镁合金大塑性变形技术的研究进展

相比于变质处理、快速凝固、粉末冶金等方法,大塑性变形技术(severe plastic deformation,SPD)因具有独特的受力状态和较大的累积应变量而易获得超细晶组织及优异的力学性能,因此,SPD方法在高性能镁合金制备及加工方面显示出了明显的技术优势和发展前景.本文重点阐述了等通道转角挤压、往复挤压和高压扭转等典型镁合金SPD技术的研究概况,明确了镁合金SPD技术未来的向纵深方向发展的潜力所在.     

S －次仿紧空间

针对一些广义仿紧空间以及拓扑空间中半开集和半闭集的性质,本文将次仿紧空间的一些结论推广到半闭集的条件下,新定义并研究S －次仿紧空间的基本性质。首先给出一些基本的定义和定理,然后在此基础上定义S－次仿紧空间,最后得出一些主要结果：（1）空间X是S－次仿紧空间,则X的每一开覆盖U,存在半开加细覆盖序列｛Vn｝n∈N使对每一x∈X,存在n∈N,使ord（x,Vn）＝1,这里（ord（x,Vn）＝｜｛V：V∈Vn,x∈V｝｜）;（2）空间X是S－次仿紧空间,则X的每一开覆盖具有σ垫状加细覆盖;（3）如果（X,Fa）是S－次仿紧空间,则（X,F）也是S－次仿紧空间,并给出相应的证明。     

一种新的DNA模体发现聚类求精算法

模体发现问题是分析基因转录调控关系的一个重要方面．提出了一种新的基于熵的聚类求精算法--ECRmotif,用于DNA序列中的模体发现问题．ECRmotif使用灵活的概率模型从背景序列中鉴别模体．它首先使用一个基于熵的聚类过程将数据集划分为若干子集,并对各候选子集压缩其实例的搜索空间,求精得到模体．通过模拟数据和真实数据的实验,表明ECRmotif算法可以有效地提高运行速度和效率,并准确地找出模体．     

低铬X70管线钢组织及其抗CO2

为了明确Cr的质量分数高低对埋地用输油输气管线钢性能的影响,设计了4种Cr的质量分数的X70管线钢,研究了不同Cr的质量分数下管线钢组织及其力学性能,并采用高温高压反应釜进行了实验钢的CO₂腐蚀试验.结果表明：钢中加入0.1%~0.8%的Cr后,其组织均由针状铁素体和准多边形铁素体构成,Cr元素均呈现明显的沿晶界分布状态;随着Cr的质量分数的增加,钢板强度随之升高,晶界中Cr分布密度随之增大,Cr（OH）₃在腐蚀产物膜中的富集量增加,促使钢板的平均腐蚀速率降低;同时由于Cr（OH）₃可以有效阻碍阴离子穿透腐蚀产物膜,因而大大减少了Cl-的催化作用导致的点蚀,使得钢板点蚀速率明显降低.     

Synthesis and densification of magnesium aluminate spinel: effect of MgO reactivity

Stoichiometric magnesium aluminate spinel was synthesized by reaction sintering of alumina with caustic and sintered magnesia. The volume expansion of 5–7% during MgAl₂O₄ formation was utilized to identify the starting temperature of spinel formation and densification by high temperature dilatometry. The magnesia reactivity was determined by measurement of crystallite size and specific surface area. Caustic magnesia and sintered magnesia behave differently vis-à-vis phase formation and densification of spinel. Densification of stoichiometric Mag-Al spinel was carried out between 1650 and 1750 °C. Attempts were made to correlate the MgO reactivity with microstructure and densification of spinel.     

Remediation of activation energy anomalies,scaling distortions,and bandwidth limitations in superionic conductivity modeling of NZSP NaSICON synthesized by an augmented SSR method

Less constrained by bandwidth limitations and sampling scarcity, broadband profiling in a wide temperature range, starting at the cryogenic threshold at ?150 °C and extending to 200 °C, can be used to derive parameters of minimal variance for the Jonscher power law for ionic conductivity; these are employed to model the superionic regime over elevated temperatures and frequencies beyond the limits accessed by contemporary electrochemical impedance spectroscopy (EIS) equipment. We apply this technique to non-stoichiometric NaSICON based on the canonical NZSP formula with 5% excess sodium, synthesized by an augmented solid-state reaction (SSR) method. We thoroughly analyze broadband conductivity, dielectric permittivity, and electric modulus data over the extended temperature range. Activation energy anomalies and scaling distortions inherent to the Arrhenius approximation are investigated, and an alternative formulation based on linearized difference equations is proposed to remedy these issues. With Cole–Cole analysis establishing non-Debye relaxation behavior, dissipation analysis is employed to identify relaxation bands, used for extracting initial condition parameters for the Jonscher power law. Finally, simulations of the AC dispersion region at high temperatures and frequencies suggest the dominance of polaron tunneling mechanisms instead of the classical ion hopping mechanism assumed for NaSICON, in line with the latest insights on superionic conduction.     

