热变形对GH4169合金中NbC析出相尺寸形貌影响研究

通过Gleeble3500热模拟试验机进行热压缩试验并结合微观组织观察和统计分析,研究了热变形对GH4169合金中NbC颗粒尺寸形貌、分布特征的影响规律。研究表明压缩过程中的绝热效应会导致试样心部温度的进一步升高,从而为变形过程中的NbC回溶提供条件。NbC颗粒与基体在变形过程中形成的高位错密度区促进了元素的扩散,并加速了小曲率半径的尖角区域回溶和钝化。随变形量的增加NbC回溶趋势增加,其平均尺寸与体积分数均呈降低趋势。变形过程金属流动会促进NbC颗粒的位移,在70%的变形量下,NbC颗粒平均间距增加趋势显著高于30%和50%变形量试样。因此随变形量的增加,NbC颗粒有从链状→链条弯曲→链条方向改变→弥散分布的分布特征,促进基体中原链状NbC呈细小、弥散分布。研究结果为GH4169闪光焊接性能的提高提供了直接的参考。     

热挤压成形GH3625合金管材组织及裂纹形成机理

通过对比热挤压成形管材和爆裂管材的组织以及对爆裂管材裂纹和断口的分析,研究了热挤压成形GH3625合金管材的组织及裂纹形成机理。结果表明:爆裂管材与成形管材的组织均为等轴晶,但爆裂管材的开裂使晶界处的应力集中得以释放,其组织中并没有形成变形孪晶,在管材径向方向上也不存在晶粒尺寸不均匀的现象。挤压比过高导致管材在热挤压过程中绝热升温严重,使低熔点的Laves相熔化并扩散到周围基体中,是裂纹形成的根本原因。在模具出口处高拉应力的作用下,这些裂纹不断扩展最终连接在一起,导致管材的爆裂现象。由于断口表面冷却速率较高,组织通过奥氏体区的时间较短,再结晶形核核心多且晶粒长大过程受阻,使断口表面形成了一层十分细小的再结晶晶粒。     

喷丸处理对GH3535合金900℃恒温氧化行为的影响

采用不连续增重法,对喷丸状态与非喷丸状态GH3535合金900℃恒温氧化行为进行了对比研究。结果表明,900℃下,喷丸强度0.45Nmm样品与未喷丸样品相比,氧化增重降低了79.7%。未喷丸GH3535合金表面氧化产物为NiCr2O4,MoO2,NiMoO4,喷丸状态下氧化膜主要由NiO、NiFe2O4、Cr2O3和NiCr2O4组成。喷丸处理后GH3535合金表面产生塑性变形使晶粒细化,位错密度增加,在合金表层塑性变形区域的位错及晶界充当了Cr原子的快速扩散路径,增加了Cr原子扩散通量,促进Cr向表面扩散形成富Cr氧化物,使得Cr2O3层的更快形成,减少了瞬态氧化期。     

Incipient melting phase and its dissolution kinetics for a new superalloy

Based on XRD, SEM and EDS analyses, the phases in GH4151 alloy were identified. Differential scanning calorimetry (DSC) experiment and metallographic method were carried out to determine the incipient melting temperature (IMT) of the alloy. The result shows that the IMT of alloy is situated between 1150 and 1160 °C. Subsequently, the dissolution process of Laves phase was carried out, and the dissolution kinetic equations were obtained at different temperatures. And then based on the verification of experiments, the model was confirmed to be credible to predict the fraction of the Laves phase dissolution. Finally, the results of diffusion coefficients indicate that the diffusion of Nb element is a critical factor for homogenization process of GH4151 alloy.     

Neutron diffraction and finite element analysis of quenching residual stress of GH4169 super alloy

The quenching process is indispensable for manufacturing the superalloys. However, high residual stress is inevitably induced by the large heat gradient, which influences the mechanical properties of the alloys. Therefore, it is of great significance to accurately characterize the internal residual stress of the super alloy and establish an effective finite element modeling. The quench- induced residual stresses of GH4169 super alloy were measured using neutron diffraction stress instrument. The results show that the center of the workpiece is subjected to tensile stress in three directions (hoop, radial and axial), which is about 400MPa. The rims of workpiece are subjected to compressive stress in one or two directions (hoop or axial), which is from -300MPa to -400MPa. The temperature and strain/stress fields of the GH4169 super alloy workpiece during quenching process were simulated by a 3D finite element model. The calculated residual strain/stress at the center and rim of the workpiece are compared to those by neutron diffraction, which shows good correspondence. These data provide reliable evidences to the formation of the residual stress during quenching.     

热处理工艺对高温合金GH2132力学性能的影响

研究了时效处理对高温合金GH2132力学性能的影响,并分析了合金组织与性能变化的原因。结果表明,由于时效过程中析出物γ'的沉淀强化作用,合金强度得以提高,塑性下降。982 ℃固溶+718 ℃时效能使合金获得较好的综合力学性能。     

组织特征对GH864合金裂纹扩展行为的影响

测试不同热处理条件下GH864合金在650℃空气中疲劳/蠕变交互作用下的裂纹扩展速率,分析热处理制度及组织特征对合金裂纹扩展速率的影响.通过组织分析试验、裂纹扩展速率试验和断口形貌分析,对比不同组织状态下GH864合金的微观组织及裂纹扩展行为,并用Paris公式对裂纹扩展速率的结果进行描述.结果表明:热处理后合金的裂纹扩展速率都明显降低;晶粒度对合金的裂纹扩展速率影响较大,且粗晶组织能显著降低裂纹扩展速率;晶界析出相对裂纹扩展速率有较大作用,而强化相γ'相大小对裂纹扩展速率影响不明显.从组织形貌及断口分析可较好解释不同热处理制度裂纹扩展速率曲线的试验结果.具有疲劳条纹特征断口对应较慢的裂纹扩展速率,而沿晶断裂对应较快的裂纹扩展速率.     

水胶比及矿物掺和料对净浆塑性收缩影响

采用自行设计测定塑性收缩的方法,对不同胶凝材料净浆在不同水胶比情况下的塑性收缩变化规律及矿物掺和料对塑性收缩的影响进行了研究。试验结果表明,净浆塑性收缩与水胶比有关;水胶比为0.28~0.35时,塑性收缩随水胶比的增加而减小,而在0.35~0.45范围内随水胶比的增加而增加;矿物掺和料的品种及掺量对净浆的塑性收缩也有很大的影响。     

GH141高温合金的热加工工艺

通过高温拉伸试验、热顶锻落锤试验、M6C相析出规律分析以及高温扩散退火试验等一系列试验,研究了GH141合金的热加工塑性。结果表明,GH141合金在1000～1150℃范围内加热具有良好的热加工塑性,生产中最佳加热温度为1170℃,使M6C相在加热过程中全部回溶,开锻温度≥1100℃,停锻温度≥1000℃。合金在锻造前应先进行(1180±10)℃高温扩散退火处理,保温时间≥10 h。