₂O₃ phase. The MnCr₂O₄ spinel phase was found to be an excellent Cr-stabilizer in stainless steel slags, where the leaching tendency of potentially hazardous Cr-related ions decreased with higher MnO content and lower equilibration temperatures within the range of 0 to 15 mass pct. and 1500 to 1300°C, respectively. Thermodynamic calculations by conducting the phase stability diagram also showed that the MnCr₂O₄ spinel phase was relatively stable and the Ca₃Si₂O₇ (Ca_3-xMn_xSi₂O₇) phase was relatively unstable compared with other crystal phases in acid extractant with pH value of 3.2. Combined with the scanning electron microscopy and X-ray powder diffraction results along with the thermodynamic calculations, the leached Cr-related ions was predominantly originating from the unstable amorphous glass phase.     

Wear mechanisms of PcBN tools when machining AISI 316L

This paper investigates the machinability of AISI 316L stainless steel without and with NMI treatment, when machined with three different PcBN tool grades: low cBN content (50% vol.), medium (65% vol.) and high (90% vol.). The NMI treatment consisted of resulfurized and Ca-treated steels with two different Si/Al ratio. The tool materials were evaluated in terms of tool life, showing the best performance for the medium cBN content grade. Results showed that the crater wear has a more significant effect on the tool performance than the standard wear criteria of maximum flank wear. The worn tools were examined using scanning electron microscopy (SEM), focused ion beam (FIB) and transmission electron microscopy (TEM). In most cases, the crater exhibited three distinct regions from the edge to the end of the contact zone: the plateau, middle crater, and the upper region. Plateau and crater region displayed tool protective layer (TPL), consisting mostly of Al, Si, Mg and Ca-oxides; and some dimples in the tool from preferential wear of cBN grains. In the upper region of the best performing material, a ~1.5 μm thick TPL of mostly MnCr₂O₄ spinel was found, a result of the transfer of Mn- and Cr-rich oxide NMIs found in this material or oxidation of workpiece material, during the machining process.     

高温预析出对Al-Zn-Mg-Cu铝合金显微组织、强度和应力腐蚀抗力的影响

通过改变固溶条件 ,对Al Zn Mg Cu高强铝合金采用先高温后低温的两步固溶处理 (高温预析出 )来改善晶内和晶界的析出状态 ,研究了高温预析出对Al Zn Mg Cu铝合金的金相组织、强度和应力腐蚀性能的影响。结果表明 ,4 6 5℃高温预析出在保持较高强度和塑性的同时 ,可以改善合金的抗应力腐蚀性能     

High Temperature Oxidation of Steels in Air and CO2–O2 Atmosphere

Three kinds of hot rolled steel slabs, viz. high strength steel, bake hardened steel and low carbon steel, were oxidized isothermally between 1100 and 1250 °C for up to 2 hr in 1 atm of air and an 85%N₂–10%CO₂–5%O₂ gas mixture. The steels were oxidized in a similar fashion in both the atmospheres. The oxidation process followed an initial linear rate law, which then gradually transformed to a nearly parabolic rate law. Thick, porous and nonadherent scales formed rapidly, due to the high oxidation temperature. The scales formed consisted of Fe₂O₃,(Fe₂O₃+Fe₃O₄), (Fe₃O₄+Fe₂O₃ +FeO) and (FeO+Fe₃O₄) from the outer surface. The presence of supersaturated oxygen beneath the scale resulted in grain boundary oxidation and the formation of internal oxide precipitates.