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931.
932.
采用放电等离子烧结法制备(TiB2+TiC)/Ni3Al复合材料。在950°C下烧结的(TiB2+TiC)/Ni3Al复合材料的组织比在1050°C下烧结的(TiB2+TiC)/Ni3Al复合材料的组织更细小。对烧结温度分别为950°C和1050°C的复合材料在900°C下进行循环氧化性能测试。结果表明,在950°C下烧结的复合材料的循环氧化质量损失要小于在1050°C下烧结的复合材料的。晶粒细化有助于在氧化过程汇总的选择性氧化,使得连续的TiO2和Al2O3氧化膜得以在复合材料表面形成,从而提高复合材料的抗氧化性能。 相似文献
933.
With considering the characteristics of keyhole plasma arc welding (K-PAW ),the resonant frequency between arc and molten pool was solved in the frequency range 15000 Hz to 72000 Hz by finite element m... 相似文献
934.
We report here for the first time bulk and grain boundary conductivities from impedance spectra of a ceramic proton conductor (BaZr0.7Pr0.2Y0.1O3-δ) taken during hydration and H/D isotope exchange transients (at 400 °C). The results suggest that water moves quickly along grain boundary cores, and then interact from there with the space charge layers and, in turn, grain interiors. Hydration and H/D isotope exchange have simple monotonic effects on the bulk conductivity in line with what is expected from it being dominated by protons. The transients for grain boundary conductivity exhibit however hysteresis: During hydration, the core charge and grain boundary resistance appear to go through transient minima related to non-equilibrium distributions of defects between the core and grain interior – notably because protons diffuse faster than oxygen vacancies between the grain boundary and grain interior. At equilibrium, hydration increases the core charge and the depletion of positive charge carriers in the space charge layers. During H/D isotope exchange relatively fast hysteretic transients indicate that the space charge layers experience changes in charge carrier (D+ vs. H+) mobility as well as in D2O vs. H2O hydration thermodynamics. 相似文献
935.
The morphology and crystallography of the isothermal transformation of Fe-N austenite at 225 °C were characterized by transmission electron microscopy and scanning electronic microscope. Fe-N austenite was produced by through-nitriding thin pure iron sheets at 640 °C. Lath-shaped and periodically distributed (γ-austenite + γ′-Fe4N + α-Fe) microstructures formed at the prior austenite grain boundaries, this kind of microstructure was shown to be bainite in nature and kept a Greninge-Troiano orientation relationship between the γ-austenite (γ´-Fe4N) and α-ferrite. The formation mechanism of the grain boundary microstructure was shown to be the preferential precipitation of the proeutectoid γ′-Fe4N at the grain boundary, followed by the transformation of the N-depleted austenite into α-ferrite and γ′-Fe4N, thus forming a periodic γ-γ′-α-γ′-γ-γ′-α-γ′-γ-γ′ arrangement. 相似文献
936.
937.
In this paper the influence of high-temperature pre-precipitation treatment on corrosion behaviors of 7055 aluminum alloy is investigated. High-temperature pre-precipitation treatment enhances the discontinuing distribution of the coarse precipitates along the grain boundary, and increases the Cu content of grain-boundary precipitates, which obviously improves stress corrosion resistance, suppresses the serve fracture of sub-grain boundary under the stress corrosion and reduces inter-granular corrosion (IGC) susceptibility with the same strength and ductility. The electrochemical corrosion results of inter-granular phases indicate that the Cu-rich, discrete and coarse grain-boundary precipitates and the decreasing potential difference among inter-granular phases in the grain boundary are responsible for the enhancement of corrosion resistance of 7055 alloy. 相似文献
938.
Multi-phase-field (MPF) model with a higher-order term representing energetic penalty for multiple junctions was proposed to predict the grain growth accompanying the inclination dependence of grain boundary (GB) energy and mobility. The inclination effect was introduced on the basis of GB energy obtained from molecular dynamics (MD) simulations. The preliminary grain growth simulation of an isolated grain surrounded by Σ3 GB certified that the analytical equilibrium shape was well reproduced. The augmented higher-order term added to conventional MPF model could improve convergence and stability of numerical calculations around triple junction (TJ) region even if there exists the large GB energy gap at the TJ. Moreover, the present MPF model can realize well the Young’s relation with no GB inclination effect and further extend to the case with that effect. For the polycrystalline grain growth simulations with the GB energy distribution according to the misorientation angle of Al 〈1 1 0〉 tilt GB, Σ3 GB inclination lead the weak anisotropy characterized by Σ3{111} twin boundary. Besides, the inclination dependence can effectively drive the GBs with low GB energy like the low-angle GB during grain growth. 相似文献
939.
Paul C. Millett 《Computational Materials Science》2012,53(1):31-36
The percolation behavior of grain boundary networks is characterized in two- and three-dimensional lattices with circular macroscale cross-sections that correspond to nuclear fuel elements. The percolation of gas bubbles on grain boundaries, and the subsequent percolation of grain boundary networks is the primary mechanism of fission gas release from nuclear fuels. Both radial cracks and radial gradients in grain boundary property distributions are correlated with the fraction of grain boundaries vented to the free surfaces. Our results show that cracks surprisingly do not significantly increase the percolation of uniform grain boundary networks. However, for networks with radial gradients in boundary properties, the cracks can considerably raise the vented grain boundary content. 相似文献
940.
Prior austenite grain size dependence of the low temperature impact toughness has been addressed in the bainitic weld metals by in situ observations.Usually,decreasing the grain size is the only approach by which both the strength and the toughness of a steel are increased.However,low carbon bainitic steel with small grain size shows a weakening of the low temperature impact toughness in this study.By direct tracking of the morphological evolution during phase transformation,it is found that large austenite grain size dominates the nucleation of intragranular acicular ferrite,whereas small austenite grain size leads to grain boundary nucleation of bainite.This kinetics information will contribute to meet the increasing low temperature toughness requirement of weld metals for the storage tanks and offshore structures. 相似文献