Micro-scale fracture toughness of textured alumina ceramics

Enhanced fracture resistance of textured alumina is ascribed to crack deflection along grain boundaries. In this work, we quantify and compare the micro-scale fracture toughness of textured alumina grains and grain boundaries by micro-bending tests. Notched micro-cantilevers were milled from single alumina textured grains (perpendicular to the [0001] direction) and across several textured grains (along the [0001] direction), using a focused ion beam technique. Bending tests were performed with a nanoindenter. A shape function for notched pentagonal-shaped cantilevers was developed using finite element analysis. The critical stress intensity factor at the notch tip was determined based on the measured fracture loads. The micro-scale fracture toughness of the textured alumina grain boundaries (2.3 ± 0.2 MPa m^1/2) was about 30% lower than that of the grains (3.3 ± 0.2 MPa m^1/2). These findings at the micro-scale are paramount for understanding the macroscopic fracture behaviour of textured alumina ceramics.     

Defect redistribution along grain boundaries in SrTiO3 by externally applied electric fields

During thermal annealing at 1425 °C nominal electric field strengths of 50 V/mm and 150 V/mm were applied along the grain boundary planes of a near 45° (100) twist grain boundary in SrTiO₃. Electron microscopy characterization revealed interface expansions near the positive electrode around 0.8 nm for either field strength. While the interface width decreased to roughly 0.4 nm after annealing at 50 V/mm, the higher field strength caused decomposition of the boundary structure close to the negative electrode. Electron energy-loss and X-ray photoelectron spectroscopies demonstrated an increased degree of oxygen sublattice distortion at the negative electrode side, and enhanced concentrations of Ti³⁺ and Ti²⁺ compared to bulk for both single crystals and bicrystals annealed with an external electric field, respectively. Oxygen migration due to the applied electric field causes the observed alteration of grain boundary structures. At sufficiently high field strength the agglomeration of anion vacancies may lead to the decomposition of the grain boundary.     

High-temperature compressive creep behavior and mechanism of Hf6Ta2O17 ceramic as a candidate for thermal barrier coatings

A novel Hf₆Ta₂O₁₇ ceramics is prepared by a solid-state reaction method. High-temperature creep behavior of Hf₆Ta₂O₁₇ and 8YSZ ceramics are investigated by compressive creep test combined with a digital image correlation (DIC) method. It is found that the creep mechanism of Hf₆Ta₂O₁₇ ceramics is controlled by grain boundary sliding associated with dislocation movement (stress exponent ∼2-3, and activation energy of 600–620 kJ/mol). Grain boundary sliding accommodated to the interface reaction is the main creep mechanism of 8YSZ ceramics (stress exponent ∼2, and activation energy of 425∼465 kJ/mol). Hf₆Ta₂O₁₇ ceramics have higher creep resistance than 8YSZ ceramics under the same conditions.     

Synthesis,sintering, and grain growth kinetics of Hf6Ta2O17

A systematic study of the solid-state synthesis, pressureless sintering, and grain growth kinetics of Hf₆Ta₂O₁₇ is presented. The ideal conditions for solids-state synthesis of Hf₆Ta₂O₁₇ powder with minimal particle necking was 1250 °C for 2 h in air. The resultant powder has an average particle size of 210 ± 70 nm. The combined synthesis and ball-milling procedure produces highly sinterable Hf₆Ta₂O₁₇ powder, achieving > 97 % of theoretical density after pressureless sintering at 1600 °C for 2 h in air. The grain growth mechanism was sensitive to processing conditions, appearing to be primarily driven by surface diffusion below 1600 °C and grain boundary diffusion above 1650 °C. The respective activation energies for grain growth were found to be Q_S = 659 ± 79 kJ mol⁻¹ and Q_GB = 478 ± 63 kJ mol⁻¹.