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101.
102.
TiSiW12O40/TiO2催化合成丙酸正丙酯 总被引:2,自引:0,他引:2
研究了固载杂多酸盐TiSiW12O40/TiO2催化丙酸与正丙醇的酯化反应,探讨了催化剂用量,反应时间及醇酸摩尔比对酯收率的影响。当醇酸摩尔比为1.3:1,催化剂的量为醇酸总质量的1.5%。反应时间为1.0h,酯产率可达71.4%以上,采用该催化剂合成丙酸正丙酯不仅酯化反应温度低,反应时间较短,催化剂用量少,而且可较好地回收利用,可降低成本;因此,TiSiW12O40/TiO2是合成丙酸正丙酯的优良催化剂,具有良好的应用前景。 相似文献
103.
Preparation of Compound Ultrafine CeO2 by Wet-Solid-Phase Mechanochemical Modification 总被引:1,自引:0,他引:1
To satisfy practical requirements from industrial applications, an alternate route for synthesis compound ultrafine CeO2 powders by wet-solid-phase mechanochemical modification using industrial grade hydrated cerium carbonate as raw material was proposed.The effect of modifier reaction percentage, reaction time, calcining temperature and modifier amount on particle size, density, suspensibility, and hardness of compound CeO2 powder was investigated.The phase evolutions of preparation process were characterized by XRD.SEM micrograph of the final product shows that compound CeO2 powders obtained are well-dispersed, spherically-shaped, uniformly-sized and submicron-sized particles.The method is readily available in raw material, low in cost, simple in process, and has great potential for industrialization.The compound CeO2 powders of different physical properties can be synthesized by controlling the above-mentioned influence factors in preparation process. 相似文献
104.
根据生产实践 ,结合PLC的技术特点和 385m2 凯利式叶滤机的电气联锁特性 ,阐述了应用PLC技术 ,可进一步提高 385m2 凯利式叶滤机的运转率和自动化水平。 相似文献
105.
F.A. Rodrigues 《Cement and Concrete Research》2003,33(6):823-827
This paper describes the synthesis of cements, chemically and structurally related to Ca2SiO4. Silica was obtained from rice hull after heating at 600 °C. Calcium oxide and small amounts of barium chloride were mixed in order to obtain a final (Ca/Si) or (Ca+Ba)/Si ratio equal to 1.95, 1.90, and 1.80, which is lower than in the conventional cement. The solids were mixed and ultrasonically treated for 1 h with a water/solid ratio of about 20. After drying and grinding, the mixtures were heated up to 1100 °C. It was possible, in some cases, to obtain a cementitious material. These cements are structurally related to β-Ca2SiO4 and the lower (Ca+Ba)/Si ratio obtained was 1.95. The initial chemical compositions of these cements are: (Ca1.83+Ba0.12)SiO4 and (Ca1.79+Ba0.16)SiO4. A further lowering in the (Ca+Ba)/Si ratio changes the nature of the silicates. 相似文献
106.
The removal of Cu(II) by adsorption on fly ash has been found to be concentration, pH and temperature dependent. The kinetics of adsorption indicates the process to be diffusion controlled. The Langmuir constants have been calculated at different temperatures, and the adsorption has been found to be endothermic (ΔH = 15.652 kcal mol?1). The maximum removal is observed at pH 8.0, and variation in adsorption with pH has been explained on the basis of surface ionisation and complexation. 相似文献
107.
MoSi2-based intermetallics containing different volume fractions of MoB or Mo5Si3 were fabricated by hot-pressing MoSi2, MoB, and Mo5Si3 powders in vacuum. Both classes of alloys contained approximately 5 vol.% of dispersed silica phase. Additions of MoB or Mo5Si3 caused the average grain size to decrease. The decrease in the grain size was typically accompanied by an increase in flexure strength, a decrease in the room temperature fracture toughness, and a decrease in the hot strength (compressive creep strength) measured around 1200 °C, except when the Mo5Si3 effectively became the major phase. Oxidation measurements on the two classes of alloys were carried out in air. Both classes of alloys were protected from oxidation by an in-situ adherent scale that formed on exposure to high temperature. The scale, although not analyzed in detail, is commonly recognized in MoSi2 containing materials as consisting mostly of SiO2. The MoB containing materials showed an increase in the scale thickness and the cyclic oxidation rate at 1400 °C when compared with pure MoSi2. However, in contrast with the pure MoSi2 material, oxidation at 1400 °C began with a weight loss followed by a weight gain and the formation of the protective silica layer. The Mo5Si3 containing materials experienced substantial initial weight losses followed by regions of small weight changes. Overall, the MoB and Mo5Si3 additions to MoSi2 tended to be detrimental for the mechanical and oxidative properties. 相似文献
108.
A semi-empirical mathematical model for the acid-oxygen pressure leaching of Ni–Cu matte is presented, based on data from batch leaching experiments. The primary controlling factor in the leaching process is found to be galvanic inhibition of the more highly oxidized copper and nickel sulfide species by less oxidized species, particularly Ni alloy and Ni3S2. The leaching rate of many species is greatly reduced by the presence of one or both of these phases, and others will not commence leaching until neither is present. The mathematical model is based on first-order chemical reaction controlled rate expressions, as the reactions occurring are electrochemical in nature. Mass transfer effects are included only empirically. Some possibly diffusion-related phenomena are noted, although the model is not extended to incorporate these effects on a fundamental level. The model is verified and extended by the inclusion of several different factors that were tested experimentally. The effects of variations in O2 flow rate and partial pressure, initial particle size, reaction pulp density and initial acid concentration were all studied, and included in the model. Variations in O2 flow rate and partial pressure are found to affect the reaction rates via the dissolved oxygen concentration in the solution phase. 相似文献
109.
Five new salts based on 1-alkyl-2-methyl pyrrolinium ion are reported, two involving the iodide ion and three involving the bis(trifluoromethanesulfonyl) amide ion. The iodide salts have melting points around 100 °C, while the amide salts have melting points around room temperature. Two of the amide salts can be easily quenched into the glassy state and exhibit glass transition temperatures around −70 °C. The 2-methyl pyrrolinium cation bears structural similarities to the aromatic imidazolium cations on one hand and the cyclic ammonium cation family based on the pyrrolidinium cation on the other. The properties of the salts reported here are compared within these two related families of salts. 相似文献
110.